Document dJnZ6Vj3xBjykEGM3y2VVaeb
FILE NAME: Crane Company (CRC) DATE: 1943 Jan
DOC#: CRC039
DOCUMENT DESCRIPTION: Journal Article - Chemical & Metallurgical Engineering - Safety in Handling Aluminum Powders
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Cubi Dddms McG&AWmUL Jow 70r
1ANTJARY, 1843
O tti Y ar H o i W o rH W cd 1!,
75
BBlfomU TOREWQRS
W a s te D is p o sa ] P io R e m s i n W a r tim a ................ ........................ .... 7B ' . Si *, W. HOKLKOT
S a ie tv I n K a n d U n g A lo m ln u m P o w d n is'......................... ............... 8 3 i r c, K.8M0ac 4 r, . BEtBvnsca
fio tn u u fiepw l (IheEubbejr D i i o d o t t 85
Selectron ai Pampe ior Oleum and Slrong Sulpfrurlc Acid. , , 86
By W*JU> E. ff if itt
'
E ile d a l tKe Kinatic S nezgy T crm Su G a s Fiow C alcu lafio n s. . SQ
H y .f ilS iJ im m N U 1B&
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Nylon B astarda W ins Ite Wcar W togs......... ........................ .. 92
m at m L V tA irt& M t
M anufacture a! Butadiene From Btliyl AlcoKol--l i ............. . * 94
lY }. A IIMMA wI Ts atOUYB
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Ltd>or Belaltana and Cll^dlv BctrgateJng in Chemkicxi
InduBtry .......................................................... .......... ..
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A C fifJtf. I )O T, fJCTUBED IXOW sHCST
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Pet&ucaBllH r . , . s s . . 137
M elth9 tu O o n fe n ib n i . . . M
Wevrs Paetn A ^ re8 . . * 1S8
Cbem , A
fi k A * v . . . . 167
C berfcd Eccuom le and MadeeH I7
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Meo rtmag tny addala e ObinUol d f4ttiHiasical
SsofeaMlne
..................................... . . .
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Safety ili
Powders
Gr. M . BABCOCKand P. B , RETHWISCH Xtymdi Metals Ci,, leulsrllf#, ty.
-- ..... ......... -- - Chaw. 6 Mel. IHTTEBmETATIOM"*- '- ....
Except t o -those people who week conBtantiy with cduBiinujn pow ders, su ifid ert respect to r (he tucploslhUlfg .ol this m aterial does not appear to .exist. W ith (ho presort widespread, use pi aluminum pow ders ja r the m anufacture a t military pyrotechnics, need has developed t o the a n te w tdeapread dissemination oi intenw rtien an safe practices In their handling and in nnmuftrcluring pyrotechnics. The article which fallows fa hewed on (he experience gained by the Reynolds M etals Co. in m any years of producing and handling m etallic powders and Is ottered as a starting point in tit* develop' meet o j safety program s for condense engaged in or beginning opera (tons In pyrotechnic work. Cettcdn fundam eulel precaution* are dfacasaed by the authors a s a servifi to the indw iry, but neither they nor their company assum e Mobility of any kind in presenting this inform ation.--Editor*,
F u iMjjtiumi rowD, some- should he stared unopened in n sep wimt pimit&r to the materiel arate urea itesw er porsiIdo, stow ounmxraly used in ulinufaun pointif they ore stored along vidi sue))
under the lather muleitdl&g nano of tem utala'as sulphur, iu ta ! m l
ifalnmlaum brum pewter; fa a others of similar character, t fin
valuable unponcal o l pjvutodhoie from any emise would present, a most
mixtures used t o dares wifi signals. The. high Biufaea area of a given
idiom problem. "Whaieyer a drum uf aluminum pandar Is opened for
weight of aluminum flake powder Wading or inspection, i t should the
mutes il e&ldty ignltible When in the efaued and iwoaofctl os Boon as pen
pmeaoe o l oxygen or air,- burning, atole. Till* not only lunares greater
it evolves n bunendoua uuuwrt -uf safety against flic farai external
heal and light. Owing .to 11* low cansa hut aho limita (he likelihood
apparent Arisily, to o pnrtidaa o l of tramp rnafarlnl goUIng into fhe .
the material tond fa float in air with . powder; 01 of tbe powder absorbing
Uu> attendant dong of violent a - water vtam the air. In one instance
plosion npon Ignition. when a proper a staled drain of flake aluminum
rsttt of nluoinnm to oxygen h withstood an aluminum dust pk>:
reached,
sien and subaagBmt fire without
' K somewhat difinrtmt nhumnlD ignition of (he dram coniente
pnwdar, tlm grained nariety, eonetels Thors are' few' practical means of
o f spheres, asmsoge ntiapre nr irre xtingnnhittg f l involving alumi
gular grains at nlominiun. vtnte are num powder or mixtures containing
relatively hard fa Ignite. TVhra mixed Uih powder. Aijlldcg whirl tend
ttHh oxygnn.pradmng compound*, to distarti die burning moti may
` (ho glviseil powder will Irani vlili (brow (he aluminum fate the ah* and
the evolution of nmdi h d t and light. result Is a violent aspfatiea ol ir*--
Tbfa materia!, howcTcr, Sms * high mendons dutenotive potter, I I it
apparent deaiity imd low snrfaoo trae teal dry sand, uttfuDy planed
area white Wttds fa keep i t from over a pite of burning olnmimna,
mijpenmnn in air so that the danger will amodier tee flams, bat in Ibe
a t explosion or lira from aluminum croitaiaent attending strali a fro,
fog ia almost nil
them fa danger that Bio ximd vJU
Both flake and grained alundntuu he (known or shoveled on to the
are skipped ia sealed drum* with ms, and that the powder will bo
fully Msumbie heads. Those, drnme thrown into the air. Ttere have been
several awe where relatively hann-
leno fires have hesi changed te aeri-
us nnd fatal explosion* from this
CAtlM.
'
Consefiusntly, the enter and more
prudent rale fa te instruct amptoyce*
to walk out of the building in tee
uso of (in aluminum fire, shutting
the door seenrely but os gently aa
posoible to avoid distnteing the
homing mass.
dll employees should he instruefai
in prooedoras to avoid, Itn y should
understand thoroughly tint water,
carbon. fatratetaride, tiro foam, nut.
bon dioxide and (to tto ertiugniah- '
ng agente should net be used on
ahuniuiitb firn*. V nt t{ lute materi
als riti tana xpWona. Might
watchmen should lie matraotod to
convey Hite inform*tier fa any xeg.
lar or volunteer group which at*
tempt* fa extinguish an ahiunnnm
fire. Furthermore, (ho use of o fine
prey of v a t from a stirrup jmmp,
cute as lx osmi by civilian defence
worker* on Inrandlnry bombs, toltili
never he traed on alnmnmm murder
fires.
.
It is of nfaiost importance timi
lutai tire depurimelib. be htlwniefl
of these precautions. ' The ileptiri-
mpt should ho provided vi111 rom
pici information and teoria reynrd-
big those wrateouses white confaio
ateiafauxo, ua well eo t ta c cmiluiti-
Ing other teemteak. These tem i*
samiU) also bo reodtiy uVaifaUe to
the watchmen and to the plant's own
protection division a t oil tfaite.
XVOlbfa HAZARDE
'
A. evuree of great danger ia IV bundling of ahnninum powder n lie presenes uf foreign bubtetnecs. ptivtiunluil.v bund or metallic materials,
(fare teoulll bo eaten to see tinti doting balte, mula and siuiilnr bill of metal mntiot eonutniiuti lunU join pQirdrr or p^olrohnio mixlitMa,
JQood plant liomteeepin? fa one of tea mud, uitvclim metbufa fa-
oehleriiis plant cafuty and eoro dim,) ho taken psi'tiouUdy in Bio iroighing, miring and preatfag rooms. Jfa little material a* fa practical should bo kept in one pinco a t one teme. Stoops for handling pmnlwc chotdil
he of mm-spwking material and the handling should be slow and ddi~
8*
- JA X V A .B T iP iS - a B E W C A P * M E tA P I- tlia C tC A I, E N G N fc C tflJi ;
berate, la reduce duKung be & mini-
mom flooma in lfkwdi powder ie
handled should be eleaned i t Ire.
^uent mtcrvei, bet never during
Trcigtin, misitig or pressing opera-
Liona. AD n o ta ttl ibnuM be kept
in i-luued containers while denning
is in progress, i f oil is need in Hie
pyrotechnic mixture, speaial 00
jantti. be liken to insure Hist sli
oily rags or waste w doporited in
.oloaed snfcty cant w**g Itera lbs
steriige or loading areas. Use* ngs
must be disposed of daily, in Arm
ing, ears must be takes purlianMy
to keep nD eornorc, window ledges
booms, building steel and other rost
ral! plaoas free from fast.
'
U KO TKG PHO TECTIO H
Tho buildings seed lor minting,
' mbang and leading operaiieua should, 'Pboreror puadble, be so spaciad end. protested that Sees or etplndons iu one trait cannot be tanomuniestiMl to other units. Cooatraetlon should be adapted to the Mat. log ot Hzpiesltras, ualng either a "soft" wall or root, or a Hovr-eni
- panel AH equipment should 1 Inosted so that the operetur has free paflt to an outside door, with-
eut a mixing beach, pmas or mixer
li*tws bin end His door. All metal in the buildings should
be grounded. This not only include),
the equipment Uwdl, hot also rartol window ond d a n traaat end ofW
building idomenh. Clips ecOnwtol to dsztlde grounded lends should bo placed on 11 metal drums nr oiler movable equipment, Only ryplozionpreuf mntore should be pnmiUnl, and tor these tho' oontrelu slnnld be fidlv j'nrJo&ed and muiiireiufc Inoatad outside Ilie workroom *o ibnt no worker need h* in the Raxing nr
pressing more Ihvm the time ot storting Uiaae operation Rnlfl they
are oopleti. .All lights should be n t n type approved for explosive opemtionf: and conditions. Pnrtteular rare mnot bp token who ontanmtho or TWatnal tools ate to be used in bnUdlugs for repair* or ebmufns.' Where inch -work fa ta be earned out, the rooms must irs t be emptied of all ipiitlbie material end ttaroufjkl.v elannei fatal explosions have .been
enured ia dust-idled rontns by on
re from the smteb of bn ordinary flashlight. Therefore, rely fliwh
1*1hi*,
]trilling tutil pMver
aipuietd carrying Undarunters'
approval lor use iu plosive areas
mid trW* (oiplooivo vapor* are *n-
euUOLnrwl .should bo used.
Wherecr pfwiiWc, built Urn those
of wetkaK mi the doe-re bnaU be
pt coraluflive hut iion-spstlaag
typo. ISJeclrieal discharge produced
by Klabe or lightning are llio most
difficult outcry hazards |o centred.
The danger iiom stetie ehsrgcs pro
duced by ftiolioiL 1 gicuteel in soli,
dry weiiibsr. ftymi wslkrng oo eun
role or omiipouilioH flooring in ninl-
uuhfacSing , Aiuse may prednrr
apurka capable ut igniting pyiolrt'li-
nic mixtures or line slutuimrn par
tides susjiondcil iu the nir. Row
ib< rotation caiiMul by nUualunm
pomler pourud fnnu 'a ureop In a
cimtamor eon omile high stnih,
elmrge un the nlumiiiina }Mittir-les.
I'oriltnUriy iu die cure of flake Hi. . imam powder, considerable time is reginred to dissipate dlls tdraxge,
Several typos, of win-aprtridog, rondueUv floors lture been employsd ueewsCully.' Three types may Ik described briefly bore, including (I) Magnetite flooring installed ever a wood or onunde Lush, with oandiielite inctol gi'Jibi p!aed beneath the
mirfacc ut the floor mil properly gro'usilei; (2) craulsHted BKpball
etiUtpotUion flooring m b a eomhietire aggregate whioh a U iu Imd oi<er Xronndod nietu) grids, aud 1) indHelical graphite tile outdo of l conductive stie, the Mlgre of the l<le bring melted togetiier wilh a tvo) bore mi itt- u lk li- u io prm id e a n'ntlimmt. surtace. Wuh tlut-Jiut
uuoilueii<d i>7>e no isctul grid it
ncetSNiry, lie )3e ilecll1 bring gsunndml ut vuriouA paiala,
thaso vlooic, hoc pketoa by Iha V, S. Army Score Cmpa. ahow c lltemlte 1-- u stmuimliatlon ci the Army War Cellow . WoskUistea. b. C j iho a * ,o ru n , ho, the bomb fcaglnobtu to aaplodo, u ttli die lower d e v s the cilrwix o) the exnlealjai whore the botOb. hartn roaehod n leancerelow ol chinl tfltD da, fa raellbs
threuch Iho rloh ol rice) a which R m b
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!
Mmrtism In This Issue
Ni09
Abhl tau. fari O.
7
Acm i CftpptrsmlHdM A W** v d fa e C e T ............ i
AWl*C60lniar* VUff* C o ............5 , IS
Atti C * , \*u l*..................... itum tam Co. eJ to n te a ..*.. i l
A iutatasi Or C * , , . , . K M
Am u Ic u Citis A Cubi* Ch^ ^
A tnffrtt D U rlci ttcM Co It i
Atnoifcoti Rttefl* A btf|< Co 41
A fM itan LeameHv C *. . . .. S (
Amctmii M(h. A
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toxican Mt*r C*. Ine.. .* <4
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A n tr ia i M t rlts Co*
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Amatimi) Sm rillns A fcofakg
Co. :................................. W
Am oikto Teol A M edita C * . 44
Amari** W riff C e . (ab... IW
tonrtrwtfl Mach. W vitav.n- It i
A tktU teO rri fttdutfc r i f a O I
A tti! ta rd a r ............................ 292
labek A W IIcm Co.
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lid o * A Sodi C C, 6 . . . . . B tt
Beto A & , lue . .................. 44
lald rio-H I* C ri . . . *............... I
|a n m C e ,, I. ...,. .
A lt
t * k i Cb.( W ....................................... I
r t a t u i`A U lnb p lleil Cc . 24T
Nttfe Are. * * Ce......................... * t i
H r4 M atti C * . . . . . . . . . . . . ? lie v it a i C e . .............. . . . 51
B llctau *, Iw u, 5 . . . . . . ............ IH
Bella C e. ...........
1M
Boimty fa tte A Tesi W rifcl . . IR
Irta ltV
C O .,............V i
Brlehlen t o p * W ork............... 31)
m fa ri . C e rp ............................U i
B ririri Co,
. . Iti
Beali Uff*? C * . . .. .A B
" 'M I* !* fa tt* C e ....
201
M ale fa r * A Matte Ce . 2 fitta* Pwnp C o .................... . . . . tifi
C * M I* A C t|U n CUmleaiK ,
Coti. . .
I l
.,. >m> Caiparter Steri Ge............... 2
C IA C * * A . W ..,',................ III
Galeota Co
HI
Ctatory B a d rtt Ge - ......... . *
CftapMM) V*Wo Cb ..~
. 341
Cbu Boa C e ......................
22
CUm lcel G w irtitclta Cera . 214 Dhkoffo IrU g A fora Ce . M I
CJ& et M oiri H o Cerp . W9 Ciopay Cerp- . 4^*. M. . 2
Cochee Coip*
. . . , M6
Gota A C,, L . ~ . . . . . . MB
C o k M * CeM A. t> . . . . , . . . 1
Commercial Attraete corj*.. t**>pa$
Ctnrafldatad Ire A . 0. (m 27
C e rita rte l )n Co__ ,
KB
Oeeper A5*7 fa ty. C o ........ Iti!
CofjH ii Eh^tt*
SI
C o g ita e !* a V ta tr.t,........ .. W
C 'O - ta R n lo tta m f Co . . IBI
_.C rM Ce ...............................i . IS7
(KkMSeanl Tonicoit a E*wiim ini Dlv. Anw4ce Mm A. A h k k it. toc. ............................. Hi-
21 la re i S ip v tia r C e ............ .211 Po le n i Skem I wMm Co . H i C eieokii OtNui C d .... .............. It i
DlMUMid A ta U C o .. . . . . .. . . . 27 P it t ili Co. ................................... m bino MeseelJc kpoutor C e ,. I l i
Pota Mkt. C e ti . ., ....... t Coir Co^ tue ................................. 24
P e vtitatfr ***** A ....
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T*H
b-w Cfcm . C o ..............................m
Pfntafeiglowa trae W ork......... 4t
P/Acct C *tt*
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D ietat d A ,C e .. Ine.. I . A ... 273
Dorata C e. . . . . .
. . . , 271
(hrM w kttte Ctop............................. (42
Parirea Co* M e........... ............. ? l
Eoeto*7tsr leaA C a ,.
03
U ffa M ior lien W ork, U t.... 28S
C kciflral Cnfftaoii tautll Co. 7*
Mira C o ...................................... JM
R u iH t Eqolprni Co,
. . . 3c
f M f
Cv . . 303
Epponbecti. tee. . . . . .
IM
EppUr U toueiwy, t a ..v , , . . 2M
EaM*Hewll It k l Co . ` ; 203
fi* ACe#j V ietar J*............ 274
E m rita V rirt C e .............. M
MrAonks Ce. ................................... #6
frtrb tekj, U em A Ce m ,., It N o val N4. ................................... 210
R th r f*f t 0 .<
274
ftai Morii. CetA- ***, 242. 211.7H
R ritfc li V farti ..........................tif ^ fo ite f V ira ta Ceip .. . 2l>
Roer Carp, lid .
. . . .73?
fa ri Ira, Goar A Mede Corp. W
fa lta ra C o ,. . . . . . . . . . . . . . A i
(m ietici: Iran A S ta i Co . . . . lift
fa lta Ck . . .
. . . . . . . . . 10
Carted fa cto Co . . . . . . . 0
olb I Scfl, 8
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C tteral CtM ndn C o ................243 6cefal Oealroll ....................... t il
/ Gravimi M at. Ce. . . . . 21-22 4(
B&'ft&fc.'Sfl: ,,
GlrAler Gecp. . Tad Cover. 4 , H i
Glota Stool Tub Ce . . . . . . . 267
GlMldhrQ. M cfa it Ce............... H i
. CodAr fatnftf Ine ......................... 2(4
Gravar le a l t Mfe: Ce. lee . . M l
Cleoni, fwvt A Ce . c It i
v 'C fk fitV Co, U , .
. 22 .
Gravo t a r la t a G . . 2 tl
tiurdlaf Co Ine . . . . . 62
rt*rv7 tra i, , ................ ... , A ll
Honiy (Afg.
U4
KrHierlal<Mt A lunar I n e I S i
H lik i EiiQig, Cau t a t %. D. . 14*-
Hotataa fabbr Co........... .. . 141
H m iit a Vota Mig. Ce . . . . 217
Hoelcer BkdrediM etcri Ce 26i
HowA Beetite tu ta Co
n
aBnob V a l tiu t M ii -C* . . U t
j loffonotiAtaA ............................ 10
Mori A Dico W v, Itaff -
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