Document n9xyL87X5DKG6B3V1avNx9ez1

ETHYL CHLORIDE SHIPMENTS 1966 AVG- JAN PITTSBURGH PLATE GLASS COMPANY CHEMICAL DIVISION LAKE CHARLES, LOUISIANA LABORATORY PRODUCT REPORT FEB MAR APR MAY JUNE JULY AUG SEP OCT NOV DEC 1967 Avg . Color Moisture Specific Gravity Distillation Range Acidity as HCl NON-VOLATILE RESIDUE Distillation Range Ethyl Chloride apha ppm 0/4 C low C Wt. ft WT. ft High C Wt. ft 12 6 7 9 6 (5 7 5 (5 6 (5 (5 5 5 ~T~ 18 ~r~ 36 21 27 1L 9f. 32 14 11 23 22 - 0.921 n. Q9J, 0.921 0.921 0.921 0.922 0.922 0.921 0.922 0T922 0,922 0.922 Q.32L -- 12.0 I?.? 12.1 12.2 T2l] 12.1 12.2 12.2 12.2 12.2 12.3 12.3 12.2 - .00010 .00001 .00003 J00001 .00070 .0005C .00002 .00002 .00005 .00020 (.000K .00015 -- C.0003 .0002 (.0001 (.0001 (.0001 ;.oooi .0002 .0001 .0005 .0006 .0001 (.0001 .0002 -- 12.4 12.4 12.7 12.4 12.7 12.6 12.5 12.5 12.6 12.5 12.6 12.6 12.5 - 99.99 99.99 99.97 99.98 99.98 99.98 99.98 99.97 99.98 99.98 99.98 99793" : 99.9 . UJ o co ------------------- -----------4i. JL? 1 - 1 W> iwm! iTTttMflflr AT 'live-- naCr i si 1 rr . U L'Z-i. g - LOUS! fl- Ho. ai _i At; 'NFIDEl ITIATr! C..V n Prni PI'L T >J t________ /-> F 1 4 i o i r* 1 n i <tt- r i r*f Cr irT 1 n Q | 1145 - FORM NO.45A202-18- SL 012855 ETHYL CHLORIDE HCl Feed C2H4 Feed ft * REACTOR FeCl-3 FeCLj, CjH.fi.' H,0 *T. ft FPM jl966 Avg -- PITTSBURGH PLATE GLASS COMPANY CHEMICAL DIVISION LAKE CHARLES, LOUISIANA LABORATORY OPERATIONS REPORT . CONFIDENTIAL: Subject to Protective Order of 14th Judicial District Court No. 91-1145 JAN FEB MAR 99.02 99.10 99.24 98.88 APR 99.03 MAY JUNE 99.22 99.32 JULY AUG SEP _- 99.07 99.20 99.38 OCT -- 99.48 NOV -- 99.73 DEC 1967 Avg -- 99.02 99.42 99.26 0.21 0.23 0.24 0.30 0.33 0.16 0.20 0.19 0.34 0.28 0.32- 0.12 0.24 0.12 0.11 0.17 0.16 0.19 0.11 0.32 0.53 0.22 0.37 0.14 0.25 0.22 - 99.91 99.76 99.78 99.57 99.32 99.33 99.45 99.58 99.67. 99.67 99.47 99.58 99.59 _ 255 887 232 309 272 252 466 319 244 255 211 170 323 PRIMARY STRIPPER FEED CjHcfL FECLI,^ - H20 Wt. % PPM ppm BOTTOMS HCL FECL3 HjO PPH - - 38.8 99 -- 112.7 5272 145 122 22.9 157 -- 30.9 4.6 88 2A.6 120 -- -- 104.4 38.2 202.4 121.0 127 163 162 66 -84.0 70. b 72 150 - 19.1 35 26.2 50.9 16.1 58 6.5 9.0 86 9.8 7.7 5.9 55.7 42 79 3.4 80 _-- 11.9 33.8 71 83 -- -- -- 88,9 112.0 63.0 92 61 58 12.6 39.1 68 STILL OVERHEAD C2HsCl HCL H20 Wt. ft PPM PPM Still Bottoms C^H^Cl . Wt. ft -- -- 99.98 99.98 99.97 46 40 49 _-- 99.97 99.97 --- 67 "41-- 49 -- 99.98 90 99.98 99.98 99.79 99.96 - -- 68 74 53 65 -- --- 99.91 -- 44 -- 99.95 -- _J>Z_ -- SECONDARY STRIPPER PRODUCTION C2H5CL HCL FeCl3 H20 Color - Wt. ft PPM ppm PPM APHA -- - 'T2H5CL Ha VENT ANALYSIS WT, ft " - 99.99 39.99 0.1 1.1 0.7 (1.0 17 22 15------ (5 99.97 1.5 1.8 33 (5 99.98 99.98 0.1 0.3 1.2 1.2 49 28 15------- (5 99.98 0.3 0.9 29 V5 99.98 (0.1 1.1 . 49 (? 99.98 97797" (0.1 1.2 0.3 1.1 1577" 0.9 23 19 25 T5-- (5 (5 99.98 0.4 1.6 17 (5 99.96 0.1 0.4 22 (5 99.98 0.5 1.0 28 (5 - -- --- - - - - --- - -- --- -- - 1- _ - GENERAL DEPARTMENT Ethyl Chloride production EC Area Production EC Shipments TVD T/D T/D 1966 AVG - -- ETHYL PITTSBURGH Hk GLASS COMPANY CHEMICAL DIVISION LAKE CHARLES, LOUISIANA CHLORIDE DEPARTMENT OPERATIONS REPORT JAN 74.5 72.5 "32.7 FEB 99.6 98.6 106.2" MAR APR 105.6 101.1 103.0 99>9 98.5 101.8 MAY 127.9 122.6 132.2 JUNE 95.2 94.2 100.4 JULY AUG 109.2 93.8 106.4 91.4 97.4 131.0 SEP OCT 93.0 102.7 92.0 . 1*3.9 86.2 95.2 NOV 126.3 123.6 136.6 DEC Avg 134.6 105.2 136.8 103.7 97.7 101.3 HCl To EC Purity Ethylene to EC Purity T/D - *- T/D -- *- 47.4 60.2 63.3 59.9 73.4 - * 57.3 66.8 59.3 - 32.9 44.7 46.7 47.0 59.0 44.9 50.4 42.0 99.10 99.24 98.88 99.03 99.22 99.32 99.07 99.20 60.2 - 42.1 99.38 68.6 61.7 --- 47.5. 56.7 99.46 99.73 86.5 65.4 --61.2 47.9 99.42 99.26 HCl HCL Efficiency yield %-- *-- 86.4 _22.5__ 92.0 94.2 94.4 ~W7T 90.0 87.0 86.3 85.5 88.0 89.5 86.4 92.5 92.0 94.2 94.4 "92.9 90.0 87.0 86.3 ~apr 85.5 88.0 89.5 Carbon Efficiency Carbon Yield **- 96.7 95.9 95.9 92.5 91.1 "91 ."3 92.5 95.4 94.9 94. 94.9 96.2 94.3 96.7 95.9 95.9 92.5 9i.i 91.8 92.5 95.4 94.* 94.9 96. 94.3 Excess HCl Exceiss HCl T/D %- 5.0 -2.1 11.9 3.7 2.6 -1.1 -2.7 4.2 -1.9 -3.5 -0.7 1.8 -1.1 2.8 5.2 5.4 9.5" 9.9 6.9 8.1 _J_.U 3.8 11.1 11.0 9.4 5.6 HCl to EC Tons/Ton EC Prod C2H4 to EC Tons/Ton EC N2 to EC Tons/Ton EC - 0.654 0.611 0.614 0.600 0.598 0.608 0.628 X649 0.654 653' 0.573 0.642 0.625 - 0.450 0.453 0.454 0.470 0.477 0.473 0.470 3.456 0.458 0.463 0.458 0.452 0.461 -0 00 00 0 00 00 000 FeCl3 Lbs/Ton EC Steam (actual) Lbs/ton EC WELL WATER M GALLON EC KWl/ton EC - 8.4 8.6 .1177 864 8.1 8.8 500 403 8.1 577 3.2 8.4 13.9 9.3 16.1 9.1 11.3 9.4 694 42.4 to A 62J " 658 898 1532 743 -0 00 00 0 00 0 00 0 0 - 95.4 56.5 69.2 67.2 55.9 70.7 73.8 67.7 66.4 46.4 51.2 74.0 66.2 MAN HOURS/TON EC Production Maintenance _____ Salarjed__________________________________ _____ Totai________________________________________ Contract Maint. included in Above - - 0.503 0.416 0.228 0.360 _0.090 0.197 0.821 0.973 0.0 0.009 0.387 0.310 0.096 0.793 0.000 0.315 0.227 0.093 0.635 0.024 0.247 0.471 0.081 0.799 0.238 0.416 O.464 0.109 0.989 0.097 0.297 0.382 0.357 0.296 1246 0.179 0.228 0.441 0.153 0.135 0.085 O.lli, 0.102 0.097 0.076 0.561 O.OGG 0ir.7.2m4 r 0.900 JL00Q_ 0.546 0.000 0.457 0.00Q 0.264 0.344 0.136 0.278 0.066 0.100 0-468 0.722 0.000 0i031 SL 012856 --COW IAL1 Siibjt TTt txr Pi ote L'tl Vg Order -------- 0 f 141.1 "Uud i rra-1 D iateric t Colt "t------- No. 91-1145 FO 0.45A 214-2 MATERIAL BALANCE CHLORINE-- TONS Total Chlorine in Feed CulORINE IN PRODUCTION Chlorine Loss in Process Blowdown From Heavies Still Vent Loss Tar buggy Loss Unaccountable process Loss Chlorine Loading Loss Total Chlorine Loss 1966 Avg JAN ETHYL PITTSBURGH PLffTE GLASS COMPANY CHEMICAL DIVISION LAKE CHARLES, LOUISIANA CHLORIDE DEPARIIVENT 'OPERAT ION5 REPORT FEB MAR APR MAY JUNE JULY AUG SEP OCT NOV DEC 1967 1 AVG 1 -- 1/, 9ft. ft 1640.3 L907.1 1747.7 2211.1 1670.8 2012.8 1788.2 1755.2 2067.7 2382.7 2606.3 1934.9 mm 19R/, I5i6.9 175/..4 1447.7 2087.6 1552.1 Ift-p ,6 1556.0 1515. ` 1749.3 2036.9 2292.3 1729.6 194.5 123 .4 152.7 100.6 123.5 118.7 201.2 232.2 239.8 318.4 ,345.8 314.0 205.3 0 00 00 0 00 0 0 0 -0 0 _- -- ---- --- - -_ --- ---- -- --- -- - 194.5 123.4 175.4 100.6 123.5 118.7 201.2 232.2 239.8 318.4 345.6 334.0 205.3 - -34.5 -15.2 -33.6 -18.6 -90.4 -17.7 -47.5 -41.4 -16.7 -21.0 -45.6 -36.1 -35.0 - 160.0 108.2 119.1 62.0 33.1 101.0 153.7 190.8 223.1 297.4 300.2 275.9 170.3 CARBON -- TONS Total Carbon in Feed Carbon in Production Carbon Loss in Process Blowdown From heavies Still ' Vent Loss Tar Buggy Loss Unaccountable Process Loss Carbon Loading Loss Total Carbon loss - 86 5.4 1972.0 1240.1 1206.8 1552.7 1145.2 1326.6 1105.3 L082.4 1260.3 1453.6 1614.6 1243.8 - 836.4 1027.9 nftft o 1116.1 1414.7 1051.8 1227.6 1054.4 L027.0 1185.4 1360.3 1553.4 1172.0 - 28.9 44.1 51.2 90.7 138.0 93.4 99.0 50.9 55.4 75.4 73.5 61.4 71.8 -0 00 00 0 00 0 00 0 0 -- --- _-- --- -- -- -- - - -- -- ---- -- ---- -- --- - - -- 28.9 44.1 51.2 9CL.7 138.0 93.4 99.0 50.9 55.4 75.4 73.5 61.4 71.8 -23.0 -10.3 -22.7 -12.6 -61.2 -12.0 -32.2 -28.0 -11.3 -14.2 -30.9 -25.6 -23.7 * 5*9 33.8 28.5 78.1 76.8 61.4 66.8 22.9 44.3 61.2 42.6 35.6 48.1 - ct 012857 OL ^ . roi pidf.n 'I AL: Rnh" Prot ictive Ordei if T 4 l h .liifT cia 1 bistri ct Coi Et _____ 91-1145 F GW'NO. 45A 214-3 1 REACTOR 1 Pressure psi g 1--Temperature of 1966 A VG FLASHER Temperature op Bottom Top - JAN 136 125 U1 3Tft PITTSBURGH PL GLASS COMPANY CHEMICAL DIVISION LAKE CHARLES, LOUISIANA ETHYL CHLORIDE DEPARTMENT OPERATIONS REPORT FEB MAR APR MAY JUNE JULY AUG SEP 121 118 112 12ft 128----- 126 111 126 108 130 _ 115 115 125 126 123 123 146 149 151 160 170 154 141 137 144 150 156 148 163 160 156 150 OCT 107 122 157 149 NOV 104 122 i DEC m 121 1967 Avg . 112 125 171 in- m___ 159 15.9 m___ PRIMARY STRIPPER Pressure psig Temperature op Top Bottom - - 76 79 79 80 80 80 76 96 1C1 108 lift 113 113 108 141 144 147 . 147 14ft 150 148 76 76 _ 76 80 83 78 113 106 "105 100 97 106 149 145 136 133 122 m___ HEAVIES STILL .Feed Rate Reflux Steam (actual) gpm - 20.4 27.3 22.6 29.2 29.3 27.7 26.9 29.4 34.7 33.1 37.6 20 gpm - 13.0 13.9 11.6 11.0 11.4 12.4 12.4 12.3 12.1 13.4 13.7 12.4 12.5 Lbs/hr - 2614 2705 1520 1000 1662 " 1593 998 1296 1792 2899 3Q8_ 6166 2225 Temperature Top Bottom op - i/,i 146 149 148 148 147 147 147 144 144 144 144 146 - 229 227 209 225 207 200 200 181 158 20& 209 206 206 SECONDARY STRIPPER Pressure psig Temperature of Top Bottom - -- 6L 63 49-- 57 1L7 143 150 14ft 147 153 151 154 67 67 67 149 150 150 153 -J5T~ 151 67 66 149 145 150 149 66 65 138 133 149 147 68 64 129 145 153 150 SL 012858 C 3NFIDI N IlftL --"Sir 6f~ 1 >1ect till Ju to Ptl jTCTtri tect i' UlSt T--UlQ ,ii tt rI* Uo-9J *3-4-5- --