Document omN52adgbNXy26zQJ85Vo4kor

LIA 16 95 3 0 INTERNATIONAL LEAD ZINC RESEARCH ORGANIZATION, INC. E*E M4D<0*i 4v |mw I. Wtw **. a* v WO** ay-oa u n c o m ** *il *ODMM Mn > ro*Ni Mroh T, To] Cbalraaa, Lead Indurtry Dawalnpaanf CcaMttaa Qalma, Laad Technical Starring OcBlttaa land Blactrochaalral MtiTlurgloal ftiiTri--ltH* Sr. 8. P. MU* Fros A. 8. Cook Subject: LB-99 - Bacortsiaatlaa of Osaa ta taad Aeld Battarlaa Attacbad 1* a copy of a rrport ce a aaatlog racautly bald at tha Polytechnic Xnatltuta of Brooklyn to ialtlata tha aheaa pragraa. I bava aada tha report awaally datallad slnoa tha application of calorlartrle tachdqua* to tha atudy of laad acid hattarla* la qulta umsunl and I aa arurlcm that all ccaoaraad should bava tha opportunity to ba fully couraraaat nth tha work. Flaaaa nota th* Appendix to tha Jteport, which 1* aa iadapaadast appraisal of tha use of ealcrisatric tachalqa* to problaaa of this typa. M bare boon l*>r**#d nth Brooklyn Folytaehola Institute's approach and look forward to a wary aueeaaafUl p AlCta* sociosuras OCr Dr. A. Salkynd Mr. B. Itltchla Sr. V. task Sr. Paul Bmlaa Mr. Btaalay Oauldar aw* WqRMpnvWWpCMPPM? - .JJ.W1UM H fiP mjpmmm L IA1695A A| tan WKm *rch j, 1966 tato of nUt Mbruary El, 1966 Joj Polytocbaie Saatltato of Irooklya 333 Ay fitroot Brooklyn, Brw Tort ttan fwiti Sr. A. EiUjfal.......... JlMtrie Storage Bttery Oo. Mr. X. Rltcbl* ........ Bagle-Plcber Ocegaay Dr. V. Zook.................C. fanout tal Bed Mr. A. I. Cook........... JLZJC Sr. Paul Bruits*........ .Polytechnic Sartltute of Brooklya Mr. Stanley Cauldar, Maeearcb BaUcw...JolyteckBlc laetltote of Brooklyn Purpooot To Mt up the reeearch profrea for LX-99 boccabiaetloc of Oeaea la Load Acid Batteries" ud arrange lo4u*try cooperatloe. Tbara u unanimous agrsaaaat oo the course of octloo decided. *oc-p*clllt la the battery flolA aay b lstarerted la the appendix to till report outlining how calorlaetrle rtudiea toa bo applied to the study of load acid battorloo. Action; Nr. S. Caul dor, with guidance frao Sr. A. BaUgrad aad 1 Prof. Brute*, trill co--nco work oo tbo progra* a* r outlined below. Sr. Zook will supply copies of tbo AUK bibliography 00 load battorloo. A. B. Cook will act op tbo aaxt nesting for Mld-Jaao. Mr. Xltchl* will supply eagles a* detailed la tb* report. Ackaowlodcaont*: IL2J0 would Ilk* to acknowledge tb* a**lotaaea pro vided by Sr. V. Zook, Sr. A. Salkynd ail Nr. B. Ritchie la setting up tbla program, aad to Sr. Zook la correcting tbo draft of tblx report. AXCtM CCt Sr. 8. t. Radtks Load Klactrocbcslcal-Metallurgical Subeoneittee Cbalroa, Load Technical Steering Coaedttee Cbalma, Load lndu*try Sevelopaact Coadttee aw -Af. * " * iV 3363 Ml -------- .------- ---------------- ...- t<1h -Wiiwwi'.awpiBWWMbBiiP1 J 'HJH.'MWIM--I L1A16955 '' 'l f (MM l Tut program, u agrssd to, mi bs seosldsrsd Is thrss jurti ss follows i 1. Cc--rclal 0*11 Ptudn Initial ealorlaatrle s^srlasots will bs cosdnrtsl with ft ftsftll no--rclal lsad acid mU, tbs -2V>. this work will prorlda fto Initial Ids* of tbs Iswnl of tbs boat sffsets background for tbs later work. 2ft addition, tbs sonstxwctloB of tbs oU is sosb that tbs ssnslni tbsrsistcrs efts saslly bs lsssrtsd lsto it, ftad prsssars --wiring Asrloss ess bs ftttftobsd. Bns tbs bsst bslaans ess bs ssMirsd as a ftnetiosi of ftlsctrolyts cooosotratlcs ftad polarisation, asd slMiltsnsoos ssssur--t caa bs Mds of proctors charge*. 2* fcpsrlasptal Qsll Studn A auftbsr of slsiatars slsctrocbsadoftl oalls will bs constructed for study Is ft plastic pressure borii sbleh sill Is turn bs plaosd Is tbs ealorlsNtsr. Prsssars will bs Is tbs t*og* 1/2 to 5 otMospbsrs positive prssw. lbs s--tlvn grids to bs sto&lsd will bs wds aft (s) Pars lsad (b) Oftleltfti (0.5*) lsad alloy (c) Astlaoey (6^) lsad alley (d) Mspsrsloe bardaosd lsad. * avoid aotlaocy cocrtaslnstloo of tbs ssgstlsss, tbs posl. tlrs platss ftad grids to bs ussd will bs sods with O.ff eolelua lsad alloy (ealolus doss sot traosfsr to tbs m.. r mmm .-'f' ra<Wi'ntfi> ttuffiti LI A 1695 6 m aH M U M M l l '1 .! ` i 3 * miiIIk ). Sa tba mm fain puM MfiUn pUtM art n^ulnd, tt bu teas mo mM that a aartala aoooat of to-oallad *aqaaten* ba lacVoted, (fepaadara ara aatarlal* teieb pravaet tbt aa^tlva plataa (To m daoalfyiag terlng epdlag ) 1/8$ Barlua telpbata was dltooaaad aa a aaltabla aldltlvaj oaltbar Mitoo Mack aor orprnln addltltaa vara ra^arted aa aaltabla tea to tba aabhar of tpoloa latoltad. Attrltloa aiU nrldti vtll ba waad. Patta tealtp till ba Sa tba atdlaa teaaa raaga. teagtt grate acid taa lodged aaltabla. Both but aagatlaa grids aad aall paatad plataa will ba taataA agalMt paatad poaltlta plataa, aad trout potltlwa eapaeltp will altapa ba prat tat# Tba wall will ba ebargad altbar at tarloua eooataot potastlala or aooataat currente, aad tba haat aad pratMira affaeta will ba aaaturad aa wll at tba opaimtlag potastlala aad oorraata. It abosld ba aotad that tbt baata of rtaetloo of tot of tba roaetloaa ableb art axpoctad to occur art haota, bat tba asaot ecodi- tloot of ooaat la a load acid aall ara act, aad It la anticipated tbat tbtaa coodltlcoa caa ba datarwload. ter aaa^la, tba asset of h/Aro|t& rrolutloa eaaoot ba datandaad aallp bp ritual ataaa, bat It should bt rtadllp rtcngnlitd bp tba baat affaeta. Beat of tba mrlablaa which wort ba cooaldarad la tbla todp arat (a) Total altctroda turfboa (b) Tbt capgtc prtaturt (e) Tbt rtftreact potaatial oc tba alaetrodaa 'am Ht.l.llfcl r*iWitol i iBj'i-'ftini LIA16957 a :., w '. Wfcft.. (4) tola*# f tto olootrolyto {) BMtrdgrto mMatnUoi (f) IlMtnlTU rloeodty (4) totoofotor** tlMtnii potaBtltli dll to -- nwd aotog aoroury/aercaroao enlfet* nftme* tlMtnlM. it to* to** NtoM that tto 5, 10 aad to bow latao to aaed to etorglac tb* oella, ud ttot prodeloa to aodo for etlrrtog tto electrolyte. All plate* U1 to totally totmt to tto oloctrolyt*. 3- ttare* efficiency of tto aeceitloot It la eery Itcoatast ttot o*ly aiyw to oeoleed darlaf etorslnc f a toad add mU If reoctotoettoa to to tato place aaA tto call 1* to to eealed. Zf hydro#** to rrolrad it dll leak cot throogh tto eaae, aaA tto eall dll giadually (t wt et totoao*. (A aletol naddao Me lad oall to operated ao ttot ao hydrc#*a to evolved.) Ik order to lawire ttot tto eall to aeaetroctod aad operated so ttot ao hydrogen la evolved, tto efficiency of tto active plat* euet to know. 8loo* tto oat*! Halt lac farter la lead add tottery cperetloa 1* tto chars* efficiency of tto poeltlvo plate#, very little toe toea done to aaaeore tto ctorRO efficiency of negative*. thle to of prla* irportane* to oar pragma aad a otufty of oegetlve effleleaey vlll to aad* ooacurrently dth the ealortoetrto otodtoe. pmmmmm mi i*,ip*iisfpip>ppipiww*|swww*g>w^^ L IA 1695 8 lu iiin *S It u fait Ut It would ba waluabla to low tba mm Mtarlala waad la tbla procxaa aa ara uadar atudy at tba fetal feaaareb laboratory. Slaea tbaaa ara tt^pllad by tba fegla-Flebar tavaay, Mr. Bwaratt Ktehia kindly afraid to fbntlab tba grlda aad allcqra for thla prafrm. h < ftarnlah tba (bUola|t Orlda Matal l--atlraa Poaiilvaa soft n 6*m m-t+ 8 8 8 8 0 o k 0 faatad Flataa fregatlvaa Kalllwaa laonOLnlc OrgLol? LrpaoAar" kpaaAar 88 o 88 0 80* 80 0 total A A 1* 16 It waa alao agrtad that fela-yiebar would aaalat by tba laad ylatlac taralaala to prenrlda aacaaaary corroaloo protactloa. Mota> A aactlaa on alaetrocbaalcal calorlaatry tabaa froa tba fecydo- padla of Hactrophaal rtry la attacbad to prorida a furtbar background tor thla ealorlaNtrlc atudy. - '*S9k