Document dQzGwYp7mmL9r4z2oqmraaBk0

0 f Q, 0 Monsanto otters you the largest assortment of plasticizers--both in number and variety--in the world. This broad line has unique advantages: you can select from Q one source the plasticizing system that offers you the optimum in processing and perforniance; you can obtain impartial technical guidance; you can take advantage of the savings in combined shipments: you can simplify your purchasing procedure. The need for a selection of plasticizers is readily apparent. In the 1930's--when Q Monsanto pioneered the technology of plasticization--performance demands were relatively mild. Plasticizing was simple because applications were few and resins fewer. In the intervening years, many new resins were commercialized, countless applications have developed, and today there are rigorous specifications and a variety of needs for ease of processing, speed of cure, and particular perform ance qualities. Confronted with the multiplicity of end-use requirements on one hand and a multitude of plasticizer and resin choice on the other--even the most experienced 0 formulator is bewildered by the maze of possibilities of from which to select the one best system for his particular application. O This catalog has been designed to serve as one tool to help you solve the often perplexing problems of what plasticizer to use. It contains complete descriptions o of the performance and processing characteristics of each of Monsanto's more than eighty plasticizers, it also includes tabulations of performance data of various o plasticizers in several end-use applications and guides to superior plasticizers to develop compounds with special performance. This catalog is not the final guide to plasticizer selection. It is primarily a guide to performance of types. However, if these data are used as a guide to plasticizer selection, Monsanto technical bulletins on individual plasticizers and on certain enduse applications will provide more complete information. Specific consultation services are offered by Monsanto's Plasticizer Council. We hope these three sources of information will be helpful to you in your manufacture of plastics products, surface coatings, and adhesives. MONS 077721 m PLASTICS Z 3 I For the Widest Choice in the s World r../'pc* ..Jjj*. .J Si- j<j_j . - .1 6* M. l i r" . f * !> -tmm 1 i? : .* - i . ,~ . *1' l ' ad^ * 'i .----*" I. * - >. - V': ? . r j , ' 7 Wt '`Z' t * ->' ! ;r ^"1- A- < >.J t ' ! ' .* 1 ` H -T ,i ' .'S'*' r I. ..p , tkiJ' ; j .- _ L> . 7-sj U1 V--1 i, A' " ' I Jr k I I Th following art trademarks of Monsanto Company, registered In the U.S. Patent Office; Aroclor, Gelva, \todaftow, HB-40, Mod-Epox, Montar. Option, Phosgard, Senticizer, Santolite. o HONS 077722 o o o  0 o 0 0 0 0 Q O ten bulk station distribution points ll/page 2 0 To give rapid delivery and multi-product shipments, Monsanto maintains bulk station inventories at strategic industrial centers along the east coast, the south and southwest, the midwest and the west coast. These bulk stations are another customer service that enables plasticizer users to save money in the following ways: Lowest cost/!b. With Monsanto's distribution, com trucks. Multi-product combined shipments from pounders can reduce their materials costs by pur *bulk stations can also reduce in-plant inventory chasing in tank cars direct from the producing costs. plant or by ordering tank truck shipments from the nearest bulk storage station. Bulk prices are about 10% lower than car- and truck-lot drum prices. Mixed Car-and Truck-lot Shipments By offering such a full line of plasticizers, Monsanto can load out mixed drum orders in a single car or truck. This Conservation of plant storage space Since the gives the buyer the cost economy of full carriers. Monsanto bulk stations are strategically located dose to major manufacturing centers, minimum plasticizer storage space is needed. Supplies are available in most areas for fast, short-haul delivery. Ordering, invoicing simplified With this efficient distribution system, compounders can make ad ditional savings by fewer shipments, fewer orders, and reduced paper work in clerical handling of invoices. Compartmented shipments With such a broad line of plasticisers, compounders can take the savings of Monsanto is always ready to work with customers bulk purchasing by ordering as many as three to establish and maintain convenient bulk station different plasticisers in a single order. The different distribution centers wherever volume justifies a plasticizers are shipped in compartmented tank mutually convenient storage station. MCNS 077223 0 %3 0 Q jjspecifications and physical characteristics LaKUET^ hhpiU-rM1*M1i mJ of Monsanto plasticizers Monsanto plasticizers comprise both liquids and solids representing a variety of distinct chemical types, including phthalat estars adipate esters permanent plasticizers glycollates sulfonamides phosphate esters aroclor* plasticizers ... plus a variety of "specialty" compounds and extenders. Each of these, in themselves, but primarily in combination offer special processing or end product quality advantages in particular applications. Specific plasticizers and specially researched combinations have been developed for formulation of plastisols for slush molding, fabric and paper coating; for adhesives and surface coat ings; for extrusions both profile and crons section; for floor tile; and for cast or cal endered free Him. o G O o o o o o 0 o Tin Mowing pages describe physical properties of the various plasticizers of choico available from Monsanto; MOMS 077724 o o 0 piocessing specialty color improver for alkyd resins > m. : ' 9w B General Description ' I 1 I] .11,,Jimm*.W'1' . I It/page 54 r| i I [11'4 J i1 j m 9 o 9 0 Q o o Triphenyl phcwphite is widely used as a stabi liser in polyvinyl chloride compositions. It serves a dual {unction: (a) When cadmium compounds are part of the composition, triphenyl phosphite solu bilises and removes the haze developed by the cad mium chloride formation; (b) When chlorine ions are split from polyvinyl chloride, double-bonds sus ceptible to oxygen-darkening are left behind on the polymer; triphenyl phosphite acts ss an antioxi dant end contributes to better light stability. [This function, also valuable in other resins, is covered by U. 3. Patents 2,572,571 (Monsanto) and 2,564,646 (Argua Chemical Company) ]. In alkyd retint, triphenyl phosphite improves the color of the resins which tend to oxidize at the 406-540'F. processing temperatures due to presence of free peroxides or iron soluble salts. If calcium . hydroxide is used as an alcoholysis catalyst, the presence of triphenyl phosphite will improve the Inlshed resin's clarity by solubilizing the calcium pbthalate precipitate which forms. In polyester res,P> manufacture, small amounts of triphenyt phosphite reduce the reaction time and improve the renin's color. The seme color improvement is obtainable in the manufacture of bodied oils made by the treatment of soya, linseed, and tall oils with maleic anhydride or fumaric acid. In phenolic resin manufacture, triphenyl phosphite promotes the formation of permanently light colored liquid pheno) formaldehyde compositions (U. S. Patent 2,616,(76, Monsanto Co.). p Properties Chemical formula' ,^~Qj ^ Molecular weight 310.28 Appearance Oily liquid or fight ycMow solid > Neutralization number 0.08 mg. KOH/gm. max. Color APHA 50 max. 1 Hydrolyzable chlorine 0.010% max. Free phono! 0.5% max. 1 Refractive index @ 25'C. 1.5875- 1.5900 f Specific gravity 30*/I5.5`C. 1.176 to 1.J82 [1 weight per gallon @ 25*C. 9.83 lb. jJ j Boiling point, 760 mm Hg > Crystallizing point |j { Flash point (C.O C.) 360*C. 25'C. 375'F. ; | Fire point (C.O.C.) 525'F. ! Vapor pressure @ 220*C. 11 mm Hg Viscosity @ 25'C. . 17.5 cks , Solubility in water ( 25'C. Hygroscopic 1 General solubility Soluble in common solvents ` ; jj | * Specifications t Triphenyl phosphite Is considered only slightly toxic from the standpoint of oral ingestion and is not readily absorbed in lethal doses through the unbroken skin. Repeated or prolonged skin contact ih+ttld be avoided, however,-to prevent skin irrita tion. The material may cause irritation if there is accidental contact with eye tissues but no perma nent damage should result. Prompt flushing of the ye#with water will reduce the degree of irritation. In laboratory studies, no deaths occurred among rats exposed for six hours to a saturated atmos phere of atomized triphenyl phosphite. i f t l [J HONS Off725 9 HONS 077726 o ,) 4JMCI0/? PLASTICIZERS AND RESIN EXTENDERS 1 O O' o o 0 o 0 0 0 The Aroclor polychlorinated polyphenyls range in farm and appearance from mobile oily liquids to fine white crystals and hard yellow transparent nnrina. The Aroclor products are useful as low-cost, efficient plasticizers and resin extenders fa vinyls, eeUulosict and rubber material*. The Aroclor com pounds are compatible with most of the common plastic resins and numerous special resins. These permanently thermoplastic materials are non-oxidizing; non-corrosive to metals; and not hydrolyzable by. water, alkalies, or acids. They pea--as excellent electrical properties. The viscous liquids and resins will not support combustion when heated alone. The flexibility they impart to rtoto* increases with the mobility of the particular Aroclor compound, while the degree of hardness imparted increases with the viscosity of the Aroclor selected. fn adhesives and surface coatings, the Aroclors im port outstanding adhesive qualities, good resistance to water and chemical action, and resistance to bacteria and fungi attack. fn vinyl resins, the Aroclors are used mainly as co-plasticixers with tricresyl phosphate, dioctyl phibalateand others. Theyimpartplastlcizingaction, chemical and corrosion resistance, flame resistance and reduced migration to nitrocellulose lacquers. itsed with dioetyt phthalate and Santicizcr 141, the Aroclors are efficient co-plasticizers for vinyl or ganosols, plasli&oh v pastes for free films, and textile and paper coatings. In these applications, the Aroclors impart valuable fire resistance and serve as excellent grinding and dispersing media for pigments. In polyvinyl acetate, the liquid Aroclor compounds make excellent low-cost, quick-tack adhesives. The more viscous and solid Aroclor compounds are widely used in hot-melt adhesives, The Aroclors are highly compatible with ethyl cel lulose. The liquids impart great flexibility and the resins impart great hardness. Aroclor M60 con tributes high gloss and exceptional weathering qualities to coatings for rigid surfaces. fn cellulose acclatt-bntyrate, the Aroclor com pounds are useful in making flame-resistant, lowcoat formulations for applications such as paper coatings, lacquers. And strippsble coatings. In nitrocellulose, the Aroclors function both as plasticizers and resins. They may be used alone? or with other plasticizers and resins to impart weather resistance, luster, adhesion, and decreased burning rate. Because of their excellent electrical character istics (high dielectric strength and resistivity and low power factor) and their property of retarding the passage of moisture and gases through nitro cellulose, chlorinated rubber, and other similar plastics films, they are especially useful in coatings for electrical insulating materials. In chlorinated rubber ('Parian) and copolymers of styrene-butadiene fPlfolltc S~5), Aroclor 1254 is an excellent plasticizer; and Aroclor 5460 acts as a Aim fortifier in protective and decorative coatings fa concrete and masonry structures, steel struc tures, railway tank and gondola cars, wood, and metal maritime equipment. Aroclor in these types of coatings imparts excellent resistance to flame, corrosion, acids, alkalies, and water; as well as good electrical insulating properties. The Aroclors are most useful in natural and syn thetic rubber*. The liquid Aroclors 1221, 1232, 1242 and 1248 provide a strong plasticizing action. Small amounts of Aroclor 1260 plasticize hard rubber and reduce brittleness. Milled into rubber. Aroclor 1254 and 1260 impart permanent tackiness and adhesion. As a plasticizer fa crepe-rubber resin (formulated into paints), Aroclor 1262 increases the gloss and 1 alkali resistance of the film and its adhesiveness toward steel. Aroclor 1268 has excellent working qualities at 225-325F. as a plasticizer in injection moldings. Ground into powder and milled into rub ber at a temperature below its melting point, Aroclor 1268 can be dispersed through the rubber and acta aa an efficient flame retardant. in epoxy resin coatings, the Aroclor compounds with their excellent chemical resistance, oxidation resistance, and adhesion enable the formulator to reduce costs without detracting from the saleable features of the epoxy resins. In plastic applications, a combination of an Aroclor compound plus anti mony oxide make low-cost non-burning formula tions. The Aroclor compounds are also useful with phenolic resins, polyester resins, polyisobutyiene, waxes, and rosin. i MOMS 077723 [ rmwwn i uwiivufcn^ (wmuiuBu; At ordinary temperatures, the Arcelor chlorinated pOlyphcnyls have not presented industrial toxi cological problems.-When Aroclor compounds are used at elevated temperatures, engineering con trols must be applied, either by the use of closed systems or by effective local-exhaust ventilation to gether with general workroom exhaust. The threshold limits (maximum allowable concen tration for an 8-hour working day) act by the American Conference of Government Hygienists are 1.0 milligram of the lower-chlorinated Aroclor compounds per cubic meter of air and 0.5 milligram of the more-highly-chlorinated compounds, such as Aroclor 1254, per cubic meter of air. In akin patch tests, neither Aroclor 1254 alone or in a polyvinyl cloride film (H.5 per cent Aroclor) nor Aroclor 5480 In an alkyd resin coating (17 per cent Aroclor) on canvas irritated or sensitized the skin. Continuous or repeated skin contact with the Aroclor compounds must be avoided because of the possible occurrence of chloracne. toparties Aroclor 1248 Clear, mobile oil - Acidity 0.010 mg. KOH/gtn. max. Color Moisture APHA 100 ma*. 50 ppm max. Attractive index @ 20*C. 1.630 to 1.631 Specific grsvity 65'/l5.5*C< 1.405 to 1.415 Weight per gallon 25'C. Boiling point 760 mm Hg 12.04 lb. 340to375*C. ' POW point, (ASTM M7J --7*0. Rush point tC.OCJ 379 to 3M*F. Fire Point (C.O.C.) None to boiling point Viscosity 37.1*0. S4.4*C.* 98.9'C 18S to 240 SUS 73 to 10 SUS 36 to 37 SUS Specifications j Aroclor 1221 Appeeiance Acidity Color Refractive index @ 20*C. Specific gravity 25'715.5'C. Chlorine, % Weight per gallon @ 25 "C. Boiling point. 760 mm Hg Pour point {ASTM D-97) Flash point (C.O.C.) Fire point (C.O.C.) Viscosity 37.8 *C.* 54.4*C. 98.9*C. Clear, mobile oil 04)14 mg. KOH/gm. max. APHA 100 max. 1.617 to 1.618 1182 to 1.192 21.0 * 0.5 9.85 lbs. 275-320*0. Crystals at 1'C. 286-302* F. 349`F. 38 to 41 SUS 35 to 37 SUS 30 to 31 SUS ^Specifications o Q O o o o -a Properties Aroclor 1254 Appearance Acidity Color Moisture Refractive index @ 2G*C. Specific gravity 65*/15.5*C. Weight psr gallon @ 25*CBoiling point, 760 mm Hg Pour point. (ASTM 0*97} Flash point (C.O.C.) Fire point (C.O.C.) Viscosity ( 378*C. 54.4*C. 98.9*C. Light-yellow viscous liquid 0.010 mg. KOH/gm. max. APHA 100 max. 50 ppm max. 1.639 to 1.641 1.495 to 1.505 12.82 lb 365 to 390*C. 1Q*C. Nona to boiling point None to boiling point 1800 to 2500 SUS ?60 to 340 SUS 44 to 48 SUS Specifications] o o o o MGNS C77728 o o o iii/imtx m 0 o, Aroclor 1232 0 0 > o Appearance Acuity Color Refractive index @ 20`C. Specific gravity 25*/ll$'CChlorine, % Weight per gallon @ 25'C. Boding point, 769 mm Mg Pour point tASTMlW FfMlr point {C.O.C.J Fire point (C.O.C.) Vtacoarty @ 374'C.* 54.4'C. 9*9'C. Clear, mobile oil 0 014 mg. KOH gm. max. APHA 100 max. 1.620-1.622 UTOtoUtt 32.0 05 1055 m. 290 to 325*C. -355'C. 305-310'F. 460*F. 44 to 51 SUS 39 to 41 SUS 31 to 32 SUS [ ,8p*tWcfen| Properties Aroclor. 1242 n * Appearance H * Acidity K ' Color Pi Moisture ^ Refractive index @ 2Q*C. tj Specific gravity 25`,'15.5`C. f, Weight per gallon @ 25'C. Boiling point, 760 mm Mg ij Pour point (ASTM D-97) H Flash point (C-O.C.) H Fire point (C.O C.) C] Viscosity @ 37.8`C. O 54.4*C. fj 98.9'C. Clear, mobile oil .015 mg. KOH/gm. max. APHA 100 max. 50 ppm max. 1.627-1.629 1.381 to 1.392 U.5Q 10. 325 to 3G6'C. -- 19'C. 348 to 356`F. None to boiling point 82 to 92 SUS 49 to 56 SUS 34 to 35 SUS | ^Spaciificatiooa j 0 Aroclor 1260 0 0 1 * I 1 I ' Appiatence xlitity Cater Mate*** ftaftaettva index 20*C. Sawsifk gravity 90*/ 153*C. Weight per gallon $ 25'C. Bq4HH point. 790 mm Hg Pour point (ASTM 0-97) Flash point tc.O.C.) Ffrt point (C.G.CI Vtesutty 544*C. 99l9*C* , Ughtyehow, soft, sticky rssin 0.014 mg. KOH/gm. max. APHA 150 max. SO ppm max. 1.647 to 1-649 1.S55 to t$66 U50 lb. 305 to 420'C. 31-C. Nona to boiling point Nona to boiling paint 3200 to 4500 SUS 72 to 7t SUS \ `Specifications) Propartia* Aroclor 1262 * Appearance Ught-yellow, sticky viscous rsm Acidity 0.014 mg. KOH/gm. max. Color APHA 150 max. Qhlorina, % 61.5 to 625 Retractive index @ 20*C. 1.6501 to 1.6517 * Specific gravity 90*/15.5'C. 1.572 to 1.563 Weight per gallon <> 25'C. 13.72 lb. Boiling paint, 760 mm Hg 390 to 425'C. Pour point 35 to 3S*C. Flash point (C.Q.C.) None to boiling point Fire point (C.O.C.) None to boiling point Viscosity @ 71.0'C. 98.9'C.* 600 to 850 SUS 86 to 100 SUS ("Specifications | HONS 077729 jNCWUif rutbitvufcfc* (conitflitca; Properties Aroclor 1268 Appeerance ' Midlty Color (molten) Specific gravity 25*/23*C, Weight per gallon 25*C. Boiling point, 760 mm Hg Softening point (ASTM E-28) flMH point (C.O.C) Fite point (C.O.C.) Whit* to off-white powder 0.05 mg. KOH/gm. max. 1.5 NPA 1J0? 15XW lb. 435 to 450'C. 150 to 170*0. Non* to boiling point None to trailing point f*Sgecification> | rnwwOM Aroclor 5442 Appearance Acuity Color (molttfl) Spociflc gravity 25*f25*C. Weight per gallon ?5*C. Softening point (ASTM E2S-51T) Bplliftt paint, 4 mm Hg Pgur point, (ASTM 0*97) Flnh point (C.O.C.) Fife point (C.O.C.1 Viscosity 98.9*0. Clear, yellow, sticky resin 0,05 mg. KOH/gm. max. 2 NPA max. 1.470 1124 lb. 46 to 52*0. 215 to 300*C. 46*C. 477-F. >662*F. 300 to 400 SUS 1 Specifications | Properties Aroclor 4465 Appearance Acidity Color (molten) Refractive index @ 20*C Specific gravity 25*/25*CWeight per gallon 25*C. Soiling point. 4 mm Hg Softening point (ASTM E2S-51T) Flash point (C.G.C.) Fire point (C.O.C.) Viscosity @ 130`C. Clear, ligin-yellow re<n 0.05 mg. KOH/gm. max. 2 NPA max. 1.664 to 1.667 1.670 13.91 lb. 230 to 320*C. 60 to 66 *C. None to boiling point Nona to boiling point 90 to 150 SUS Specifications 1 Propartlu 5460 Appearance * Acidity Color (molten) Refractive index @ 20*C. Specific gravity 25*/25*C. Chlorine, % Weight per gallon @ 25*C. Boiling point, 5 mm Hg Softening point (ASTM E28-51T) Flash point (C.O.C.) Fire point (C.O.C.) Clear, yellow to amber. brittle resin or Hakes 0.05 mg. KOH/gm. max. 2 NPA max. 1.660 to 1.665 1.67Q 59.5 13.91 2*0 to 335*C. 98 to 105*C. None to boiling point None to boiling point | 'Specifications | m *1 a m o o o o o o a o o o m 0 MONS 077730 o 0 '.Him -MmE -3 o Q Summary of Specifications and Typical Proparties For your convenience the following chart lista Monsanto's Permanent, O Sulfonamide, and Miacellaneous plasticizers. If a specific property is ideally auited for a specific application simply find the optimum value oi that property in the vortical column, the name of the plasticizer offering this value may be reed from the left hand listing. ; o MGNS 077731 > MON K R *'X tK T AM1DS Sentieizer 401 SafttlcUar 406 Santlcizer 409 ' $antici*er 4U Santlcizer 482 SntlciwW> Senticixer 401 Sentidzer 482 Santicirer 483 ! 1 Santlciztf 1-H ; Santicizer 3 Santlcixarl Santicizer 9 Santolite MHP $*ntolit MM0% 1 j ` Aroclor 1221 , Aroclor 1232 " Arodor 1242 Aroclor 1243 Aroclor 1254 Aroclor 1260 Aroclor 1262 . Aroclor 1268 , Aroclor 4465 1 Aroclor 5442 ` Aroclor 5460 .i-WUM,. 1-0 - to - *u - to -- * 0-24 - * dfiO - 085 - *U - * 0J4 * Claar. viscous liquid * Clear, oily liquid * Clear liquid * light yellow, viscous liquid soma solids on standing * Clear, oily liquid * Clear, oily liquid * Clear, oily liquid Clear oily liquid * Clear, oily liquid * 250 (50ml.! 50ml.) 95% Ethanol * 200 (50ml.: 50ml.) 95% Ethanol 150 (50ml.i 50ml.) 95% Ethanol 175 (50ml: 50ml) 95% Ethanol 150 200 300 325 125 * (US MS * (US ais * 0.13 *(US * (US * ais * 0.13 ?iivi IW-23 199-22 17U - - * 1.60 * QJO pH 4JJ (min.) to (mg KOH/g) - * Yellow-brown /used mass 300 (molten) * Practically whits solid 60 (molten) . * light-yellow, viscous liquid - 200 (molten) * Fine* white to light-cream granular particles 85 (33-1/3 wt% in acetone) ' Hint, practicin' caloric, r,,in * 50 (2Sg:7Sg butyl acetate) * Light-colored, viscous liquid. Free flowing above 20*C * 80 (25g:35g butyl acetate) * ais * 0JB * LO ' - - * .014 . (mg KOH/g) Clear, mobile oil - * 014 Jgi*QHfrL Clear, mobile oil - * 015 (mg KOH/g) * Clear, mobile oil - 010 (mg KOH/g) * Clear, mobile oil - 0.10 (mg KOH/g) light-yellow viscous liquid - * 0.14 (mg KOH/g) * light-yellow, soft, sticky resin - * 014 Light-yellow, sticky, (mg KOH/g) viscous resin _ * .05 (mg KOH/g) * White to off-white powder - 0.5 (mg KOH/g) * Clear, light-yellow resin *- * .05 -(myKOH/g) Clear, yellow, sticky resin - *-05 (mg KOH/g) Clear, yellow-to-amber brittle resin or flakes * 100 * 100 * 100 * 100 100 - 150 ` 150 * 1.5 NPA (molten) 2 NPA mas. (molten) * 2 NPA mas. (molten) * 2 NPA max. (molten) - * 38 (ppm 50 (ppm * (ooir 50 (ppm - - - - ' HB-40 ! Mod-Epo* 1 Photgard C-22-R > Triphenyl Phosphite i - 610.5 310.28 - *0.08 (mg KOH/g) '50 * 0.8 (mq. KOHa) Cloar, oily liquid * Oily liquid or fight-yellow solid * Clear, viscous liquid * Oily liquid or light-yeilow solid 100 50 * 50 * 50 MOMS 077732 123 g '- - 0rrtER MONSANTO PtASTICIZl `y 14 CMr, viscous liquid ' Ctaur, ally liquid li * Clear liquid I.0 * Light yellow, viscous liquid tom solids on standing UN * CImt. oily liquid 040 Cltsr, oily liquid 0M * Clear, oily liquid U deer oily liquid X* * Claw. oily liquid * 290 Mtoli MmU 98% Ethanol " 200 MnU SOmU 95% Cthenol * ISO $0mU 95% Cthenol * 175 (90tnh 50AM 95% ethanol * 150 * 200 * 300 * 325 * 125 * 0.15 * 015 * 0.15 * 0.15 * 0.15 0.15 ' 0.15 * 0.15 * 013 * Characteristic * Very slight, characteristic 1.470 1.478 Very faint, ester * Slight, characteristic 1.4854 1.4772 Characteristic Slight, characteristic 1.508 to 1510 1.4943 Slight, characteristic 1.4795 Slight, characteristic 1.4751 Slight, characteristic 15015 to 1.5050 ~9 ^ ~w 9 - * Yellow brown fitted men * 300 (molten) U * ftpcltcplly whits solid 4 60 (molten) m lu nlnJ It tHQH/M * UghbyeUow, viscous liquid * 200 (molten) * Hr* white to light-creem arenulsr particles * Hard, precttartty colarloss rosin * UfW-colorod, viscous liquid. Frep Aawind show ffl-C * t5 (33-1/3 wt % in acetone) * SO (2Sf;75g butyl acetate) * C25gx33* butyl acetate) * 0.15 * 0,25 * L0 - _ * Slight characteristic essentially none Faint formaldehyde - Clear, mobile oil deer, mobile oil * Deer, mobile oil 0.U 'U4 K0H/g| Jti *KOH/d l&OHM * Clear, mobile oil light*?allow viscous liquid * UiM-ysllow. soft, sticky resin ' U(hl-yollow. sticky, vieoeus resin * Whits to off-whits powdar illjOH/l) * Cteer, light-yellow mein * Cltsr. yollow, sticky resin * Clear, yeHaartoember brittle retin or Hakes * 100 100 * 100 100 * 100 * 150 150 * 14 NPA (moltan) 2 NPA mate (molten) * 2 NPA max. (molten) * 2 NPA max. (molten) - * SO toom max.) *50 town max.) * 50 (oom max.) *50* (ppm max.) - - - - - -. -- - _ ROH/ll A tt INOHD Claw, oily liquid * Oily liquid or light-yellow eoiid * dear, viscous liquid * Oily liquid or light-yellow solid * 100 * 50 * SO * 50 * IS ppm - Faint characteristic - Essentially none - 1512 to 1532 (85*0 ar 1540 U427S to 1.4325 (23gi75g butyl acetate) ar A -- 1.817 to 1.611 (20*0 1.620 to 1522 (20*0 1527 to 1529 (20`C) A 1.630 to 1531 (20*0 1.639 to 1.641 (20*0 1.647 to 1649 (20*0 A 6 1.6501 to U517 (20*0 - 1.664 to 1.687 (20*0 - 1.660 to 1465 (20*0 1.5600 to 15750 * 1587 to 1590 * 1492 to 1.494 0 9 _ w * 1.5875 to 1.5900 MONS 077733 9 Summary of Specifications and Typical Property* c .-<f'rV. - :c-ja*t*.*. . - U24 to 1.132 941 - LI -H***f . S-/T -- ~>r a-,, 10600 to 13504 *UB 19 13*1 9.08 - +.16 - - -- 8800 to 9504 * LOtttoLOM r * 1,104 to 1.110 ^ * i.072 \art * 1-019 to 1XM6 9.01 9.20 1.95 172 - 4 4-21.1 --21 -1 - - -- - - -- - - -- _ _ -- - 290flto 3504 - 9000 to 9400 - 291 - 556 * 1.072 to 1.071 9.96 - 10 - - -- - 3878 * UK to 1.103 * IMS to 1452 U 9.16 174 - 14 -31 - - .- - - - - -- - 6422 156 ./*k. u 1.125 U66 to U76 flV65*C> U9D 1JU faoMd) 1J9 U96 .A * 1.IMMU92 11 u;tou 'rT3UlpUK 0 f MW to U15 Haviwc) MM to 1,905 W/WCI # * iJU im wnuti 1 tat to tan (W/15J'C) IJKt # U79 1479 im _ 9J2 105 (in vacuum joefcat) * 825 min. * 515 min. <0 105 62 - 340 - 350 340 360 (approx.) 0.8 (160*0 0.45 0.25 - '- 915 1055 1150 1254 1252 U50 13.72 1559 1191 12.24 1191 -* - - Cryitaoai'C (ASTMD-$7> 275 to 320 -35 (ASTM D-97) 290 to 325 -19 (ASTM 0-97) 323 to 366 -7 (ASTM 0-97) 340 to 375 10 (ASTM 0-97) 365'to 390 31 (ASTM 0-97) 345 to <20 35 to 34 390 to <25 - 435 to 450 - 230 to 320 (4 mm. HD - 215 to 300 (4 mm. Hg) - 240 to 335 5 mm. HD - 55 12 - - --- 10.000 ---- 3544 - - * 34 to 41 SUS (178*0 35 to 37 SUf (54.4*Ci - * 44 to 51 SUS (378*0 39 to 41 SUS (544*Ci - 82 to 92 SUS (374*0 49 to 56 SUS (544*3 - 185 to 240 SUS (37.8*0 73 to 80 SUS *(5U'Q - 1400 to 250) SUS 280 to 340 SU' (374*0 (54.4*C - - 3200 to 4500 SL (54.4'< - - 600 to ISO SU (71.0*C -- - -- - -- - -- - UQJtoUW Wtm-Q # * U7I io UK 00^115*0 1.4 to 1.445 w * 1.17 to 1.182 CK*/155*0 in A 137 9.43 U.9 953 25 ftona-flMsy 25 -26 5 345 to 396 2 360 ' - Not DistMlabla - 360 - IS 11 (22Q'C) - 11 (220*0 230 - 70.0 - 294 <37J*C 174 MONS 077734 {v^'iSSI t^r-rr-..............h l .riWvfcVs^ 301 13500 tAto n - goto 3500 - to 9800 m - - m- ; 3871 - 848? - m- - - - - .J?" - 0.00071 - - 555 S35 530 540 - 475 485 525 485 Specification f .-* ' j0:-s.-..-y9a$.., .ig?-"" ' -fcp-' ...... .*** 1 - _ - Practically insoluble - - ' - . Practically insoluble 570 - --535 535 580 - 525 ' - - Practically insoluble - Practically insoluble - Practically insoluble - Practically insoluble - Practically insoluble - Practically insoluble - Practically insoluble -- MO - '- - -- -- 6.0 44.5 (25*0 - - -- - -- - -- -- - 371 - - 345 - - 420 - . - - - - -- - ttoVOui . turn.. fSllua *ijiBUg 38 to 31 SUS 31 to 32 SUS 34 to 35 SUS * 3 to 37 SUS J53 i to 48 SUS m 40oo sos (3*a * 72 to 78 SUS w * 86 to 100 SUS - - 90 to 150 SUS (U0*C) - 300 to 400 SUS -- - 0410071 U5-40-C) 0.00073 {25-100*0 0.00068 12-65*0 0.00070 (2S6$*0 0.00066 (25-65*0 04)0067 {20*100*0 0.00064 (25-65"O 0.00067 (30-100*0 000061 (2540*0 D.Q01Z3 UW*C) 04)0179 (25-125*0 286 to 302 305 to 310 348 to 356 379 to 384 None to baling point * None to boiling point None to boiling point None to boiling point None to boiling BOinf 477 Non# to boiling point 349 460 None to boiling point None to boiling point None ta boiling point * None to boiling point None to boiling point None to boiling point None to bolilng point >662 None to boiling point - - 04)0045 (30*0 - Slight - 0.13 (23*C) - 1(34*0 - Practically insoluble - Nil - Practically insoluble - Practically insoluble - Practically insoluble - Practically insoluble - Practically insoluble - Practically insoluble - Practically insoluble - Practically insoluble - Practically insoluble - Practically insoluble - Practically insoluble 0M (37.1*0 ii -_ * to to 60 17J - 40.1 (25*0 - - 345 385 - - - 375 525 - - Hygroscopic No seif supporting combustion - - Nil 375 525 - - Hygroscopic HONS 077735 o # o. Q O & 0 i if/i 1 i with DOP V. with DOA wifli SANTICIZER 141 o Fire retardant plastics materials are growing in favor in many end uses. Recent Underwriters Laboratories' rulings on air conditioners, the California fire laws on plastics film, and the specifications of end-product Q users mark a trend toward greater safety consciousness. This awareness for possible dangers will increasingly put a limit upon the flammability of materials of manufacture, construction, and decoration. Monsanto supplies a variety of plasticizers which provide molecular structures with tightly linked chlorine and phosphorus, to impart fire Q resistance to compositions containing them. These plasticizers represent a range of properties, in addition to the imparting of fire resistance, that make them efficient plasticizers for a variety of resins for uses in a large number of diverse applications. These plasticizers offer a choice of price and compatibilities; many offer outstanding chemical resistance, extraction resistance, and good permanence. By selecting a one, two, or three component plasticizer system based on these products, the formulator can develop fire-resistant compositions using a number of resins, offer a variety of end product characteristics, in a range of costs. HOMS 077738 luuHMVAitDMfr mawmmThe following are liquid and (olid fire-retardant modiHer*: TRICRESYL PHOSPHATE Tricreayl phosphate is a standard flame retarding liquid plasticizer for polyvinyl chloride, cellulose (excepting acetate), and synthetic rubber. It has low volatility and offers good permanence; it is especially recommended for electrical insulation applications. It is also compatible with phenolic*, impart* a degree of flexibility to phenolic electrical laminates. TRIPHENYL PHOSPHATE Triphenyl phosphate fa a solid plasticizer, particularly suited for producing flame retardant celluiosic compositions and coatings. It may also be used with synthetic rubber and with a variety of vinyl resins in conjunction with a solvating type plasticizer. iLaHtflE* iir.wifcliai SANTICIZER 140 Santiciicr 140 in * phosphate type liquid plaaticizer. It makes an excellent general purpoee plaaticizer ea wall aa a meant of making flame resistant products. On a pound tor pound bails it is more efficient than tricreayl phosphate in vinyl reains and imparts a superior flexibility. SANTICIZER 141 Santicizer 141 is a liquid, phosphate-type general purpose plasticizer which is non-toxic. It imparts good low temperature flexibility, has low odor and improves the processing characteristics of most formulations because of Its excellent resin solvating power. (BhaeMedsifri" rffiKSlnlir Shi^yhiiNK r' 4lihM AROCLOR PLASTICIZERS MONTAR PLASTICIZERS The Aroclor polychlorinated biphenyls' end terphenyis are particularly effective in reducing flameout time and the glow termed "punking." The Aroclor compounds are compatible in varying degrees with vinyls, celluiosic*. rubbers, polyethylene, and epoxies. M These polychlorinated poiyphenyU are similar to Aroclovs except for their dark color and lower cost. Although slightly compatible with vinyls (for use as tow-cost, extender plasticizers where color can be tolerated), they are especially effective in asphalt, to which they impart instant flameout when present in concentrations of 25 to 30 per cent ?3SBg PHOSGARO C-22-R Phosgard C-22-R is a flame-retardant organophosphorus polymer for urethane foams, polymethylmethacrylate, phenolics, polyester resins and epoxies with optimum performance properties: high efficiency through high phosphorus and chlorine content, essentially non*volatile for lasting flame-retardant service life, excellent color stability on U V and heat exposure, easy formulating and non-compHcated handling, long storage stability ("per se" or in formulation), and good hydro lytic stability. MGNS 07773* V -% i 6 C c a * $ a a a a a o SOLID PLASTICIZERS Solid plasticizers perform unusual functions in adhesives, coatings and lacquars, foams, rigid compositions and dims. Many times solid plasticisers are overlooked in solving processing problems or in obtaining unique product properties. A solid plasticiser often transforms a deficient product Into a completely different, high performance product. HOT PROCESSING Solid plasticizers offer processing advantages in hot processing applications. For example, in Banbury mixing, a solid plasticizer will melt at or below the processing temperature and function as a solvating or fluxing liquid; the lowered viscosity of the Banbury charge improves the flow resulting in faster and easier processing. Upon cooling, the plasticizer returns to a solid form producing a rigid or semi-rigid film or molded product. The solid plasticizer thus reduces processing costs as well as imparting unique properties to the finished product. SOLVENT PROCESSING Certain solid plasticizers enable successful formulation of higher solids content In lacquers. This means fewer coats to build a surface and, there fore, reduced application costs. As the lacquer dries, the presence of the solid plasticizer helps reduce blushing, sweating and separation. HQhS C7JM0 SQUD PLASTICIZERS (continued} Description of Monsanto Solid Plasticizers Plasticizer Description *I i ] Melting Point or i | Softening Range CC) Aroclor 5442 Triphenyl Phosphate Montar 1 i1 \ clear, yellow resin white flakes black rasin < i Malting Point !: f ------- ------------------ 48.5 [ Softening Range 46 to 52 54 to 160 SantJcizer 3 Aroclor 4465 Sentolite MHP practically white solid dear, yellow resin herd, color!ass resin j . . 1. * t f 58 62 60 to 66 CHcyclohexyl Phthalate Diphenyl PMhalate Montar 2 Santicizer 1-H white solid i- white solid black resin yellow mass | 63 j 69 i | | 82.5 70 to 170 Montar 3 Montar 4 black solid j brown solid | | 86 to 168 92 to 206 Aroclor 5460 yellow-to-amber resin Santicizer 9 white particles Montar 9 Aroclor 1268 : Montar 5 . ................ . L. brown solid white flakes brown solid . | j: j |. i f t j 105 98 to 105 130 to 175 150 to 170 155 to 1% MOMS 077741 I < C C C e c c @ c G m/ptfO FOR ADHESIVES ... unusual properties Deiayed-tack and heat-seal adhesives owe their existence to solid plasticizers, because It is the solid plasticizer that makes deiayed-tack and heat sealing possible. Deiayed-tack adhesives are activated by heat, and ones activated, remain tacky long enough to permit handling before the adhesive cools and sets. The sharp melting point of solid plasticizers provides a sharp activa tion point for the adhesive. This activation temperature varies with different solid plasticizers, and special adhesives can he easily formulated to fit handling methods by selecting the proper solid plasticizer, Deiayed-tack adhesives are covered by several U.S. Patents. D F<>R FILMS ... no blocking Solid plaaticizers can be used with other primary plasticizers to produce tough, clear films that feel dry and separate easily. Liquid plasticizers used alone often cause blocking due to a slight surface tackiness. Solid plasticizers also add resilience to films and impart exceptional resist ance to extraction by kerosene, oils and grease. FOR RIGID PRODUCTS ... easier processing Processing of rigid vinyl products can be made easier by using solid plaaticizers . . . without changing present equipment or methods. With heating, the eolid melts and acts as a solvating liquid plasticiser for the refin. Upon cooling, the article becomes rigid because the plasticiz ing effect of the solid plasticizer is slight at room temperature. Used strictly as a processing aid, the solid plasticiser pays its own way by lowering processing costs. FOR HEAT-SEAL COATINGS ... sharp activation temparature Lika adhesives, heat-seal coatings require the sharp melting points of solid plasticizers to give them the heat-seal property. By themselves, liquid plasticizers cannot endow coatings with a sharp activation temperature. Instead, the coatings tend to block and be tacky at tempera ture* beneath the activation temperature. In this type of coating, solid plasticizers can be chosen to provide an exact temperature at which the heat-seal property is activated. And be neath that critical temperature, the coating does not block or have tackiness. FOR RIGID FOAMS ... toughness In the chemically-blown foams, solid plasticizers can be used to add toughness to the finished foam. In the plastisol foam process, solid plasticizers thicken the starting formulation to make pos sible more uniform cel) formation as the gas is released. A uniform ceilulAr structure makes the foam tough and provides uniform dimensional stability. In chemically-blown vinyl foams made by milling or Banburying, the solid plasticizer acts as a liquid solvating plasticizer at the process temperature to make possible easy processing. At room temperature, the solid plasticizer's inefficiency results In a higher compression-resistant foam. FOR IMPREGNANTS .. . bettur flow To get even diapersement of impregnating powders, solid plasticizers can be used as a (low aid for producing brake band linings. The flow aid property is also useful in certain types of adhesives, phenolic moldings, thermosetting ureas, and melamine coatings. MOMS 0777*2 iffy'i\ k'JSVi'T 'Vs 'i-; Heat-staling costings Dicyclohexyl phtholote (DCHP), Diphenyl phthalate, Santolite* MHP, Santicizer* 1-H, Santicizer 9 Rigid extrusions Diphenyl phthalate, Aroclor* 5460, Triphenyi phosphate Santicizer 1-H, DCHP Meldings and rigid foams Triphenyl phosphate, Diphenyl phthalete, Aroclor 5460 and 1268, DCHP Break-awey "glass'* Santolite MHP Phenolic brake linings Senticizer 9, Aroclor 1268 Surface coatings and competition watlboard Cellulose acetate Triphenyi phosphate Nitrocellulose DCHP, Diphenyl phthalate, Santolite MHP,, Aroclor 5460 Melamine Santicizer 9 Thermosetting rssins Santicizer 9. Santicizer 1-H, Triphenyl phosphate, Aroclor 5460 and 1268 Urea melding compounds Santicizer 9 Melamine molding compounds Santicizer 9 Fire-resistant cellulose eeotate Triphenyi phosphate Crystallizing lacquers Senticizer l-H . Polyamides Senticizer 9. Santicizer 1-H Vinyl end other hot melts Triphenyi phosphate, DCHP, Diphenyl phthalate, Aroclor 5460 end 1268, Montar* 4; 5, and 9 Otlayed-taek adhesives Diphenyl phthalate, Santicizer l-H DCHP Book-binding adhesives Triphenyi phosphate, DCHP, Diphtnyl phthalate, Aroclor 5460 and 1268, Santolite MHP, Santicizer 1-H Registered U.S. Pat. Off.. Monsanto Company MGNS 07770 o PLASTICIZER - RESIN COMPATIBILITY GUIDE The following table shows a close approximation of the upper limit o of compatibility of each of Monsanto's plasticizers with a particular type of resin. oin'*'* |HQ(*S ' BWT T''. > apfS^nm yw 1 ' '*< 5*r_ - ^ - ' S*!MWn...' K ... .>. . ..*u_ c c PfefyvMiyt Chloride Polyvinyl Acetate Polyvinyl Butyrel Pofyv(n*lid<n Chlerld* Polystyrene 100 30 1 100 100 | 1 too too 80 100 100 too 100 too too 100 100 itw 50 100 1 1 100 1 1 70 t 100 t 10 1 40 75 100 50 50 25 15 5Q 15 15 50 25 100 10 SO 20 30 20 ~ 75 20 75 10 25 50 2$ 25 20 10 75 50 2S 10 15 25 SO 100 20 100 100 100 100 100 50 70 100 too 100 75 75 100 50 75 NrtrtollulOM 100 50 100 10Q 100 60 100 100 if) 100 100 100 40 40 40 100 100 Etht MIuIom 100 SO 100 100 100 100 100 100 30 100 100 100 75 75 100 100 75 CoMvMm Actt* Cellulose Acetate Butyrate a l 85 1 l 80 I 1 1 l 10 t J 1 1 t t 100 20 100 50 50 100 50 so 20 50 too 50 40 20 40 50 75 Cellulose Acetate Propionate 30 10 100 15 20 100 20 20 10 15 80 50 20 5 1 25 so CMorinarted Rubber Hf|b Styrene-Butadiene Pnitein Compounds SM\t* Acorfic Type Retina MytmUn 100 20 25 100 100 25 50 33 30 too 80 too 25 25 100 30 50 50 20 25 50 50 20 50 50 20 50 50 50 40 40 40 50 30 20 1 20 1 1 2Q 1 \ l i 10 1 J 1 1 1 1 15 1 15t 1 t t 1 1 t 1 1 11 70 25 100 25 25 too 25 25 25 25 70 25 15 1 20 70 so 25 10 t 20 25 l 25 25 to 20 25 25 t t 5 20 ia Polyester EW Phenolic Alhytf Metemine Polyurethane NHriie A Neoprene Rubbers 20 20 10 15 20 5 20 20 20 IS 20 20 5 5 5 15 10 -025 10 10 I I 1 J l 10 t 25 10 1 t l 15 15 50 25 25 25 25 25 25 25 30 25 50 50 25 25 25 25 30 70 25 25 25 25 25 25 25 25 25 50 SO 25 25 20 25 30 1 1 1 1 1 \ t \ 1 t J_L \ t 1 1 25 10 15 25 25 15 25 25 10 25 25) 25 20 20 20 25 IS | o100 50 100 100 100 too 50 50 33 100 \' 50 50 50 40 70 60 MOWS 077745 o 0 Plasticizer-Resin Compatibility Guide Q~~ O a o 100 100 100 100 100 100 90 100 SO 75 75 100 100 60 IX 20 1 1 1 1 1 15 15 25 j-- 1% 1 1 1 1 1 1 1 1 1 1 1 40 SO 40 40 to X X IX X X X IX 25 25 23 25 20 25 5 20 1 25 100 100 50 IX 50 X X IX X X X IX a 15 20 25 25 10 25 20 10 10 15 13 75 75 50 75 20 20 25 X 20 25 25 75 | 199 ioa 100 100 75 100 GO 75 25 100 20 15 SO 100 15 20 10 10 X 10 10 10 X U 100 50 60 40 100 TO 40 35 35 35 100 100 IX IX 75 75 X X X u IX IX 109 NO 100 100 73 100 10 75 100 100 50 70 100 50 70 30 X X X 75 75 75 75 i 1 1 1 1 1 1 1 1 t 1 1 35 20 10 15 35 20 45 X X 25 25 ,00; 90 40 25 30 20 50 35 20 SO 25 25 30 SO 25 X SO 40 40 X 25 X X ix ; 40 5 10 5 20 5 5 a 1 1 1 40 100 40 40 X X X IX X X X IX | too 90 100 100 25 100 100 25 100 100 too 100 100 100 IX X 25 25 X 25 X X X ; 9 t so 40 40 40 so 35 40 20 20 20 50 50 50 ! 50 2Q 25 25 | 25 25 25 25 '1 ' 1 1 1 1 1 1 1 1 1 <0 25 10 30 10 X | 50 j 40 25 25 25 1 1 1 f f 1 1 , 1 ' 1 1 1 1 1 1 1 25 25 40 j X 25 25 10 29 25 10 10 1 25 1 1 1 l 1 25 100 25 25 25 25 25 25 25 25 25 50 1 20 20 1 1 ' 20 25 25 25 25 25 25 15 25 10 X X X 25 X X 1 j 10 15 5 5 5 10 5 5 1 1 1 20 20 20 | 20 10 S 5 | 10 5 20 20 5 1 10 1 1 1 1 1 1 f 1 1 25 25 25 | 25 10 20 20 X 50 j 25 25 25 A 29 a 25 23 25 25 25 25 25 25 25 50 50 50 j 50 X X X X X i X X X . L. 25 25 25 25 23 25 25 25 25 50 25 70 70 50 j 70 X 40 X 25 25 25 25 70 1 1 r' 1 1 1 1 1 t 1 f 1 1 1 25 25 X K 25 25 1 25 2$ 20 20 20 25 20 20 15 IS 15 25 25 25 25 10 10 10 20 10 ! 25 23 25 L_ 90 50 50 ! 50 50 i 50 j 65 50 M 20 { 33 33 40 50 55 X X X X ( 50 j X X X MOMS 077746  IS IS SO a _too 100 100 20 100 100 75 100 80 too wo j too 100 i 75 1 100 a 100 50 JOQ 100 100 i 35 50 40 10 * ii' i 10 10 I... so so too too 100 40 40 n 40 15 30 * so 15 SO SO ;> 2S a a 75 n 10 10 a 10 a 10 10 25 50 a 1 10 1 10 to 10 30 X 1 l so 1 50 40 20 1 50 100 100 f | 10 : too 1 too 100 100 100 100 too 100 100 too 100 too 100 100 10 1 M 10 1 } 1 l 1 ti 75 75 JLj a 10 10 33 10 100 SO 75 25 100 75 100 f1 a a 100 50 100 1 1 1 1 f t i t K 1 i , M so 100 too LOO 100 100 100 50 70 80 80 50 50 X 5 15 t1 5 10 5 l 5 |r' M ' N 100 50 too 50 50 10 50 a 40 40 50 a 10 I 1 1 j 1 1 J 90 M N 80 KB SO 96 9 50 30 70 SO 50 100 100 3 10 s a - 50 50 50 1$ IS 25 10 33 30 a ..a.. 40 50 a i | a 9 a a a 40 a 1 1 1 1 1 1 i 1 1| 1j 1 i a a to 30 10 t 1 l 1 l i 1 | t t ; i j i ! i 5 1 1 1 1 a a M a so 1 1 1 1 70 " 10 10 50 10 2D 1 1 1 1 N M 1 ] 20 | 1 1 1 1 a a 15 i | a a I i | i 10 1 a a 5 JO 5 5 5 10 s a a a 10 20 a 1 5 10 1 } a a a JL a 1 1 1 1 i ! t 1 50 j l 100 a 100 3 SO $0 SO 50 50 IS IS - IS a a 15 15 a a 25 25 a a j a a 70 70 70 20 a a 20 a a a a 23 a 15 5 25 05 a a 1 1 1 1 i i 1 i 11 . ' j '! ' ; 1 ! ' i ' 1 J a a a " 2S 10 10 15 10 a a 15 10 25 25 15 t 10 1 a w 50 SO . -r 50 a 'a 50 a IT 25 a SO S3 50 25 50 a MGNS 077747 Mil etonomerfc md polymeric pfasttetaon that contain unaatumtion often become ieaampetfela becauee of chemical tnetaWMy. Epoxy *tabill*ert KctiwiU thie ancdattto ao that tack amt dirt pickup cm frequently obaervetf in month or two. Qwnplelety saturated polymeric pteeOaliora. euch ae Penheiaer 409. remain tack i (Kpokm to North Indirect for more than on# year. Abaturn at wtedation under cowdlttona ot high humidity la Important In many vinyl applteatlone. Ptaattmars with goad humidity compatibility do not axuda front him ipaalmana In 19 waehe' axposwio at 60*C and 100-par cant iMathi humidity. 0 9 9 Potential plasticizara am quickly acmanad tor compatibility with pofyvirryi chloride by com pressing loop* of plaaticixed vinyl specimens for ona waak at 23'C and 90 par cant relative humidity. The amount of plasticizer squaaaad out, if any, is datarminad by wiping the inaMe of the fold with cigarette paper- 6 9 9 HOMS 077748 t o guide to plasticizer performance - PROTECTIVE COATINGS ^ for metal, wood, fabric, paper m HONS 077749 Cetteles# NRrate *4 * Cellulose Acetate Cellulose Acetate* Butyrate Cellulose Proptonata Ethyl Cellulose Acrylic NlfrtjniM Pelyvinyl Chloride Pslyvinyt Butyrel Pelyrinyl Acetate Pofprtayi Alcohol Pelyvinytlderw Cftlerl* Tripbartyl Phosphate Santicizer i*H Santicizar l&O Santtener X2 . SantoiH* MHP Dtqhanyt Phthalata Santicizer 1-H SantteiaerS Santicizar M-17 Santolite MHP Samiciiari Santicizar 160' Santicizar 26? Tricrasyf Phosphate Santicizar 165 i Aroder Santolite MHM Santicizar! Santicizar 8-16 Santicizar 8 Diethyl Phthalata Santicizer E-15 Santicizer 8 Santicizer M-17 Santolite MHP Santolit# MS-80% Diethyl Phthalata Santicizar 8 . Santicizar M-17 Santtelxer 1-H Santicizer 8 Santicizer M-17 Dicyctohexyi Phthaiate Santicizer B Diethyl Phthaiata Santicizer E-15 Santicizer 8 Santicizar M-17 Santolit# MHP Aroclor Santicizar 141 Dioctyl Phthaiate Dibutyi Phthaiata Santicizer 1-H Samlcizarg SentJcfxar M-17 Santicizer 1-H Santolit# MHP Oiphanyl Phthaiate PicyctoMtayi Phthaiata Oicyciohexyl Phthaiate Santicizar 1-H Diphenyl Phthaiate Oipbanyl Phthaiate Santicizer 9 Santoiit* MHP Aroeior Diphenyl Phthalata Tricrosy* Phosphate Sentfcfiar 140 Santicizar 278 $antictsar ISO Santicizar 262 Diphenyl Phthalata Dicyctohezyi Phthalata Trieroayl Phosphate Santicizer 140 Arcelor Tricresy* Phosphate SantWiar tt-16 Bentfcizeri Santicizer 9 Santicizer M-17 Aroclor Santicizer 8 Diethyl Phthaiata Santicizer E-15 Santicizar 9 Diphenyl Phthalata Santicizar $ Santicizar M-17 Santicizar 160 Santicizer 141 Santicizer 8-16 Santicizar 262 Santicizar 9-16 Santicizar 160 Santicizar 160 Santicizar 141 Dioctyt Adipate Oi(rH)ctyi, rxJacyl) Adipate Santicizar 160 Santicizar 141 Santicizer 8 Tricrtsyi Phosphate Santicizar 046 Santicizar 8 Santicizar M-17 Santicizar 8-16 Santicizar 160 Santicizar 8 Santicizar M-17 Santolite MHP Santolite MS-80% Santicizar 8 Santicizar 9 Santolite MHP Aroclor Santicizar 6 Santolite MHP Santicizar 160 Santicizar 262 Otcyctaheayi Phthaiata Santicizar 8 Santicizar9 Santolite MHP Aroclor Santicizer 160 Aroclor Santolite MHP Santicizer 278 Santicizar 262 Santicizar 160 Santicizar 8-16 Santicizar 8 Aroclor Diethyl Phthaiata Dimethyl Phthalata Santicizar 9 Santicizar 8 Santicizer M-17 Oioctyl Adipate Oiisodecyi OKn-oetyl, tvdecyil <' Adipate ____ [ Santicizer 160 Santicizar 141 Santiciiar 9-16 Santicizar 262 Dibutyi Santicizar 141 Dioctyl Adioatt } DKn-octyt, n-decy*) t Adioate I Diieodtcyl Adipate | Santicizer lAl Santicizar 0-16 Dibutyi Phthaiate Santicizar 141 Santicizar M-17 Santicizar E-15 Santicizar Ml Dibutyi Phthaiate Santicizar B-16 | Santicizar 160 f .M Ieqr Aroclor Mod-Eoo* Santicisar I Chlertnatad Rubber (Parte*) Triphenyl Phosphate Santicisar 140 Aroeior Styrene-Butadiene Rubber (PlieMto and Marben) Tricrasyf Phosphate Aroclor Dibutyi Phthalata Casein, Zstn Santicisar 9 *TJwy i!-OQl Santicizar 8-16 Oibutyl Phthaiata Santicizar 141 Santicizar 160 Santicizar M-17 Santicizer 160 Santicizer 141 | Santicizer 8 Mod-Eoox Aroclor Santicizar B-10 Aroclor Santicizer 160 Trlphenyl Phosphate Tricrasyf Phosphate Aroeior Tricresyl Phosphate Trlphenyl Phosphate | Santicizar 141 1 Oibutyl Phthaiate i Santicizar tH i Santicizar 160 Santicizar 141 Santicizar 8-1S Santicizar 6 Santicizar * | Santicizer I MOMS 077750 1 auSa ;JSb2Wt *teltarl69 hmkttmm ., j i} tnMatssri rtfebw )*t lartrf >UwM ; imw nitriMH* mii:: Oibutyl Phthaiata Santicizer 163 Santicizer 9 Triphanyl Phoaphata uc--f-C-*'w --an r- firmware CHphenyl Phthaiata Trfemayf Phoaphata Santicizar 409 Santoiita MHP Triphanyl Phoaphata Santicizer 9 Santici-rer M5 Santicizar 9 Santicizar 1-H Triphanyl Phoaphata Santoiita MHP Triphenyl Phosphate Santicizar 1-H Santicwer 140 Triphanyl Phoaphata Santicizer 1 Oiphenyf Phthaiata Arocior Santicizar 049 Santicizar 9 Diphanyi Phthaiata Santoiita MHP Santicizar 9 Santicizar M*U Santicizar 3 Santicizar E-15 Santoiita MHP Santicizar 9 Santicizar M-17 Santicizar -15 Santoiita MHP - fBdfeNr Arocior Tricraayt Phoaphata Santicizar 141 Triphanyl Phoeohata octyl Phthaiata Santicizar 166 Santicizer 160 Santicizer 262 Oibutyl Phthaiata Triphanyl Phoapliatt Santicizar 141 Samicizar 140 Santicizer M-17 Santicizer E-15 Diethyl Phthaiata Dimethyl Phthaiata Santicizar 141 Tricresyl Phosphate Triphenyl Phosphate Arocior Santicizer M-17 Santicizar 409 Santicizer 8-16 Dioctyl Phthaiata anCMurt anUcixar M*l? TWpbanyl Phoaphata Santicizer 140 Santicizar 9 jMgctyf Mlpat* Santfcizar M-17 XMacirt MtyMM Diphenyl Phthaiata ntSSaS* >Hl<,*yn Santicizar 9 l.tnMnilw MW nSetwrlM .itMteMarB-M ISaatWaar Ml Santicizar 190 Santicizar 0*16 Santtcizar 292 Mk|ay SMtfdnr Ml Santicizar 141 Sentidzar 190 Santicizer 0-19 Santicizar 1-H Diphanyt Phthaiata Oicycohexyl Phthaiata Diphanyi Phthaiata Diphanyl Phthaiata Triphanyl Phoaphata Santicizar 6 Santicizar M-17 Santicizar -15 Santoiita MHP Santicizar 9 Diphanyi Phthaiata Santicizar 8 Santicizar B-16 Santicizar 160 Santicizar 262 Dlcyclohexyl Phthaiata Santicizar 9 Santicizar 9 Santicizar B-16 Triphanyl Phoaphata Santicizer 140 Tricresyl Phoaphata Santicizar 141 Arocior Triphanyl Phosphate Tricraayl Phosphata Santicizer 141 Santicizar 140 Phosgard C-22-R Arocior Tricraayt Phoaphata Santicizar 141 Santicizar M-17 Santicizar -15 Diethyl Phthaiata Dioctyi Adipate DMnoctyl, n-dacyU Adipate Dioctyi Phthaiata Santicizer 160 Santicizer B-16 Senticizer 262 Oibutyl Phthaiata Santicizar 160 ^jj ^ TM M| Q ^ ^ ^ ^ K * -*'---*MMkpIMIiwm Otoctyi Adipate OiCixictyl. rKkcyO Adioeta ONaodacyt Adlpata Diphanyl Phthaiata Santicizar 213 Arocior Santicizar 409 Santicizar B*16 Santicizar 141 Santicizar 160 taUelaar Ml twMdM> Santicizar 141 Santtcizar 190 Santicizer B-16 Diphanyl Phthaiata Dicyelohecyl Phthaiata Trlcraeyt Phoaphata Santicizar 8*16 Santicizar 160 Tricresyl Phosphata Santicizar 140 Santicizar 141 Arocior Tricrasyf Phosphate Santicizar 141 Santicizer 140 Dioctyi Phthaiata Diisodecyl Phthaiata Santicizar 409 ga ^ Santicizar 160 Santicizar 0*16 Dicyciohaxyl Phthaiata | ^ Mufti nwhttatt MtaiMrMt .. WdwM' iMHctar e Santicizer 1 Tripbenyl Phoephata Santicizer 0*14 Oibutyl Phtiuriata Santicizar M-17 Santicizar -1$ Diphanyl Phthaiata Santicizar 1-H Triphenyl Phoaphata Dicyclohaaryi Phthaiata Santicizar 9 Triphanyl Phoaphata Santicizar 9 Oibutyi<PhthaJate Santicizar 160 Santicizar 8 Santicizar 9 iMttcinr Ml Mufti P*th*<a fcwMMur i-M twittclarlM Dibutyl Phthaiata Santicizar 190 Arocior Santicizar 160 Diethyl Phthaiata Arocior Tricresyl Phosphata Triohenyl Phosphate Santicizar 141 Triphanyl Phosphate Tricrasyl Phosphata Arocior Santicizer 141 Tricresyl Phosphata Dibutyl Phthaiata Santicizar 160 Diethyl Phthaiata Santicizar 0*16 Santicizer M17 Santicizer -15 Santicizar B-16 Santicizar 8*16 Santicizar -15 Diethyl Phthaiata ft TM ft | UntMam MB Santicizar 0*16 Mod-Eoo* Santicizar 9 Arocior lawitiwm ttkuftl HWWu Santtciiar 14* zs&sffl KnWctol ftW . Santicizar 0*19 Dibutvl Phthaiata Santicizar 141 Trlcraeyt Phoaphete Santicizar 160 Santicizar 141 Santicizar 0*16 Mkinrt Santicizar 9 V HIWMpiaa- Arocior Triphanyl Phoaphata Tricresyl Phoaphata Santicizar 140 Tricrcsyl Phoaphata Santicizar 140 Triphanyl Phoaphata Arocior Santicizar 9 Santicitar B-16 Santicizar 160 Mod-Cpox Oibutyl Phthaiata Santicizar B-16 Santicizar M-17 Santicizar 160 ' Santicizer B-16 Santicizar 141 Santicizar S Santicizar 9 Arocior Mod-Epox Tricresyl Phosphata Santicizer 140 Arocior Tricresyl Phosphata Santicizer 141 Arocior - Tricresyl Phosohate SanUcizer 141 Santicizar B-16 Santicizar B-16 Santicizer 160 Oibutyl Phthaiata Santicizar 160 Santicizar 8*16 Dibutyi Phthaiata f l * At SwiBtiar E!S : ' , [ KwDtIw Ml I Baatiaiaar 110 . 1 4k Dtactyl PMfnMt* SUM* MS Oftftyi f'lithplati StMkinrKI OtodySnittiUM* Santieixar f Santieizar M17 Santieizar E-l5 ~'7ttafaiytPfcofpfwt Oioctjr) PhltMlirtt Dfathyl Phthalata SinticijwJSO PKwbbjU SMtiebw# Santieixer 282 Santieizar M-17 OioctjFl mthalM* SanttetMr 140 SanticfrtrMl Santicinr 263 SurtolitaMHP Aroclor Santieixar M-17 Santieixar >15 Santieizar 8 Santieixer f Santieizar M-17 - Sxntotite MHP Nfiutyf PMMM* SanttclMT 1M Ofocfyl PWtulH* S-ntlcu* 146 Santicuer 262 5nlllt* MHP Santieizar E-15 Santieixar M-17 SantolitaMHP 0 P '* b f;- ' ^ ,. Satttcinrg-IS tontieJwr B-U Santidnr 141 DiaWrf FtittwMt*- Otactx Mliww S*nffdnr C-15 Oltthjf Pfittulat* 9 Dtoetyl Mlpatt Santfctair 9-j Santieizar E-1S SanUciaar 141 Obchr* Phthalata* Oantteitar 0.14 Santieizar 141 Santieizar 140 Tricraayl Phoaphata $aMietzar409 A/oc*or Oloctyl Phthalata Tricraayl Phosphate Santicinr 1*17 Sintklwr 1 Triphcnyl Pimpht Snnticirrr 409 Santieixar 140 Santieizar B Santieixar M-17 Santieizar 140 Santieizar 4 Santieizar M47 samidztr ho Dhrthyi Phthalata Santieixar 8 Santieixer UP Santieixar 1*17 .Santieizar 8 Triphenyl Phoaphata Santieizar M-17 Tricrasyl Phoaphata Oloctyl Phthalata Santieixar 409 3anticiztr 141 Santieixar 160 Santieizar 141 Santieixar 282 ArecPor Oloctyl Phthtt TrkrMyl Phoftphau Santieizar 1G9 Trleraayi Phoaphata Santieixar 282 Santieixar M-17 Santieixar E-15 Triphanyi Phoaphata Santieixar 8 Santieixar f*17 Santieixar 8 Santieixar 180 Santieixar 282 Oloctyl Phthalata Santieixar 409 Ditftooctyl Phthaiata Santieixar 100 Santieixar 141 Santieixar 262 Santieixar M-17 Santieixar E-15 ^ t Santieizar M-17 Santieixer E-15 [ ^ Triphanyi Phoaphata \ Santieizar 1-H 1 Santieizar 8 > Santieixar B-16 Santieixar 160 Oibutyl Phthalata Santieixar 262 t ' Z. r Santieizar B-16 SaaMHiar 141 OtofrlAdlpata Santieizar 141 Diphenyl Phthalata Santieizar 140 Aroclor Santieixar 141 Santieixar 9 Santicinr 160 Diphanyl Pthalet* OlcyclohaM Phtiuilata Santieixar 160 Santieixar 160 Santieizar B-16 f i ji SmttetowMl lanMctor B-lt MMfeMrlM 'Myl Phthaltte' MwwM PMlwlat* Oir^Hpt MiMti awittci--r ns Mfcis* 141 Wk()A04t4 Oimttw* PMaMv Smdttnr 8-14 M BmHMarg-is (> 1W Santfefear 6-15 Diactyl AcNpata M OIMhri PMhalat* SMBcinr E-IS SwKksnr B-li OIctl /Wpttt Santltlnr 141 SmMclor 140 Santicinr BIS BMleim Eli Santieixar 409 Santicinr 262 Dllaodteyt Phthalata Trieftavl Phoaphtfa Santicinr 140 Tricraayl Phoaphata Santicinr 141 * Santieixar 140 Santieizar 140 Tricraayl Phoaphata Santieizar 141 Dlphanyl Phthalata Triphanyi Ptmaphata Santtcicer B-t* Triphanyi Phoaphata Trieresyl Phoaphata Tricraayl Phosphate Santtefar 141 Santidzar B-18 MocHEpok ArocJor Santieizar 4 Aroclor Oioetyl Phthalata Tricraayt Phoaphata Tricraayt Phoaphata Santieixar 180 AroClor Tricraayl Phoaphata Cttathyt Phthalata Santieixar -15 Aroclor Santieixar 141 Aroclor Mod-Epo* Santieizar ML Santletiar >16 Dtoctyt Mipata .a. w MntNsinr B-1S Baotlclnr 141 Oipcir' Adleat* -w40r. Aroclor Tricraayl Phoaphata Santieizar 140 Santieizar 141 Tricfcayl Phoaphata Santieizar 140 Santieizar 141 Aroclor Santieizar s Santieizar 9 Aroclor Tricraayl Phoaphata Santieixar 141 Aroclor Tricraayl Phoaphata Santieizar 8 Santieixar 160 Tricraayt Phoaphata Santieizar 409 Santieixar 282 Dlisodecyl Phthalata Santieizar 409 Oioetyl Phttialata Santieizar 262 Oioetyl Phthalata Santieizar 141 Santieixar B-16 Santieizar 165 Tricraayl Phoaphata Santieixar 140 Santieixar B-H Santieixar 141 Santieixar 8 Santieixar M-17 Triphanyi Phoaphata Santieixar 141 Santieizar 160 Tricraayl Phoaphata Santieixar 6 Santieizar EM6 Triphanyi Phoaphata Santieixar 0 Santieixar M-17 Santieixar I Santieizar M-17 Santieizar M-17 Santieixar -15 Santieixar 180 Santieixar 141 Aroclor Santieixer 141 Santieizar 160 Santieizar 141 Santieizar B-16 Oibutyl Phthalata Santieixar B-16 Santieizar 141 Santieizar S-16 Santieizar M-17 Santieizar 160 Santieizar E-15 Santieixar B-16 Tricraayl Phoaphata Mod-Epox Santieixar -15 Aroclor MoP-Epox Aroclor Santieixer M-17 Tricraayl Phoaphata Santieixar 141 Santieizar M-17 Santieizar 140 Aroclor Santieixar 8 Tricrcsyi Phoaphata Santieizar 140 Aroclor Santieizar 141 Santieizar B-16 Santieizar 160 Santieizar 141 Oibutyl Phthalata Tricraayl Phoaphata Santieixar 141 Santieixar 0-16 Aroclor Santieizar B-I8 Santieixar 160 Santieixer 140 Olbutvi Phthalata Santieizar 8 Santieixar" Santieixar 8 hons anisi * * i - ; 1 | * ' i . i f s i f t / . ; -  " " ' .**T~z : ..$*%% J0> '*+&'**, *M fh* ...A A. ftiiwii ifirihrtitfii't' ;nr r- Ih^m PotywnWw Senttdee* I imparts flexibility without edeerao affecting tonsil# strength, ahreaten reetstence, or oil resistance. Sontidtar % Senticizer 1-H and SantoMo WNP ooch import property, improvements in particular application* Polyasttr* Aroelor compounds impart flam* resistance and improve adhesion, chemical and oxidation resistance. Ptisnol-Formaldshydd Senticizer 8 and Santieizar 9 improve flow and adhesion. Tricresyl Phosphite, Senticizer 160, Oi butyl 1 Phthaiate, Senticizer 140 and liquid Aroelor compounds improve h punchebiitty of laminates. Tricresyl Phosphate, Senticizer 140, t Senticizer 14! and Aroelor compounds impart flama resistance. M*ltmlti-Fermldehyd tenltclnr , improm sotution nd ealer stability, cleat, flow, adhesion, and Imped resistance of melamine costings. - ; ;> ;| H Urea-Formaldehyd Stntielnr 9 improvn flow and acts as a hardening agent . ' d i Alkydi Aroelor plasticizers impart improved adhesion, chemical and oxidation resistance. `Y ij M0NS 077753 0 O = i 'T o i,v* o o o o o PLASTICIZER PERFORMANCE o IN MOLDING AND EXTRUDING o The following table will assist compounders select plasticizers for o formulation evaluation on the basis of those properties most critical in the final molded part or extrusion. The plasticizers shown provide o the optimum effect for each designated property when used with o the resin shown. When the same plasticizer appears under two or more of the properties desired in the final product--that plasticizer o definitely merits evaluation. o o HONS 077754 G RUB CKTRUOIN*Mil* PeJyvbiyt CWOfW# L^iia^t i' . ' yg* . ~'Z2XmL- ? ' '&' Senttetoar MB - ' Dioctyf AcMpaie Santicizer Ml 0((n-ocly{, jvtfecyfJ Senttcizar HQ . Adipate ^ Trteraayf Pboaphate S*ntidzar27S Diiaodecyl Adipate - Dipfrniy) Phtttttat* Swrticinr 160 . Santiciztr 409 Trfcrwyl PhosoftRt* . SwiMciwr 262 ' '* CMM* Otethyf Phthaiate Santicizer 45 Santicizer 141 Dibutyi Phthaiate Santicizer B-16 - Aroclor .. SentieteirWa**' Santicizer 141 Dioctyi Adipate Santicizer 262 Santicizer 141 Santicizer 9-16 oS - 1 retrvtnyt fllttftr! Palyrtyrena Santicizer 9 Santicizer 8 Santicizer M-17 Santicizer 160 Ditxttyt Phthaiate Santicizer M-17 Santicizer E15 Dibutyi Phthaiate Santicizer 141 Santicizer 9 Santicizer 8 Santicizer M-17 Diphenyl Phthaiate Santicizer 8 Santicizer M-17 ^teg m i CilMra AhMi cumtatf Aaetete lutyeete CiHuMm HttntB lUl*4 C*tlKl*M <BnM WttlM ItatMrnM) lnnHma "w f^- V -M---in--w kuMMf Hum N) Acfyll* CMtmim Santicizer M-17 Diethyl Phthaiate Santicizer E-15 Santicizer 160 Santicizer 141 Senticlzar 45 Santicizer M-17 Santicizer 278 Santicizer 262 Dibutyl Phthaiate Santicizer 160 Santicizer 165 Santicizer 278 Santicizer 262 Santicizer 160 CMbutyl Ptithalata Senticizif 271 Santicizer 262 Tricreayl Phoaphate Dibutyi Phthaiate Arocfor Santicizer 160 Santicizer 271 Santicizer 262 Santicizer 160 Tricreayl Phoaphate Santicizer 141 ' Santicizer 160 Santicizer 141 Santicizer 262 Santicizer 6 Santicizer 9 Diethyl Phthaiate Santicizer 8 Santicizer M-17 Santicizer 141 Dioctyl Phthaiate Dibutyi Phthaiate Dibutyi Phthaiate Dioctyi Phthaiate Santicizer 165 Dioctyi Adipata Diiaodecyl Adipate DKn-octyi, n-dtcyil Adipata Dioctyi Phthaiate Dioctyi Adipate Santicizer 141 Dioctyi Adipate OHsodecyi Adipate DMn-octyl, n-decyl) Adipate Santicizer B4i Santicizer 160 Santicizer 262 Santicizer 8 PhlMWl Parmatdefcyde ' Santicizer 9 Santicizer 160 ...... Santicizer 8 Santicizer 1-H Triphenyl Phosphate Diphenyl Phthaiate Triphenyl Phosphate Santicizer S Diphenyl Phthaiate Aroclor Dicydohexyl Phthaiate Diphenyl Phthaiate Tricreayl Phosphate Arocfor Santicizer 1-H Diphenyl Phthaiate Dicydohexyl Phthaiate Tricreayl Phosphate Dibutyi Phthaiate Dimethyl Phthaiate Diethyl Phthaiate Santicizer E-15 Santicizer ft Oibutyl Phthaiate Tricreayl Phosphate Santicizer 140 4M 1 , /Qm i i Dioctyi Phthaiate Dibutyi Phthaiate Santicizer 165 . Santicizer 1 Dioctyi Phthaiate Santicizer 150 ^Pl _j % W Santicizer 160 Santicizer 141 a Triphenyl Phosphate Tricresyl Phosphate CMphenyl Phthaiate Dicydohexyl Phthaiate Santicizer 1-H Diphenyl Phthaiate Santicizer 9 Santicizer 160 Santicizer 141 Santicizer B-16 Santicizer 160 Santicizer 141 Santicizer 0-16 Santicizer 262 Santicizer 8 m W mP MGNS 077755 W ~1 .B AHTpinilMOMBB.||f'>ii Kf.fw'uoiuntii.i ^ iMUcDnrW ! SanHcinrCT .' Tfkreapllhlta9hllnfe6 MMNrMt''* ' SifltfcfeNr 141 Aroetor t S--MK-*-n--r|nMs Swttdzw HI Trtcrmyf Mnpluit* SwitfciorZU Santkbnr 278 ^ Arcelor o ... j_____________ gkfMmi HP TriphnW Ptw*p*ta ..0________ ' Aroclor Santicizar 141 Trtawyl PhopfMI 7rfphenyl Phosphata Trieresyl Phosphate ... U*7k-: s.ijBQg Santicizar lift Santicttac 141 Santicizar %2 Santicizar 27* Dioctyl Phthaiata Ottsodacyl Phthalate Santicizar 409 PkefrlPNlialMe^^B Qilscoctyt Phthaiata* Santicizar 141 Santicizar 160 Santkizar 0-16 1 1 1 1 Dioctyl Adipate f . Santicizar B-16 Santicizar E-15 Diethyl Phthaiata Diathyt Phthaiata Santicizar E-15 Santicizar B-16 Santicizar 141 Dioctyl Adipate Santkizar M-17 Santicizar E-15 Santicizar B-l$ Santicizar -15 Santicizar B-16 Dioctyl Adipate ; ; ! | Diphenyl Phthalate --1 Trlphenr* Phoaphata 2 Aroclor Trieresyl Phosphate Santicizar 141 Dibutyl Phthaiata Santicizar 160 r% Swittclnr* ' SinMclwr 1-H | Trtptwnyl MotptMrt* PH toaMmf 1 SentWwrl-H Phthalate %0 Anctor J * Triphanyl Phoaphats Triphanyl Phosphate Santicizar 142 Diethyl Phthaiata Sentidxer 140 Santlcizar I4t Trlciesyi Phosphate Triphanyl Phosphate Aroclor Triphanyl Phosphate Diphenyl Phthaiata Santicizar 160 Santkizar 279 . Santicizar M-17 Santkizar E-15 Diathyt Phthaiata Dimethyl Phthaiata Santicizar M-17 Santicizar 409 Santicizar 8*16 Dioctyl Phthaiata tP OiqreMmrl Phlhald* | Oiphwijrt ftttlulat* 1 THawyl Phooh*t A taUdwW Aroclor Trierttyl Phosphate Santisirsr 140 Santlcizar 141 Diphenyl Phthaiata Dicydoheayi Phthaiata Santicizar 160 Santicizar 279 Santicizar 160 Dibutyl Phthaiata Dloctyl Phthaiata Santicizar 16$ Santicizar 160 Dibutyl Phthaiata 1 SenttcUer 1-H Otphenyl Phthalate Tfterttyl Phosphate Santlcizar 140 Santicizar 141 Aroclor Dloctyl Adipate DiOvoctyi, n-decyl} Adipate . Dioctyl Phthaiata Santicizar 141 Santicizar B-16 Santicizar -15 Diethyl Phthaiata Dioctyl Adipate Santicizar E-15 Diathyt Phthaiata Santicizar 141 I > . Santkizar 6-16 Santicizar 141 Dioctyl Phthaiata* Diisooctyl Phthaiata* Dioctyl Adipate Santicizar 141 Dioctyl Phthaiata* Diisooctyl Phthaiata* Santicizar 9-16 Otoctyl Adipate Santicizar 14! Santicizar B-16 Dioctyl Phthaiata* Diisooctyl Phthaiata* ' W Trfoeayl Phosphate Trtphand Phosphata Diphenyl Phthaiata , Areeior -, J.............. - Tricraayf Phosphate Triphanyl Phosphate Santkizar 142 Aroclor Q Diphenyl PMhelete PkytMwuyt Phtftalete Trlphenyl Phosphate Mfeii*r499 Trieresyl Phosphate Santkizar 140 , Santkizar 142 Aroclor OlocWwy* Phthaiata | Diphenyl Phthaiata j Trieresyl Phosphate Santkizar 141 Santicizar 140 Okyefohexyl Phthaiata 1 lantldiH 9 Dioctyl Phthaiata Santicizar 141 Santicizar 160 Oioctyl Phthaiata* Santicizar 0*16 Diisooctyl Phthaiata* Dioctyl Adipate Dioctyl Phthaiata Santicizar 8-16 Santicizar 409 Senticizer 160 Santicizar 262 Santicizar 141 Santicizar B-li Dioctyl Phthaiata* Diisooctyl Phthaiata* Santicizar 141 Santicizar B-16 Santicizar 141 Santicizar B-16 JUi 8anUtt*9 ^Pj Anwler / Aroclor Tricrasyi Phosphate Santicizar 140 Santicizar 141 MOMS 077756 .................-------------------------------- ---- --- t 11^ flMHgHSi j4j Mtlctav 160 ' 'tanri PriuaiaM -MUdMrE-lS .MkiiarB-M jMWw Ml toctgrl Mpart* sntidaer MS antidawO-U ifeetyl Adlpete MktavMl Mm MB KnHdnrE'U Mtfl nUMIM* tetei* wpm MlMaar&U atelelur Ml ,'HltlMf B-M MMmtMI jiw^i rmiwui.XtMKHrl PftttaMt*' jteatyt Adipate MMMaar Ml Metfl PhttwIUa* MlHgllWWmMW ^*9' ra-iup-V- AN-I jwidclwr Ml (NWawt-M Met* PMMiM* DHtMdlrtnithaM*- SMUdMr MI Hum cmmm** SWMIciar B-t* OBmtHfl PhtNWM* MnBrlMlert* MklnrMl BwWrB-W oiiiMr< Withit* mMviii SMiMarB-lt SMMnrlU MWM AM-n-l*N5*mr4PPi^V' * 'SmthSmM Sultei--r4Qfc~.>. ' %2Ha!T`m TH(HM|lt PbteplMM**' ` THemM Plwpftrtt OlNNMhKQrt Phthalate SantfdwrMB SentidaeT 279 . SMtttelxr 27t Aroclor - Dloctyl Phthalate , Tricresyl Phosphate Diieodaeyt PhtftdateSanticizar 4CS Dloctyl Phthalate Aroclor Santfetar llfcSijM SantldW Ml ' Simtidzw B-1* Santicizer M-17 Santlcizer E-15 Aroclor Santicizer 141 Aroclor Santicizer E-15 Santicizer 9-16 T< iphenyl Phosphate Santicizar 8 Santicizar M-17 Triphenyl Phosphate Tricresyl Phosphate Santlcizer 3-16 Santicizer 1 Santicizer M-17 Santicizer 3-10 Santlciitr E-15 Santicizar M-17 Santicizar Ml Santicizer M-17 Santlcizer B-lfi Santidzer 19 S * *:i f s ' Tricreiyl Phosphate Santidzer 141 Santicizar 160 Santlcizer M-17 Santicizar -15 Aroclor Tricresyl Phosphate Santlcizer 141 Triphenyl Phosphate Santlcizer E-15 SMtieiw 1 Santlcizer 409 Tricresyl Phosphate Santlcizer 140 Santidzer 141 Santlcizer 4Q0 Tricresyl Phosphate Oloctyf Phthalate Santlcizer 140 Santlcizer 9 Santlcizer M-17 Santlcizer 1-H Santlcizer 276 Santicizar 8 Santlcizer M-17 Santicizar 160 Santicizar 1-H Santidzer 262 Santicizar 409 Santicizar 8 Santicizar M-17 Diethyl Phthalate Diethyl Phthalate Santicizer 141 Aroclor Dloctyl Phthalate Tricresyl Phosphate Aroclor Dloctyl Phthalate Tricresyl Phosphate SwiliclMr 109 Trlcntifl Phommu OHiodacyl Phthalat* Santlcizer 9 Santlcizer M-17 Triphenyl Phosphate Aroclor Oioctyl Phthalate Tricresyl Phosphate Santlcizer 409 Tricresyl Phosphate Santicizar M-17 Santicizar 141 THeresy! Phosphate Aroclor Dioctyl Phthalate, Tricresyl Phosphate Tricresyl Phosphate Santlcizer 141 Santicizer -15 Santicizar M-17 Diethyl Phthalate Santicizar l-H Santicizar 262 Dloctyl Phthalate Tricresyl Phosphate Santlcizer Ml Santicizar 160 Santicizar 279 Dloctyl Phthalate Tricresyl Phosphate Aroclor Dloctyl Phthalate Diisodecyl Phthalate Santicizar 166 Santicizer 160 Santicizar 278 Dloctyl Phthalate Santidzer 141 Santidzer 165 Santicizar 160 Santidzer 278 Santicizer 8-16 Dibutyl Phthalate Santicizer M-17 Santicizar -15 Diethyl Phthalate *' r f. } Dioctyl Phthalate Dibutyl Phthalate Santidzer Ml Santicizer 3-13 l 1 i Dioetyt Phthalate Dibutyi Phthalate Santicizer Ml Santicizar 165 '\ ,i j, '' 4 Oioctyl Phthalate Dloctyl Adipate Oi(n-octyl, n-decyi) Adipate . Santicizer 8-16 Oioctyl Phthalate Santicizar Ml * Santidzer 4QS Tricresyl Phosphate Dtoetyt Phthststa Santicizar 141 Santlcizer 141 Santlcizer 160 Santlcizer 262 Santlcizer 8 Santlcizer 9 Santicizar M-17 Tricresyl Phosphate Santicizar 140 Santicizar M-17 Santicizar 0 Santicizar 160 Santidzer 262 Santicizar 6 Aroclor Tricresyl Phosphate Oioctyl Phthalate Tricresyl Phosphate Santicizar 160 Santicizar 262 Switicinr 1 Oioctyl Phthalate Tricresyl Phosphate Santicizar 141 Santidzer Ml Santicizar 160 Santicizer 262 Santicizer 8 Santicizer 9 Oiooctyl PMhalat* , Santtclnr 18ft w Switicinr Ml | Santidzer 160 Santidzer 262 * ft -TrSlSifrPfft&hate Santlcizer Ml Aroclor Tricresyl Phosphate Aroclor HONS 077757 jQ CNphanyi Phthalatc i rriptonpt Ptavphar Smticizar 1 ' Santlclw 1-H Trlntonri MwIm* SanUclMrl SaMletaar im npkMM miiiai*u lift flap for chart DIckMM*I PMIw w**i*i niui>M TrtOMft Maaphati tmMarM I DMhwI nittnltt* THcnavt Wiotphito Tm*iwl Mnaplial Dtphwipt Ptithalat* Dlpftaay) PMhaiata MdcMnoqrl PWh Tilphanyl Phosphat MWBjyyABlWaWkMgljl f"tfntkTMnM* Wpftanjrt PhthalaU IwUclNrS i i ! HONS 077758 o The following table wilt assist resin compounders select plasticizers for formulation evaluation on the basis of those properties most o critical in the finished film or heavy sheeting. The plasticizers shown provide the optimum effect for each designated property when used o with the resin shown. When the same plasticizer appears under two or more of the properties desired in the finished film or sheeting-- o that plasticizer definitely merits evaluation. V o o o HONS 07776 i o 4 *0 P E.-B P- 0--R .IVI, A.N.'.CjsEy- k ..... Huflnrtor* : CMwM* umkimm Santlelzar 168 , Santkizer Ml t ,7 Santlcizar 140 Tricresyl Phosphate Dioctyl Adipate 0>{n-octyt, tvdacyl) Adipate Diiaodacyi Adipate PafyykifHitint Chtertde D4thyl Phthaiata Santlcizar E-15 Santlcizar 141 Oibutyl Phthalate Santlcizar B-16 *&. Santlcizar 28z Diphenyl Phthaiata Santlcizar iso Santlcizar 409 TricreSYl Phospbate Santiciztr 278 Aroclor Santlcizar 180 Santlcizar 141 Dioctyl Adipate Santlcizar 262 ^1*" ._........................................... Santicizer 141 Santlcizar B-1S , , i ; > ... i Patyetayt Alcohol Paiyzttyaafia CalMm AmM i fMIftllVM 1 jtHHf 1 ' WOTitt SmliclMr) SstTticiw t Saixlcinr M-17 Santlcizar ISO Ofbutyt Phthaiata Sanftfdaar 14-17 Diethyl Phthalate SantJctear C4S .Santlctaar ISO Santfcixar 141 Santlcizar -15 Santldzer M-17 Santlcizar M-17 Sinticiztf -15 Oibutyl Phthalate Santlcizar 141 Diethyl Phthalate Santidzar 8 Santlcizar M-17 Santidzar 141 Dioctyi Phthalate Oibutyl Phthalate Santlcizar 9 Santlcizar 8 Santiciztr M-17 Diphenyl Phthaiata Santlcizar 8 Santlcizar 1-H Triphenyi Phosphate Diphenyl Phthaiata Triphenyl Phosphate Santlcizar t Diphenyl Phthaiata Aroclor Santiciztr 8 Santlcizar M-17 - . J Dimethyl Phthaiata Dlathyl Phthalate Santidzar E-15 Santlcizar 8 ' Oibutyl Phthalate Tricresyl Phosphate Santlcizar 140 # ! m C-tlut-- & NHnta ^U----- IttH CtUKkM Dibutyl Phthaiata Santiciztr ISO Santlcizar 165 Santlcizar ISO Oibutyl Phthalate Oibutyl Phthaiata Dioctyl Phthaiata Santlcizar 1S5 Dioctyl Adipato Diiaodacyi Adipate DI{fvoctyl, n-dacyl) Adipate Dicylohexyt Phthaiata Diphenyl Phthaiata Ttivmsfl Phosphate Aroclor Santlcizar 1-H Diot*9f>vt Phthaiata Dicylohexyl Phthaiata Dioctyi Phthaiata Oibutyl Phthaiata Santlcizar 165 Santiciztr 8 Dioctyi Phthaiata Santlcizar 180 o dyfW*.|illl4lM IMHNfiaM) AnjlMHriN RwMm (>* N) Polyamide Trtereeyi Phoaphate Oibutyl Phthalate Aroclor _ Senticizor ISO Dioctyi Phthaiata ioctyl Adipato Santiciztr 141 Tricresyl Phosphate Oibutyl Phthaiata Santlcizar 14). Santiciztr 141 ^ Santlciaar 160 Tricresyl Phosphate Santidzar 141 Dioctyl Adipate Diiaodacyi Adipate OKrvoctyl, rvdecyi) Adipate Triphenyl Phosphate Tricresyl Phosphate Diphenyl Phthaiata Santlcizar 160 Santlcizar 141 Santiciztr B-16 a1 ^|| Santlcizar S it tha mmt efficient plasticizer. Santidwr 1-H, Santtcizer 9 and Santdite MHP are alio useful. 1 HONS 077761 3 Qiphenyl Phthaiate Arcelor Tricresyl Phosphate SantkJzer 409 0 Anchor rtefci... .* Trfcresyt Phosphate Santicizer 140 Santicizer 141 Arcelor Santicizer 262 Santicizer 160 Santicizer 141 Tricreeyl Phosphate Santicizer 27$ Arcelor SanNdxer 141 Tricresyl Phosphate A) Sentidzetf Tripft*nyl Phosphate Triphenyt Phosphate Tricresyl Phosphate Diphenyl Phthaiate I Triphenyt Phe*phete Aroclor Tricresyl Phosphate Santicizer 141 teitidur 9 SantWar 1-M TrtaNnrl PliotpAtte Triphenyl Phosphate Senticizer 141 Senticizer 140 Triphenyl Phosphate Diethyl Phthaiate SantfcJaerf Sentidzw 1-M Pfpheey* Phthaiate Arcelor Santicizer 141 Tricresyl Phosphate Triphenyt Phosphate Aroclor Triphenyt Phosphate Diphenyl Phthelate Santicizer 160 0 -0*0r 0 OMncMwny' PMhalata pHmI PMhalata Trinwyt Phoiotiit# Santtctetf 9 Santicizer 1-H Diphenyl Phthelate Aroclor Tricresyl Phosphate Santidzer 140 Santieizer'141 Tricresyl Phosphate Santidzer 140 Santicizer 141 Aroclor 0 0 0 Tricresyl Phosphate Triphenyt Phosphate Diphenyl Phthaiate Ancfcr Olphenyi nithaiate Ofcydwtexyl Phthelate Triphenyl Phosphate Santidzar 409 Tricresyl Phosphate Triphenyt Phosphate Santicizer 141 Arocior Tricresyl Phosphate Santicizer 140 Santicizer 141 Aroclor Oiphenyt Phthaiate Dicyclohexyl Phthaiate Santicizer 160 Santicizer 262 Santicizer 160 Sahticizer 141 Santicizer 279 Dioctyl Phthaiate DHsodtcyl Phthaiate Santicizer 409 Oioctyl Phthelate* Diisooctyl Phthala* Senticizer 141 , Santicizer 8 IS Santicizer 160 Santicizer 8-16 Santicizer E-15 Diethyl Phthaiate Santicizer M-17 Santicizer E-15 Santicizer B-16 Dibutyl Phthaiate Santicizer 160 Santicizer M-17 Santicizer E-15 Diethyl Phthelate Dimethyl Phthaiate Santicizer M-17 Santicizer 409 Santicizer 8-16 Oioctyl Phthaiate Santicizer 160 Dibutyl Phthaiate Dioctyl Phthaiate Santicizer 16$ Santicizer 160 Oibutyl Phthaiate Diethyl Phthaiate Santicizer E-IS Senticizer 8*16 Santicizer 141 Santicizer IMS Santicizer 8-16 Santicizer Ul Santicizer 8-16 Santicizer E-15 Oiethyt Phthelate Sentidzer E-15 Diethyl Phthelate Senticizer 141 Santicizer 8-16 Santicizer 141 Oioctyl Phthelate* Diisooctyi Phthete Santicizer 141 Dioctyl Phthelate* Diisooctyi Phthala Santicizer 8-16 Oioctyl Adipate Di(n-octyl, n-decy!) Adipate Oioctyl Phthaiate Dioctyl Phthaiate Santicizer 160 Dioctyl Phthaiate Santicizer 8-16 Santicizer 409 Santicizer 141 Senticizer 8-16 Dioctyl Phthelate* Diisooctyi Phthete Santicizer 141 Dioctyl Phthaiate* Santicizer 8-16 Diisooctyi Phthala Santicizer 141 Santicizer 8-16 Dioctyl Phthaiate* Oiisoocty! Phthala 0 HONS 077762 Ef R-MfA*N4)6sIM,tC` &&& Dleetyl Phthaiata* Oillaoetyl Phthaiata* SantMm HI SantMm 81$ Santicizar 160 Santidztr 275 Santicizar 609 SanticIxer 262 Tricrasyl Phosphate Diisodecyl Phthaiata Santicizer 406 Santicizar 41! Santicizer 278 Santicizar 409 Tricresyl Pbophat Santicizar 160 Santicizer 406 Santicizer 411 Santicizer262 Afociof Dioctyl Phthalat* Tricresyl Phosphate Diethyl Phthaiata Santicizar E-15 Santicizar 8-16 Santicue* 141 Santicizar 141 Santicizar B>16 Santicizar M-17 Santicizar -15 Santicizar -15 lantteizar 8-16 Santicizar -15 Santicizar 8-16 Triphanyl Phosphate Santicizar 8 Santicizar M-17 Triphanyl Phosphate Tricresyl Phosphate Santicizar 8-16 Santicizar 141 Santicizar 8-14 Santicizar E*15 Diathyl Phthaiata Tricrasyl Phosphate Santicizar 141 Santicizar 160 Santicizar M-17 Santicizar -15 Arocior Tricrasyl Phosphate Santicizar E-15 (Methyl Phthaiata Santicizar 141 Santicizar 141 Triphanyl Phosphate Santicizar E-15 Santicizar 8 Santicizar 8 Santicizar M-17 Santicizar l-H Diathyl Phthaiata Santicizar 141 Santicizar $-16 Santfdtot 141 Dieetyi Phthaiata* DUaaoctyl Phthaiata* Santicizar 409 Tricresyl Phosphate Santicizar 140 Santicizar 141 Santicizar 8 Santicizar M-17 Santicizar 160 Santicizar l-H Arocior Oioctyi Phthaiata Tricraayi Photohate Santicizar 141 Oioctyi Phthaiata* DJisooctyt Phthaiata* Santicizar 816 Santicizar 409 Tricresyl Phosphate Dioctyl Phthaiata Santicizer 140 Santicizer 411 Santicizar 409 Santicizar 8 Santicizar M-17 Diathyl Phthaiata Santicizar 411 Arocior Dioctyl Phthaiata Tricresyl Phosphate Santiciaw 141 Santicizar 816 Oioctyi Phthaiata* Dlisooctyi Phthaiata* Santicizar 409 Tricraayi Phosphate Diisodecyl Phthaiata Santicizer 411 Santicizer 8 Santicizer M-17 Triphanyl Phosphate Arocior Oioctyi Phthaiata Tricresyl Phosphate Santicizar 141 Dioctyf Phthaiata* Santicizer 816 Ottaooetyt Phthaiata' Santicizar 409 Tricraayi Phosphate Santicizar M-17 Santicizar 141 Tricrasyl Phosphate Arocior Dioetyt Phthaleta Tricrasyl Phosphate Santicizar 141 Santicizer 816 Dioctyl Phthaiata* Ohsooetyf Phthaiata* Santicizar 409 Tricraayi Phosphate Dioctyl Phthaiata Santicizar 141 Santicizar M-17 Tricrasyl Phosphate Santicizar 140 Arocior Tricresyl Phosphate Dioctyl Phthaiata Santicizer 262 Diisodecyl Phthaiata Santicizar 409 Dioctyl Phthaiata ArOCktf Santicizer 406 Dioctyl Phthaiata . Diisodacyi Phthaiata. Santicizar 141 . Santicizar 141 Arocior Santicizar 8 Santicizar M-17 Tricresyl Phosphate Santicizar 141 Santicizar 8-16 Santicizar -15 Santicizar M-17 Santicizar 141 Santicizar M-17 Santicizar B-16 Santicizar E-L5 Santicizar 8-16 Oibutyl Phthaiata Santicizar E-15 Santicizar M-17 Diathyl Phthaiata Santicizar l-H Dioctyf Phthaiata Tricraayi Phosphate Santicizar 141 Santicizar 160 Dioctyl Phthaiata Tricrasyl Phosphate Arocior Santicizar M-17 Santicizar E-15 Diathyl Phthaiata Oioctyi Phthaiata Oibutyl Phthaiata Santicizar 141 Santicizar 816 Oioctyi Phthaiata Oibufyl Phthaiata Santicizer 141 Santicizer 165 Oioctyi Phthaiata Diisodecyl Phthaiate Santicizar 165 Santicizar 160 Dioctyl Phthaiata Dioctyl Adioate Di(n-octyl, rt-dccyl) Adipate Dioctyl Phthaiata Santicizar 141 Santicizer 16S Santicizer 160 Santicizer 816 Dioctyl Phthaleta Santicizar 141 Oioctyi Phthaiata Tricrasyl Phosphate Santicizer 141 Oioctyi Phthaiata Santicizar 165 Santicizar 141 MCNS 077763 Santtetear 160 is unrtvaldd for rapid precasting on rha calendar and for high tsarHatrsoftfi. *o*s on16* i I I PLASTICIZER PERFORMANCE IN ADHESIVES The following table will assist formulators of adhesives select plas ticizers for evaluation on the basis pf those properties most critical in the finished formulation. The plasticizers shown provide the optimum effect for each property when used with the particular resin shown. When the same plasticizer appears under two or more of the desired properties important to the finished adhesive--that plasticizer definitely merits evaluation. \ MONS 077765 ,, PMrORMANCE Jv'M1 MDMCSIVES ' CMtatawNitrra ' Calhtlaa* Acatate Cttlbtesa AcetateiKtrnrii IWMMh PnwtmMa ftbyl CbNutaM Malta NlWim ' NO*l"jrl Ctilwtata PMydnyl Vixynl rVIffWIfl AUUIV 1 ^--i_.^ WaB_ 9-^P-H1 rR-WfcV--RW-P--fIrWB--^^-P Chtarta* lp CfttarimtaMuMw (fotanl Mww-liitailUm MUw (Pttallta and IlMkM) dMhvZpIn . 9 C'.Hv.J- O' .iVt A .'j o Trfpb*ny< Phowtnta Smuclwr 1-H SwMtatWf UO Dietm^l PWfaltt* Santidzar 1*H Santidiarl Santiciter M-l? Samoifte mhp Santicizar 1-H Santiei&rl Santicizar M-17 DJcyclohaxyi Phthalata Santicizar 1-H Santicizar 8 Santicizar M-17 Santietaer1-H Santoiite MHP Diphenyl Phthalata Dfcydohaxyt Phthalata Drcydohaxyl Phthalata Santiclzar 1-H Diphenyl Phthalata Diphenyl Phthalata Saotleixar 1 Santoiite MHP Aroclor Ofphanyl Phthalata Dlcydohezyl Phthalata THcreayl Phoaphata Santicuer 160 Diphenyl Phthalata Diqrctotiawt Phthalata Tricraayi Phoaphata Santicizar 140 Aroclor Tricraayi Phoaphata Santicizar B-16 Santidzar 140 Santidzar t Santteiaar 9 Santiclzar Mtt Aroclor Santidzar 160 . Santicizar! Santicizar 160 Tricrcsyi Phosphata Santlcizor 169 - Santicizar 8 Diethyl Phthalata Santicizar -15 Santicizar 9 Diethyl Phthalata Santicizar E-15 Santicizar 9 Diethyl Phthalata Santicizar -15 Santicizar 9 Diphenyl Phthalata Santicizar 1 Santicizar M-17 Santicizar 160 Santicizar 141 Santicizar 8-16 Santicizar 8-16 Santicizar 160 Santicizar 160 Santicizar 141 Dioctyl Adipate OKn-octyf, n-dacy) Adipate Santicizar 160 Santicizar 141 Santicizar 8 Trlcraayi Phosphate Santicizar 8-16 Santicizar 160 Santicizar I Santicizar M-17 Santicizar B-16 Santicizar 160 Dibutyl Phthalata Santicizar 165 Santicizar 8 Trtpfcenyl Phosphopi Aroclor santolita mhp Santieizer I Santicizar 8-i Triphanyl Phosphata Santidzar 8 Santicizar E-15 Triphanyl Phosphate Santicizar 140 Santicizar 8 Santicizar! Santicizar M-17 Santolita MHP Santolita MS-90% Santicizar S Santicizar M-17 Santolita MHP Aroclor Triphanyl Phosphate Santicizar 14Q. Santicizar 8 Santlclw M l? Diphenyl phthalata Santicizar 8 Santicizar! . Santicizar M-17 Santolita MHP Santolita MS-% Santicizar 1 Santicizar 9 Santolita MHP Aroclor Santicizar 160 Santicizar 8-18 Santicizar! Santolita MHP Santicizar 161 ' Santicizar 141 Santicizar 160 Santidzar B-16 Santicizar! Santicizar 9 Santolita MHP Aroclor Dioctyl Adipate Di(n-octyt, ivdacyl) Adipata Dtisodecyi Adipata Santicizar 160 Aroclor Santolita MHP Santicizar 141 Santicizar 160 Santicizar 8-16 Santicizar 160 Sant*Jzar B-16 Santicizar 8 Triphanyl Phoaphata Santicizar B-16 Dibutyl Phthalata Santicizar 160 Santicizar M-17 Santicizar E-15 Dibutyl PMIutata Santicizar 160 Santicizar 1 Aroclor Oiethyl Phthalata Dimathyi Phthalata Santidzar 160 Santicizar 9 . Aroclor Arocior Med-Epo* Santicizar 8 Triphanyl Phosphate Santicizar 140 Aroclor Tricraayi Phosphate Aroclor Dibutyl Phthalata Santicizar 9 Santicinr 8-18 Dibutyl Phthalata Santicizar 141 Santicizar 160 Santicizar M-17 Santicizar 260 Santicizar 141 Santicizar 8 Santicizar 8-16 Santicizar 8-16 . Dibutyl Phthalata Santicizar 141 Trlcraayi Phosphata Santicizar 160 Santicizar 141 Santicizar B-16 Santicizar 8 Mod-Epox Araclor Aroclor Santidzar 160 Triphanyl Phoaphata Trlcraayi Phosphata Aroclor Tricresyi Phoaphata Triphanyl Phoaphata Santicizar 8 Santieizer 9 _ MB9 BB eV M ^ ^B ^ . ^ _ A BP ^ -- 1 # 4 ^ ^B 4P ^B BP ^B HONS 077766 m 9 SantieJiar E-1& Wathjtf Phtholahr Sentidzer 141 Stfftfcisar E-15 Santidaar 8-18 8anticiaar 141 Woctyl Phtftdate* Santicisar E-15 CHetfcyl Phthalata Santicisar 8-18 Santidaar E-15 Santicisar 141 Oioctyi Phthalata* Santicisar CM* Santicisar 141 SantidBar 141 Santidzar 8-lf (Methyl Pitfieiet* DM^mtuibrt* Tricraayi Phoaphata Santidzar 140 Oiathyi Phthalata Santicizer M-17 Santidzar E-I5 Santidzar 8 Santdiie MHP Santicizer M-17 Santicisar 8 Triphenyl Phosphate Santicisar Ml Santicisar 8 Santicisar M-17 Triphenyf Phosphate Arador * Dtoctyt Phthalata Trfereeyl Phosphate Tricreryi Phoaphata SentidserlN Santicisar 141 Santicisar M-17 Santicisar E-15 Triphenyl Phosphate Santicisar 8 Santieixar M-17 Santicisar 8 Santicisar 1(0 Santicizer 9 Santicisar ISO Santidzar U1 Santidaar *18 Dioetyt PMhaMe* Dfoety! Phthalata Trteniayt Phoaphata Santidzar lb Tricrasyl Phoaphata Santicisar 409 Sentictxar B-M Santidzar 141 Diethyl Phthalata Santidser B-l* Santidzar M3 Santidzar 141 Santicisar 160 Santidzar E-15 Diethyl PMhaMta Santidzar E-IS Santidzar 8-18 Santicisar Ml Santidzar 8-18 Santidaar -15 Santidaar Ml Santidser B-ift Santidser 8-18 Santicisar Ml Tricraayi Phoaphata Santicisar 160 Arodar Trlcrapyi phoaphata Diethyl nxftaiata SantidavlCO Santidaar -15 Mt Moti-Cpoa Arodar Arodar Tricraayi Phoaphata Santidzar Ml Aiocier Tricraayi Phoaphata Tricrasyl Phoaphata Santidzar 140 Santicisar 8-18 Santicisar 141 Santicisar 8 Santidzar M-17 Triphenyf Phoaphata Santicisar 160 Santicisar 8 Santidzar M-17 Santidzar M-17 Santidzar -15 Santidzar Ml Tricrasyl Santidzar -15 MocMLpoa Arodor Santidzar M-17 Tricrasyl Phoaphata Santidzar Ml Santidzar M-17 Santidzar 140 ^11111,1 ai;'88gy;"^jjgpi"ji tmJjL. . . . Santidzar 8 '^T7T Santidzar 8 'pwyiw Santicizer! Santicizer M-17 Santidser 149 Samicizer 8 Santicizer M-17 Santicisar 140 Santidser 8 Santicisar Wir Oioctyi Phthalata Santicisar 409 Oiisooctyi Phthalata Santicisar 1(0 Santicisar 141 Diphenyl Phthalata Dicycfohexyl Phthalata Santicisar 160 HwTtff-s-o1a-a-c-y-r mva- ic.n c Santicisar 409 Dlodyt Phthalata Santicisar 141 Santicisar 160 Tricrasyl Phosphate Santicizer 8 Santicisar 0-1$ Trlphenyl Phosphate Santidzar IN Santidser 8 Santicisar M-17 Arodor Santidzar 141 Mod-Epox Arodor Tricrasyl Phosphate Santicizer 140 Arodor Santidzar 141 Trlcracyt Phoaphata Santidzar 141 Santidzar 8-16 Santicizer 8 Santidser 9 Santicisar 8 Santidzar M-17 Santidzar E-15 Santicisar 140 Tricraayi Phosphate Santicisar 409 Santicisar 140 Santicisar 8 Santicisar M-17 Tricrasyl Phosphate Oioctyi Phthalata Santicisar 409 Santicisar 141 Santidser 141 Santicisar U0 Santidzar 141 Oiphanyt Phthalata Santicisar 409 Diiaedaeyl Phthalata Tricraayi Phoaphata Santidser 140 Tricreeyt Phosphate Santidzar 141 Santicisar 140 Santidzar IN Tricraayi Phoaphata Santicisar 141 Diphenyl Phthalata Triphenyl Phoaphata f Santicisar 8-16 Triphenyf Phoaphata Tricraayi Phoaphata Tricraayi Phoaphata Santicisar Ml Santidaar 8-18 i : Mod-Epo* Arodor Santicisar 8 Arodoe Tricraayi Phosphate^ Santicisar 140 Santidzar Ml Tricraayi Phoaphata Santidzar 140 Santidzar Ml Arcelor Santicizer 8 MCNS 077761  C c c c PLASfiSOL FORMULATIONS (65 PHR) O o ol!`;: In formulating plastisols for various kinds of coatings, slush molding, rotational casting--tha sanction of the plasticizer system is critical. r Storage life, speed of cure, the hardness and tensile strength of the O cured compound can all be developed to the optimum values through selection of the right plasticizer or plasticizer blend. o The following chart shows, for quick comparison purposes, the o characteristics of a "standard" 65 PHR plastisol formulated with the various Monsanto plasticizers, using Opalon* 410 resin without o stabilizer. These values can be used as a guide to the performance of a particular-type plasticizer. However, closer values to the particular property most important to you may be obtainable by a blended o plasticizer system...which can be recommended to you by Monsanto's Plasticizer Council VlMOCJI* CMltipOitM BrooMM4 MAT #6 Spindl* SORPM *C tntttot 7Dw* aiDqp **c fntttof 7 Day* aDm *c InttUM 7Dw* . now* IM <. CWMIpOiUI Mm 90 Ml Mpti flow Ir4k YWM Valu* ttynticm* FMon ftfirt,-C ^W^ioii Tima, minutM --S--ill>na% lndMintewKl (snmm m mi dropped r ' mk> ** thkk # JB`C) ***MI Rwlltonc* inch** rabound (P* frt*i (Mil drappad 90T to cnntont htrdnaw turfaca) .vkSLt 7,700 10,700 13,000 5jOOO njoo 13300 430P 2#m 32,300 9300 12.700 12300 6300 9300 9,600 5300 1UO0 11.700 9,200 11,700 10300 6300 10.900 14,100 6300 20.400 33,100 3,600 5,400 64300 14,000 17,000 26,500 2,400 4,400 5,100 3,200 10,400 1300 6300 170,900 7,900 7J00 Gal - 13,000 2300 12J00 15,400 20,000 Gi .-- 2300 17J00 Gal 3,500 7,700 8,900 3,400 17300 37,900 9,100 Gl -- intimr n'T-'fc--M --1V 6300 9,900 8,500 134100(41) 164.000(7)) 16300(4)) 1994)00(7)) 19.000(61) 292300(7)) e 4,000 6300 6.600 7,W4i: 17300(4): 20300(5)) XJOOUK 62300(9)) Kooomt to 1 1v 3.700 7.000 7300 7.700(4)) 22.000(6)) 74.000IS1I 2594300(7)1 111300(7)) not to 9300 im 9300 10300 9,000 6300 9300 64300 9300 WOO 3,100 2,400 20300 31.400 294300 4,900 4,900 44300 5300 6300 5300 voo 6300 5,100 22,000 22,700 16300 304300 249.000 145,000 Lfl 03 IQ of U 24) 13 U H 465 370 100 32 40 16 255 L7 9S 13 9 127 US 127 - 99 119 105 146 90 122 9 11 10 - 30 20 14 7 43 54 43 23 5.1 43 S.4 - - U IS _ 15 _ _ 20 _ to C c HONS 077770 "m&mw'..1 w> eSSS"! ... * p'w,. 'im'-,'!)!'>! ' '* f- > JM ium > turn S.100 9,100 10,100 9,100 10,600 12400 9,000 10,900 12400 3.440 <410 4,400 24.000 27,500 33.000 30300 38,600 424 54 11,2 15.4 4,4 5.2 <4 54 5,6 5.6 2300 xo 3,4 JOJTO 164 23.0 97,0 934 9X6 94.6M 73,a* 6X4Qf ) MM ] wMmM ifmrn MM KM8 IMM y IUM MM h 7J \U m rm ) 10 i ) <700 11400 HSM HUM 32400 00400 7J00 UM JJOO Ul BO 129 10 <1 <400 1L400 0300 <400 11400 <100 21400 39400 <100 28400 4<000 IUM MOO MOO 9,700 0.100 <200 14 04 320 484 132 130 18 <5 44 \ 3400 <000 15400 54,400 10X200 19.2 7X600 CM 7,1 250,9 6*1 XI 10.120 1M0O 204 Q*1 -- 254 Gt -- 15,9 Gai <1 <2 <830 40,000 72,7 7X1 53J00 119,1 139400 5.8 6,400 54 14 34 34 LI 90 224 440 72 132 92 1 1 10 a 24 15 49 1.7 X7 54 xo <0 64 44 <1 1X0 1.000 9 7 04 705 139 7 104 4,0 4.0 <2 XI 4.0 4,6 9,6 1594 Gat 42.4 41.0 404 noa 3X401 32JB 34 12 54 X7W 5.2 <2 2<1 Gai -- 354 3X0 39J 31401 17481 27,681 2.500 24 1.5 15,1 144 11,7 1<5 21.4 1X2 9X5 85,0 10MK 77,0 7MM 0.4 6.1 2.1 09 OS 840 240 48 1 320 156 148 1 - - 7 7- - - 10.4 92 - -" ->. - - - - - - 27 34 28 - - - i lU- ... . ,l**111 '-la-- >MOWS 077771 > HONS 077772 Inclusion of Santlcizsr 213 greatly improves (old ralms* of vinyl plastisols. With Dloctyl Phthalata . W3 i|BR m o * '{ Plasticizer Performance - " " in Other Resins j KSnklZER'PER ETHYL "CELLULOSff FILM ' ! (48 - 49.5% Ethoxy Content) , 3T* - 15 PHR -- ~ *T*r- o Ptnttcun Control (no plaeticizar) sr Dlbutyl Phthalate w Diphenyl Phthelata Yield Point (|lli.) 6755 3625 5405 Tricresyt Phosphate Santlcizar 140 4550 5405 Triphanyl Phosphate 4550 # Santlcizar E-15 4265 roe fw ppw m 1 Santlcizar B-16 Santlcizar M-17 Santlcizar 1-H Santicizar 8 Santlcizar 9 Arador 124Z 3485 4125 5475 4625 4625 4905 Aroclor 1248 Aroclor 1254 w Aroclor 1262 5475 6185 7110 Aroclor 446S 8535 Yield Point Plasticized Film .,, # YWd Point Unplesticized Film Tensile Strength (**') 8960 5120 7680 7470 8535 6685 6685 4905 7965 7750 6900 7325 7395 7540 7825 8035 9030 loft(ation <%> 30 38 38 48 38 30 40 36 38 32 34 40 36 30 28 22 22 !* -!* '1BI- . Hardness liKto** Resistance to Volatiliotion Ion Flexibility Retention on Ligfl! Etposurt 100 55 80 70 80 70 65 50 60 80 70 70 75 80 90 105 125 EE GE EG EE EE EE GE GE GE EE GE GE PG PG GG EG GP i -- Excellent Gf = ~ Good Poof MG NS 077774a PLASTICIZER PERFORMANCE IN NITROCELLULOSE FILM (12 MIL) PtBticaw Sdwpper Fold C^Jm ' are* wphr. Tensile, p.s.1 HPH* 50 PH* Elonjalioo (X) are* 50phr Moisture Pwmtetnlitt (%) , 25 PHIt 4 Control (no plasticizer) 20 20 8533 8533 6 6 100 100 Santicizer 1 H Sentlcizer 8 Sentlcizer 9 1' I Sdnttalxer 160 1 Dlbutyl Phthalate Tr(phenyl Phosphate 26 10 ----... 3270 -- 7 22 16 ---- 2275 -- 11 27 -- --------- --------- 11 14 -- 3555 -- 10 25 10 --------- 2700 -- 4 29 24 --------- 4410 -- 8 45 41 31 63 60 -- 10 19 36 65 52 56 . i f M1 Trlcresyl Phosphate Camphor 20 -- . --------- 1210 -- --------- 5405 -- 24 _6 16 28 ---- c . * *' 3* PLASTICIZER PERFORMANCE IN CELLULOSE ACETATE (LOW ACETYL) MOLDING COMPOSITIONS (52.5-53.5X) 151.5 PHR unless otherwise specified) r Mtstibnr ~ Dimethyl phthalate SoludM Tsm^oC 120 Hardness it 70* C. Rockwell "M" Scsh 32 Flsnrsl Strcnetk (p.s.1.) 5840 Pm Cut WltM ttwM 41 In. 1.14 Diethyl phthalate 140 . 15 5680 1.20 Sentlcizer M17 148 65 7110 0.77 Santicizer E15 148 50 6930 0.97 Santidzer 8 133 75 6860 0.94 Santicizer 9 153 ?0 9160 0.85 Triphenyl phosphate (42.5 PHR) 180 . 81 9020 1.17 r r m "C d < MCS 077775 Q 0 m .m l K m V .-fc-an..-. PLASTICIZER PERFORMANCE IN CELLULOSE ACETATE-BUTYRATE FILM (37% Butyrate, 13% A'catete) I (50 PHR) Plulkinr Dimethyl Phthalate Dlbutyl Phthalate Santicizer 160 Dioctyl Phthalate Dicyclohexyl Phthalate Diphenyl Phthalate Santicizer E-15 Santicizer B-16 Santlcizer M-17 Santicizer 140 Santicizer 141 Tricresyl Phosphate Triphenyl Phosphate Dioctyl Adipate Santlcizer 1 H Santlcizer 3 S**rd Hsxdnsu 46 38 42 44 30 r 42 34 40 i- 52 42 44 4 54 40 Tensile Strength (p.s.i.) 4200 1800 2700 2900 3900 3800 2000 1800 1800 2700 2300 3000 2500 Elongation (%J 14 12 9 19 31 28 14 15 18 13 15 20 10 28 L; 46 34 2100 3900 . 1800 12 46 27 H.W(tl!|lfa.fU)MI ir-*7 14 . ........... ' "W"TM"... ' MQhS 077776 - rusnciKR Control Dibutyt phthalate DI-2-ettiyl hexyl phthalate Dilsodecyl phthalate Diitodeeyl adipate Santlcizer El 5 Santiclzer Ml 7 Santlcizer B-16 Tricresyl phosphate t Santlcizer 140 !<- Santlcizer 141 HB-40 Aroclor 1248 Aroclor 1221 Mod-Epox COMPATIBILITY liquid c Room Temperature Curt c 100 c. for Vf Hour Curt c cc c c CI/P.S. SICI c CI/P.S. SICI c Cl w cc c cc c cc c cc c c c c cc c c SICI SICI cc c cc c cc c C = Compatible Cl = Cloudy CI/P.S. = Cloudy, Phae Separation SICI = Slightly Cloudy W = White VISCOSITY Brookfield LVF #4 spindle 60 rpm (unless other wise specilied) G 0 Before Adding Alter Adding Curing Agent Curing Agent 12,800 (30 rpm) 1,550 2.650 3,250 1,200 3,050 7,900 1,300 2,700 2,450 1,100 2,100 3,150 2,300 3,750 2,850 1,500 3,900 2,450 2,000 3,000 2,200 1,400 2,300 7,700 1,650 4.300 1,200 1,650 1,250 ,Q 6 G --o%f G G 6 G m MGNS 077777 o <9 PHYSIOU. PROPERTIES Sampln cwtd 30 mm. ffi> 100-' C. o wrtli 8 pltr Mnethyfam pantamma m M Impact RtaiitiiKa Clarity %UtM IMIkM A ,V A . w~ . 0.2 -- 0.5-1.9 0.5-0.8 0.5-0.8 --------- HKF HI wt Wr' Ml- --------- -- 0.5-0.6 0.6 -- 0.8-0.9 3.0 3.5 8.0 7.0 94.0 2.5 3.0 4.5 3.5 3.5 4.0 4.0 3.0 3.0 4.0 CM CM StiofiO Hardntss (10 $.) 78 10 31 48 56 10 6 7 15 5 27 40 8 84 PHYSiCAL PRGPSaTiHS Agfd M floors fit, 85'' C. in activated carbon Shore 0 Hardness (!0Sc> 86 %WaM Chan| -0.012 78 -0.734 82 -0.368 83 -0.168 82 -0.181 80 +0.119 85 -0.131 85 -0.013 86 -0.222 79 -0.284 82 -0.425 84 -0.648 88 -0.682 81 -2.118 88 +0.134 MONS 0???78 i in Ottier ReJier (fcaatenedy e j ^PLASTICIZER PERFORMANCE IN POLYVINYL ACETATE-EMULSION ADHESIVES 11 parts plasticizer In 100 pert* (Selva S-55 (polyvinyl acetate) emulsion. Film thickness 6.040 inch 4 4 Plnlicint Volatility 24 hoer; at S7* C. (Activated Carbon) (per wnt) Low Temp. (Modified Clash A8erg fast) C C.) Oil blraction--Weight Lon After 24 Hours at Room Temperature (per cent) Kcrossrtc Peanut Oil Cotton Seed Oil 6 Aroclor 1221 Aroclor 1232 Aroclor 1242 Triphenyl Phosphate i j- i h a j 5.2 4.8 4.4 2.0 --5.0 4.0 5.3 5.7 0.63 0.54 0.57 0.02 -- -- -- 0.37 -- -- -- 0.38 IK ------- te e Tricresyl Phosphate Dlmethyl Phthalate fc j 0.75 5.6 Diethyl Phthalate Dlbutyl Phthalate t 4.8 . 4.4 Diphenyl Phthalate Santicizer B-16 Santiclzer Ml 7 Santicizer 1H Santicizer 8 ' 5.9 t 2.2 r f I 3.6 ) 1 Li 1.5 l 3.6 3.6 --1.6 --5.0 --6.1 -- --3.9- 1.5 -- 6.4 0.16 0.92 0.85 0.59 1.31 0.08 0.19 0.96 0.43 0.38 0.75 0.63 0.51 0.90 0.46 0.50 0.36 0.60 0.46 0.93 0.82 0.59 0.98 0.36 0.48 0.53 0.64 * --C 4 c 4 Santicizer 9 . Santicizer 140 Santicizer 141 Santicizer 160 1 3.1 t 1.2 j 1.8 4 ai- 2.1 -- 5.0 ----3.3 1.9 1.13 0.15 0.17 0.20 0.57 0.63 0.34 0.36 ' 0.42 0.31 0.39 ,, 0.34 MOMS 077779 i t 4 aaaa 4 r S' fl j 1 1 Ths following technical bulletin* and brochures give complete technical infor mation about the properties and applications of the Monsanto plasticizers that are mentioned In this catalog. Monsanto technical literature is continuously revised to contain the moat recent and reliable Information possible. Your request for sny lit erature will be promptly and cheerfully filled -- without obligation, of course. Title Technical Bulletin No. a, Phthaiata Plasticizers Dibutyl Phthaiata Dicyclohexyl PMhalata Diathyl Phthaiata and Oimathyf Phthaiata Dlisodtcyl PMhalata DM2 athylhaxyf) PMhalata (OOP) Oiphanyl Phthaiata Oitridacyl Phthaiata DKn-octyl.n-dacyi) Phthaiata SanHciaar 160 (butyl bantyi) Phthaiata Santiciztr 165 Santicizar 213 and Santicizar 214 Santicizar 215 Santicizar 211 Santleizar 262 Santicizar 60S and Santleizar 536 Santicizar (03 SanOcinr IX sod Santiciur S31 Santleizar 632 and Santleizar 683 Santicizar 611 Adipata Plasticizers Oiiaodacyi Adipata DKfvoetyi.fHJtcyl) Adipata Oloctyl Adipata PL-302 PL-312 PL-303 PL-300 PL-311 PL-319 PL-329 PL-330 PL-160 PL-165 0/PL-213 PL-215 PL218 PL-262 PL-602 PL-603 PL-630 PL-632 PL-681 . PL-308 PL-316 PL-304 Phoaphata Piaaticizars Tricrasyl Phoaphata Triphanyl Phosphafa Santicizar 140 Santicizar 141 PL-305 PL-301 PL-140 0/PL-141 HOhS 077780 (CSntifHHMf) Title Technical Bulletin No. Phthmlyl Gtycatlata Ptastidzara Santidatr E-15 (Ethyl phthalate ethyl glycollets! SmUdar B-14 (Butyl Ptitlalyl butyl |lycoll>tl Senticiifr M-17 (Methyl phthelete ethyl glycoMate) ' PI-15 PL-16 PL-17 Su/fonamida Ptastidzara Santlcizar l-H Santicizer 3 Santfcixer 8 Santicizer 9 Sentollte MHP end Santoiite MS-80% OfPl-l-H .. Pl-3 G/PL-338 O/PL-9 0/PL-320 Parmanant Ptastidzara Santicizer 405 Santicizer 4d8 Santfdnr 409 Santldzer 411 Santicizer 462 Permanent Plasticizer Selector Pl-405 PL-406 PL-408 PL-ill PL-4620 0/PL-344 Othar Ptastidzara Aroclor Plestldzers HB-tO (Mftially hydraemtad twvtumyl) Modalkm Mad Epee (epoiy-resin modifier) Montar Compounds Phoeiard C-tt-R Trfphanyf Phosphite 0/PL-308 PL-40 0/PL-336 PL-313 PL-321 0/PL-22 PL-317 Ganaral Monsanto Solid Plasticizers \ Monsanto Plasticizers in Synthetic-Resin Adhesives " Monsanto Plasticizers in Protective Costings Bulk Receiving ot Plasticizers Memento Modifiers for Thtofcoi* PdysulRde liquid Polymers Monsanto Plasticizers for Food PecRaging Applications Monsanto Ptasticirers for Hard-to-Plasticize Resins Chemical Resistance of Plasticizers in Piestisols 0/PL-345 PL-307 PL-327 PL-314 PL-331 PL-500 PL-332 PL-333 HONS 077781 I DO 9 0 <3 G G G C c c c c c c c c