Document 7M9R2R8yemqz5K5gyb6gqQOp6

* i GENERAL ELECTRIC 0227^^ EX P-3111 Page 1 of 63 PCB-ARCH0748996 GE !,AL ELECTRIC G GENERAL ELECTRIC COMPANY, ONE RIVER ROAD, SC-HENECTADY. NEW YORK 1234 5 ' Phone (516) 374-2211 October 22, 1975 REAL ESTATE AND CONSTRUCTION OPERATION Hr. W. B. Papageorge Monsanto Industrial Chemicals Co. 800 N. Lindbergh Boulevard St. Louis, Missouri 63166 Dear Bill: This will confirm my telephone message to you this morning. 1) We accept with thanks your suggestion that Dr. Kaley accompany Dr. Wilkins and Mr. Ligon of our CR&D Center on their visit to the EPA laboratories at Duluth on October 29. I will inform Dr. Wilkins and Dr. Veith that Dr. Kaley will be with them. 2) The visit to Envirogenics has been set for 10 a.m. on Monday, November 17, and Mr. DesRosiers would welcome your presence if you wish to join him and Dr. Modan. 3) Enclosed are copies of GE's demand for a Bill of Particulates and the response that we received from the Department of Environmental Conservation. We would appreciate any comments that you are able to make on the responses provided by the State. The document is not as formidable as it may appear, because 1/3 of the pages (Exhibit C) are the EPA report that you have already seen. ELS :1s Enc. cc: NE Evans OF Repko AV Puccini wyfwri raw ,Dr. E. L. Simons, Manager Environmental Protection Operation nrrw SERVING PROGRESS fr ... 0227196 EX P-3111 m i .I iwp.iii.jpjndPage -2 of 63_, PCB-ARCH0748997 1 I; r? A 5 1,7 V> V *'l. in Rr. p r* r uUb v $ n Ic p. ti r* W 1 CAPACITOR PRODUCTS DEPARTMENT GENERAL ELECTRIC COMPANY, JOHN STREET. HUDSON FALLS, NEW YORK 12039 Phone (518) 747-3341 September 12, 1975 Mr. Howard Bergen Monsanto Industrial Chemicals Company 800 North Lindbergh Boulevard St. Louis, Missouri 63166 Dear Howard: . This is a Notice of Hearing and Complaint issued by the State of New York. We're going to need your help on this; Very truly yours. i . 0227197 EX P-3111 Page 3 of 63 PCB-ARCH0748998 STATE OF NEW YORK DEPARTMENT OF ENVIRONMENTAL CONSERVATION In tho Matter of Alleged Violations of Section 17-0501, 17-0511 and 11-0503 of the Environmental Conservation Law of the State of New York by: GENERAL ELECTRIC COMPANY Respondent BILL OF PARTICULARS File No. 2833 Sir: PLEASE TAKE NOTICE that tho New York State Department of Environmental Conservation ("DEC'1) as and for its Bill of Particulars herein, alleges: 1. Upon information and belief. Respondent used Polychlorinated Biphenyl compounds ("PCB's") knovm by tradename os Aroclor 1254, 1248, 1242 and 1016; the actual PCB's used by Respondent and the quantities thereof are solely ( vlthin the knowledge of Respondent. . . ( 2. Upon information and belief, the exact location of each' point source discharge is indicated in the June, 1975 report prepared for Respondent by Clark, Dietz and Associates, (the "Clark, Dietz Report"), Figure Nos. 1 and 3, and shovm as discharges 001-009. . The exact dates, specific types and quantities of PCB discharges arc solely within the knowledge of Respondent except as- shown on Exhibit "A" attached hereto and incorporated herein by reference and in-the Clark, Dietz Report, Tables 8,9,12 and 13 and Figures 10 and 13. Upon information and belief the specific types, quantities and dates of discharge used by Respondent to derive the data or estimate contained in Respondent's U.S. Army Corps of Engineers Permit Application No. 250-OJCW-2-000677 dated December- 18, 1972, wherein Respondent indicates an average discharge of thirty pounds per day total PCB'a from both of EX P-31l71229 , Page 4 of 63 > PCB-ARCH0748999 t * ' I ' 1 () i ` I | Respondent's manufacturing facilities in Hudson Falls and Fort Edward-, New York . combined and a maximum of 47.6 pounds per day from such facilities, is solely within the knowledge of Respondent. 3. The exact location of each point source is ns identified in Para- graph "2" hereof; Ihe types and quantities of PCB's discharged are given in * * - Paragraph "2" hereof; upon information-end belief the entire premises owned, operated and maintained by Respondent in Hudson Falls and Fort Edward, New York (the "Premises") are a non-point source of PCB discharge; upon information and belief PCB's have concentrated in varying amounts throughout the Premises, and are known to be concentrated ly specific type and amount at the points indicated os sampling stations identified in Exhibit "B" attached hereto and incor porated herein by reference,in the amounts and types indicated therein; upon . information and belief, the period of time during which PCB's accumulated at the l( ) , v site and the aforementioned sampling stations are only known to Respondent; upon , information and belief residual and/or accumulated PCB's from non-process and non-point sources are discharged in greater amounts during periods of vet weather as 'shown by date, amount and type of PCB in Exhibit "A"; upon information and ' belief the extent to which PCB discharges increase during other periods of wet weather* and the amounts and types thereof is within the sole knowledge of Respondent. 4. See respouses contained in Paragraphs "2" and "3" hereof; upon in formation and belief the location of the only other known sources of PCB's in ... ' . ' ' the Hudson River are: . , . NAME * SAMPLED AMOUNT TYPE Hudson Falls Sewage Treatment Plant 9/11/75 120ppb 1016 Hudson Falls Sewage Treatment Plant . ` 9/11/75 46ppb . 1242 Sprague Electric Corp. Nor lit Adams, Hass. . 9/30/75 57ppb 1016 EX P-3111 -2- Page 5 of 63 PCB-ARCH0749000 `Upon information anti belief, however, the discharges from the Hudson Falls Sewage Treatment Plant originated from Respondent's premises in Hudson Falls, New York. 5. See Paragraphs "2U and "3" hereof; See Exhibits "C", "D", "E", and "F" attached hereto nnd incorporated herein by reference for specific locations of waters, sediments nnd fish- contaminated l>y PCD's, the type and quantity thereof; Upon information and belief, virtually the entire Hudson Paver, downstream of the Premises are, in water, sediments, fish and other aquatic organisms con , to . taminated by PCS's/varying degrees. . * <*- . . 6. See Exhibit "G" attached hereto and incorporated herein by reference; which,' upon information and belief, shows the specific quantities of PCB's used - t by Respondent and all others vithin New York State in 1974; upon information and belief, data regarding Respondent's, and all others, purchases of PCB is solely within the knowledge of Respondent, such others and the suppliers and/or * manufacturers of PCB's. . * 7. Upon information and belief, the fish, birds, wild fowl, marine and terrestrial mammals and other wildlife, the specific types and quantities of PCB, the effects and period of assimilation causing such effects are all in * dicated in the references listed on Exhibit MH", attached hereto. 8. Upon information and belief, the specific types of PCB's include those homologs and isomers containing 1 to 10 chlorine .atoms, represented by the mixtures Aroclor 1221, 1232, 1016, 1242, 1248, 1254, and 1260; the exact chemical composition of each type of PCB's is within the sole knowledge of Respondent and/or Monsanto Chemical Corp. A detailed description of the PCB's ic presented in The Chemistry of PCB's by Hutzinger, Safe and Zitko (CRC Press, 1974, pp 7-40). 0227^31 EX P-3111 Page 6 of 63 PCB-ARCH0749001  l Upon in*formation and be' lief, the water solubility of some PCD mixtures arc summarized below: TYPE OF PCB Aroclor 1242 Aroclor 1248 Aroclor 1254 Aroclor 1260 4 ESTIMATED WATER SOLUBILITY mg/1 0.24 0.054 0.012 0.0027 Upon information and belief, because of the chemical similarity of Aroclor 1242 and Aroclor 101G, the solubility will be approximately 0.24 mg/1. Upon information and belief, the bioconcentration of PCB's in, for example, oysters where the bioconcentration factor expressed as ratio of the concentration in oyster to the concentration in water, is as follows: PCli CHLORINE CONTENT 2 cl 3 cl 4 cl (sym) 4 cl (asym) 5 cl 6 cl BI0C0NCENTRATION FACTOR . * 1,000 7,500 8,000 12,000 * 28,000 48,000 Upon information and belief the bioconcentration factors for Aroclor 1242, Aroclor 1248, Aroclor 1254 and Aroclor 1260, for example, in minnows range between approximately 5 x 10^ and 25 x 10^; because of the similarity of Aroclor 1010 and Aroclor 1242, it is believed that the bioconcentration factor for Aroclor 1016 in, for example, minnows is approximately 5 x 10**. ' ( ' ' . ` 0227232 EX P-3111 Page 7 of 63 PCB-ARCH0749002 * llptJli information and belief, PCB's arc much more soluble in roils than in water, c.g., PCR's (2,5,2* - trichlorobiphenyl; 2,5,2',5' - tetrachloro- biphenyl; and 2,A,5,2*,5* - pentachlorobiphenyl) are 10,000 times more soluble in n-octanol than in water. . Upon information and belief, PCB's arc highly non-biodegradable, c.g., the percent degradation of PCB mixtures in a 48 hour activated sludge treatment * * * 1 ; cycle is as follows: TYPE OF PCB 7, DEGRADATION (48 hours) Aroclor 1221 81 + 6 Aroclor 1016 33 + 14 Aroclor 1242 26 + 16 Aroclor 1254 15 + 38 Upon information and belief, with shorter periods of treatment, Aroclor 1254 was not degraded in 5-10 hours, but the PCB's were dissolved in the fats present in the sludge and were absorbed at the surface of suspended material in sludge. . - - . Upon inform ation and belief, because . * microbial activity is more intense in activated sludge systems than in most natural waters, PCB mixtures are persistent in natural waters. ` ' * 9. Upon information and belief, PCB's discharged into the aqueous environment become distributed in sediments and are available to bottom dwelling organisms for uptake into the body, See references contained in Exhibit "H with respect to * * ... * . 'sbluhility sen Paragraph "8" hereof. * . , t " 10. Attached hereto as Exhibit "E" and incorporated herein by reference are the specific locations of each Hudson River sediment sample completed to date, the ( ; specific types and concentrations of PCB found therein. EX P-3111 Page 8 of 63 PCB-ARCH0749003 11/ Attft&licd hcvcto ar. Exhibits nCMf t1Dr,l "E'1, and MF'r one) incorporated* herein I i * by reference is a tabular description and quantification of specific instances of Hudson River despoliation and degradation, including its waters, sediments and fish. Upon information and belief, the degradation and despoliation have occurred over at least the past twenty years. " . t ! 12. See Paragraphs "2" and "3" for a description of each discharge, the date, V . _ location, type and quantity of PCB's. Upon information and belief, knowledge as to any other discharges, the dates, types and quantity thereof are solely within the knowledge of Respondent. . Upon information and belief, these discharges represent a hazard to human health because the PCB's so discharged are bioconcentrated In aquatic organisms. Including edible fish, to levels above five parts per million (ppm). The United States Food and Drug Administration ("FDA") has established 5 ppm PCB's as the > 1 level above i;hich fish should not be eaten because of the toxic effects of PCB's (see government's Exhibit 3 for identification)'. Upon information and belief, research studies have shown 'the toxic effects of PCB's in subhuman primates (Exhibit "11"). Upon information and belief, due to the non-biodegradable characteristics of PCB, the environmental contamination shown by Exhibits "C", "D", "E", and "F", attached hereto, the discharge of PCB's has and continues to cause irreparable damages to the Hudson River water and aquatic organisms. Upon information and belief, this environmental contamination exists continuously to varying degrees throughout the Hudson River (below Respondent's manufacturing facilities) and the coastal waters of the state. . ' Upon information and belief, because the aforementioned discharges cause nnd/or contribute to the concentration of PCB's in edible fish, such discharges EX P-3111 Page 9 of 63 PCB-ARCH0749004 ( ; r render Cite cw.cucrcinl. fishing resources of the Hudson River unnprkot<ible\ . The ' * * name, address, location and description of each comaiercial end recreational interest is unknown to the Department. 13. FDA has promulgated rules and regulations limiting the concentrations of PCB's (of any type) in certain foodstuffs, including fish and certain fish products; the United States Environmental Protection Agency has proposed water quality criteria which would establish 2 parts per trillion of all types of PCB's in waters as a Water Quality criteria under the Federal Water Pollution Control Act Amendments of 1972 (33 U.S. Code 1131 et seq.); the Advisory Board of the Inter national Joint Commission on the Great Lakes has recommended a concentration for all PCB's in fish in the Great Lakes of no greater than 0.1 ppm. , 14. Upon information and belief, such information is solely within the knowledge of Monsanto Industrial Chemicals Corporation, (`'Monsanto") Respondent and others * * ' _ purchasing PCB's from-Monsanto. . . ' , -- . : t * *. . - - . ' 15. See government Exhibit 3 for identification for the exact text',' time, date of the FDA determinations. Upon information and belief, the FDA has sole knowledge of the other information requested. 16. See Exhibit "F"t attached hereto. * ' ... 17. See Paragraphs "2" and "3" hereof. IB. See Exhibit "I" attached hereto and incorporated herein by reference. * t * 19. Upon information and belief, the discharge of any type of PCB's in amounts, together with background, which will result in excessive levels of.any type of PCB in fish will impair the receiving waters for their best usage, i.e., fishing. -- -7- 0227235 EX P-3111 Page' 10 of 63 PCB-ARCH0749005 . y * * f y * ' 20. See Paragraphs "2" and "3" hereof; Upon information and belief, these discharges, together with background, cause the receiving waters and the waters into which the receiving waters flow to be impaired for their best usage. 21. See Paragraphs "2" and "3" hereof; Upon information and belief, the dis- charge pf FCB's- by Respondent, together with background, has and continues to be in quantities injurious to fish life and protected wildlife and waterfowl and/or the propagation thereof, . Dated: October 14, 1975 . . . ,(4 } . ` . 1 Yours very truly, New York State Department of Environmental Conservation 50 Wolf Road Albany, .New York 12233 , ' Philip H. Gitlen Assistant Counsel (518) 457-6695 ' 0227236 EX P-3111 S" Page 11 of 63 PCB-ARCH0749006 STATE OF mi YORK ) ^ ss* s * COUNTY OF ALBANY' ) - . ' f Eugene Seebald, being duly sworn, deposes and sayst That he is Director of the New York State Department of Environmental Conservation, Division of Pure Waters, and is acquainted with the facts and circumstances of the above entitled action; that he has read the foregoing Bill of Particulars and knows the contents thereof; that the same is true to his knowledge except as to the matters therein stated . I to be alleged upon information and belief, and that as to those matters he belieyes to be true. I () > * * * (.* V .1 . * :* 1. v + * t_ *j*y .* .v 0227237 EX P-3111 Page 12 of 63 PCB-ARCH0749007 . - * 1 General Electric Company Hudson Falls (T), Fort Edward (X), Washington County C On-Site Effluent Monitoring Program for PCB's Dates: August 19-26, 1975 - Time Spaix All samples composited over the full length of the operating day.at both plants. . ' Personnel Involved: Representatives of Region 1I-EPA and New York State DEC - Division'of Pure Waters Location: .See attached drawings ' . Samples Analyzed By: EPA laboratories - Edison, New Jersey A. Summary (lb/day as Aroclor 1016) Fort Edward Plant 8/19 Gross Discharge Intake Level Net Discharge 0.11 0.40 -0.29 8/20 0.90 0.18 0.72 8/21 1.14 0.19 0.95 8/22 1.32 0.25 1.07 8/23 (1) 1.04 0.10 0.94 8/24 (1) 0.24 0.21 0.03 8/25 (2) 5.51 0.23 5,28 8/26 (2) 4.79 0.17 4.62 Hudson Falls Plant Gross Discharge Intake Level Net Discharge (1) (2) (2) 0.50 0.19 0.10 0.26 0.16 0.09 0.19 0.40 3.40 0.47 0.87 0.60 0.36 0.79 0.30 0.79 -2.90 -0.28 -0.77 -0.34 -0.20 -0.70 -0.11 -0.39 Total Gross Total Net 0.61 1.09 1.24 1.58 1.20 0.33 5.70 5.19 -3.19 0.44 0.18 0.73 0.74 -0.67 5.17 4.23 Average Gross: 2.12 lb/day Average Net : 0.96 lb/day Notes : (1) - Plant not in operation (2) - Rainy weather 0227238 O . . mwm "A" ., ................. Page 13 of 63 ex P-3111 PCB-ARCH0749008 b. Comp left? Sapling Data * All concentrations are expressed in tnicrograrus/liter as Aroclor 1016. All flow are expressed in MGD. ( >rt Edward Plant 8/19 1. Intake Well (cone.) 60 (flow) 0.79 (lbs) . 0.4 8/20 8/21 28 - 28.8 0.79 .,0.18 0.79 0.19' 8/22 38 0.79 0.25 8/23 42 0.29 0.10 8/24 84 0.30 0.21 8/25 35 0. 78 0.23 8/26 25 0.80 0.17 2. 004 (cone.) 16' .. (flow) , 0.79 (lbs) 0.11 137 - 173 0.79 0.79 0.90 1.14 201 0.79 1.32 430 0.29 1.04 95 0.30 0.24 847 0.78 5.51 71 0.80 4.79 Hudson Falls Plant 3. Intake (cone.) (flow) (lbs) 340 1.20 3.40 52 1.08 0.47 88 1.18 0.87 54 1.33 0.60 35 1.24 0.36 76 1.24 0.79 27 1.33 0.30 67 1.41 0.79 4. 002 (cone.) (flow) (lbs) 34 1.03 0.29 '24 0.88 0.18 10.4 0.98 0.085 27 1.12 0.25 17 1.07 0.15 9.4 1.07 0.084 20 1.10 0.18 39 1.17 0.38 5. 006 1 1 (cone.) (flow) (lbs) 6.8 0.072 0.004 3.3 4.5 (all days) 0.002 0.003 4.1 0.002 3.1 0.002 2.8 0.002 3.7 0.002 4.3 0.00 6. 008 - No PCB's detected. Sampling stoppe<i after 8/21. 7. 003A - (cone.) (flow) (lbs) 255 (1) 0.21 8.6 . * * 10 * (1) (1) 0.007 0.008 11.6 0.11 0.011 1.8 0.07 0.004 2.5 3.9 0.07 0.129 0.001 0.004 10.8 0.12 0.01 B. 003B ' (cone.) (flow) (lbs) 3.2 2.4 2.8 5.0 5.5 0.03 0.03 0.03 0.03 0.03 0.0008 0.0006 0.0007 0.001. 0.001 1.1 9.5 4.5 0.03 0.03 0.04 0.0003 0.0024 0.00 Notes (1) - Not available M <0 !*. > fO ( 0227239 EX P-3111 Page 14 of 63 PCB-ARCH0749009 General Elcc trie Company Hudson Falls (T), Fort Edward (T), Washington County C J On-Site Soil and Storm Runoff Sampling for PCB's Date: September 25 1975 . . Fittie Span: 3:30 - 6:10 P.M. Personnel Involved: L.J. Nadler, T. Chung - NYSDEC ' Division of Pure Waters (1) . Locations: See attached'drawings and description Samples Analyzed By: N.Y.S. Dept of Health at Griffin Laboratories Soil Samples Sample Number 11 PCB 702. 11 PCS 703 11 PCB 704 11 PCB 705 11 PCB 706 11 PCB 707 11 rCB 70S 11 PCB 709 11 PCB 711 11 PCB 712 . Plant Specific Aroclors 1016 1254 F.E. , 57 90 F.E. * F.E. 2800 F.E. noo >100 u? 87 H.F. *' H.F. 900 H.F.' .H.F. H.F. 3400 760 24,6 * 14 F.E. - Water Samples (gra b) " (microgrems /gram.) . 1221 0 630 ' 173 259 217 ` 0 _ ' Sample Number Plant Time Specific Aroclors 1016 1254 (micrograms/gram) 1221 . 11 PCB 701 11 PCB 71 0^) F.E. H.F. 3:30 P.M. 5:45 P.M. _ . Notes <1) - Mr. U. Marquis and Dr. R. Stengler of General Electric accompanied and received a duplicate sample at each location. (2) - Instantaneous flow measured at 0.93 gal./min., using watch and bucket. ' KXimilT "J>" 02272<, EX P-3111 Page 15 of 63 PCB-ARCH0749010 ; '-. (1) 11-7CC-711: y.'iiR i3 n tr * *'star sample i jkt r. Seen a io: ttrni.'. i.i ;<u i>ii.it pr-?->rt;; efte- ror-Apic* tie i'ritJnf. CJiyJii e-pX.Ii.-iiip.-i piartiii appzsslaatviy J:J3 p;s. Jl-.'CS-7'Jii 7alr is o oiJ ai,vlc tait-a aJJm.vr.t to cto Jaai'iii; deck. ' t3) JI'.'Ci'7J)i 7Mi is A vail saople talit in tio JU-ic.'i tide area ct d pat;ai a;j;iroiiajce-Jy JSi&i/t /rtj tia poerieecc cosr.cz of .tA* XVncr InjiMtei! P/i tis et:ae.kod ir.iwX/-..;.:, . 4i! eu a Oicec c Jitio wXtA tip part era aiAo oi tip fosse. NX U-J'W'JWi riii io e spli Sioyio taica Ciractlg beneath Civ Ppvcnol naincitjil} area. fSJ JX-rci-7f<5.- S-AXs Xs A ociJ soapjp titan t'JrcatXy adjacent to the solid vesao ccrrpavtez locatai! cast to tho i-if-ratai tttiiczsUny 4a, - fiX 11-PC0-7Itt rate to o.i soil couple takes oa tip CJSC clCo of /.Uvji PeraaC Sue pcvt.pf cio ;J,it, ei-.tl fiwcJi- across tho attest tror, s eiayara X.'aisirlc sub-atatloa. ?522L-i"Lii: . * > ' (7) 1J*JC!I'?W/ TAio is a soli stipple talien at a spot located eAoyt CO test (too c soar toot of baJldlmj IS, and on tie caster !ise of tip cite. (SI H-7C7-797. rjiJa Is e soil aar.ple tiAcn adjacent to* tip tolls itaste coopactor Jocuiocf pact Pf IciitUr.j Hi P.pprorltrials S iscnos of prevpi were oler.td aujp te cx;a soil, (91 11-TC3-7M i This is a Coll uitrple taitu i/otuuss tiro track eJJinfs adjacent to tic P-jscnol unlosSia-j urea. ' (J3J 07-7031 Title Is a soil tstiplc tcjtcn in tip soctiiurst comet of tho tank Cats adjacent .to c platrorn or. tie nortfc tieo 05 suilclr.ij 31. /tpprculnscol y <C incites of jravpl veto clesroJ away to expose soil . _ (H) ll-VCS-yie, ?ii* la c yraA water asT.ple from dioc!,c fyc 097.' Panplvi- fare eeiieeicJ i.i p plastic badei lore SoJ i|.- ro;vf, l^-lincis; ..t spproxlnataig 5j<5 (. The samples apponretl hl;hlj terolJ and contained cowii-ic table jsdinsne. After collection of tin xar.pla, a crin'.j osassreaca: cf die (loir van izaio Ay celicetlt; tlu (ail 2cci.arja tsu:i c.v.o pipe for a parlui of }j soesaio. T2.0 volctta collaatni during till U fario.T rtw AiticctvJ ct 1,77 Hints, usinf tas scale on site ir.siJit surface of tie hjenoe. This ttlsckat'je Is repotted to p-nt.'.lr OiliJ scope cater, (he ample i>ec epjiuccpi or. tho teco.iJ of tiro cenracotivo days et rainy uastntir. . - * fJ.'X 12-id:-? 11; This is c Jill! ear-pin collected Jest set si tie pczlii -; lot *cr of fat.>j n il Carporatta.:, about c-.-.a-cvertur title mnith of t.V> plant. ct> f.lien- iiztfet. Q2111HI EX P-3111 Page 16 of 63 PCB-ARCH0749011 (itiO^CiVAf EX P-3111 Page 17 of 63 1 Dale ! Summary of Hudson Kiver 1 >C :1 Sampling at Stale Duck . ** * * Fort Edward Village $ , * ' A;;enc y PCD-1016 (p:>b) Flow (els) Pounds Per Day (}0-'6 8/13/74 12/4/74 1/14/75 2/11/75 3/11/75 4/8/75 4/26/75 8/11/75 ,.. EPA DEC DEC dec DFC DFC ' DFC DEC 2. 2-3,1 (2.77 mean) 3.0 _ 2. 5 1. 3 1.5 - 1.5 1.7 ' 1. 5 3.260 .6,000 7. COO 5,000 5,410 3,160 U,`l00 3,120 49 97 * 94 35 ' 44 26 102 25 upstream samples collected at the. Portland Cement Bridji c in Glens Faft1; contained less than 0.1 ppb of PCLl-1016. KXtlllilT "n" %x\x EX P-3111 Page 18 of 63 PCB-ARCH0749013 P ortl East c o O' c i os i o N 3 in >1 o U eo o CO H t; * -* 2 to DSr *o/* 1 O OJ 1 fO rj 00 ft *1 X O V. S3 U P S ** nr: a; EX P-3111 Page 19 of 63 PCB-ARCH0749014 PCB-ARCH0749015 EX P-3114 PagefZQ'Of 63 ! > ,,Sa' r*i e> L\ l: J5; X1 1*1 . oSJ n13 41 . 1*. o O * *. *t:. * \ f; if] *u oc 1 ** f:; ni. ** * >t-* fj co 4 *- CQ rs o> r1* Pi ll f Uor:t O r,-<'* r: t00 C*--*4 *V 4J wo V) .r. o o P v< on (0 *C*l t\3 EX P-3111 Page 21 of 63 PCB-ARCH0749016 h o O) 's|h o I O m < GO o 0_ Wrt4) if. r-a n. a. , ni: fi tn: ji ct ar .: 0227248 . - EX P-3111 Page 23 of 63 PCB-ARCH0749018 riuyeuioi j n.iiuti r,j pneny L An.ijyiicui Results; Results of Analysis on Fish Flesh 'fit** rhiiuion 1 :mi.11 ys i:: o f edible fish flesh except whore whole fish ill*- iinlir.'ildll (1(1 III'* I Inched tl.'lL.-! .`.hcotu, tor polychlorinated biphenylc C (I'lai's) w::; ronduc-li.! at three lobocatorics on those fish obtained nt severa 1 r.triiioti:. given below. Tin; inmodLate* supervisor of all analysis at each Laboratory is also provided. ],nboralory_ Loco 1 (on KYS Dept, of Environmental Conservation Rome Pollution Laboratory B31A Fish Hatchery Hoad Kooe, NT 13440 C KYS Dept. of Agriculture. and Markets Slate Food Laboratory Laboratory lluilding 7 1220 Washington Avenue Albany, Kew York 12235 Supervisor Karl J. Harris Dr. Elmer George, Jr. Director . Water Stationf s1 Hudson R. , , ' Above Corinth Above Glens Falls At Ft. Edwardbclow G.E. 5 miles belcw Ft. Edward Stillwater Catskill-Trib. 193 Kingston-Rh ir.eclii: Bridge Mouth of Uappinger. Creek Mouth of Rondout Creek Mouth of Esopus Creek Tappan Zee Bridge George Washington Bridge area Hudson R. Mohawk R. *, Rondout Cr. Waterford Little Falls Below Schenectady Bloomington KYS Dept, of Health Division of Laboratories and Research Griffin laboratory Guildcrland, NY 12084 Dr. Brian Bush Walloomsac/ Hoosic R. Walloomsac River in Hoosic Hoosic River above Johnsonville A copy of the analytical procedures used by each of the Laboratories is attached as Appendix A. The calculation sheets, analytical reports and chromatographs pert a ini up. to the analysis of fish at the above stations are available at each respective laboratory for inspect Lou. . Tin: data Lola ling to dates of collection, location of collections, species of fish and numbers of each species of fifth analyzed, length and weight of each fifth, idem i f ical ion of each sample of fish, liit: I'Ct'i content of the fish analyzed, and if pmvided,. t he oil. and DDl' content, of Lite I ish analyzed, is given on the allachi-d La hies numbered 1 thru ?1 . ( ' . . EXHIBIT "F" EX P-3111 Page 24 of 63 PCB-ARCH0749019 I t*' '* ' C>*naii*>lon data cooto iued in Tables J. thru 21. Kii.lt aualy/.i-J l>y the R>:ite Pollution Laboratory in the initial sampling (July 2`< thru Crptimber 5, 19/0) wht weighed and measured by the? Laboratory ^ and, in most instances, by Lhe Regional personnel who captured the fish. The l(:u{;ths and weights reported on the attached data sheets are those obtained by tbe Rome Pollution Laboratory and converted to decimal form. This procedure was usc?d so as to obtain consistency in reporting of these measurements. The lengths, and weights reported on the data sheets do not necessarily correspond vIth those obtained and reported by the Regional personnel collecting the fish samples. This is due to shrinkage of the fish as a result of freezing prior to analysis. The length and weight information on fish analyzed by the Deportments of Health and Agriculture? and Markets are the data reported by the Regions collecting, the fish samples and converted to decimal form where appropriate. Lengths and weights reported on the data sheets for the second sampling of fish (September 16-18, 1975) are those obtained by the regional personnel and converted to decimal form, where appropriate. . EXP-3Ha Page 25 of 63 PCB-ARCH0749020 PCB-ARCH0749021 EX P-3111 Page 26 of 63 PCB-ARCH0749022 EX P-3111 Page 27 of 63 PCB-ARCH0749023 02*7253 EX P-3111 Page 28 of 63 \ o *1 tr *n-> ro> *o* ftJ KA, -^C r^i c * n YAlu.t *o>* U -h*t>:i ** IM *rTi ! % u r rf :> 3' w r, * Cl. ST jj as . d SI B4 vo io 5w AM a O -3 - 3 M 1 02212`>`' EX P-3111 Page 29 of 63 PCB-ARCH0749024 PCB-ARCH0749025 EX P-3111 Page 30 of 63 { ' . . . _ 0227256 EX P-3111 Page 31 of 63 PCB-ARCH0749026 PCB-ARCH0749027 EX P-3111 Page 32 of 63 PCB-ARCH0749028 ( ' EX P-3111 Page 33 of 63 PCB-ARCH0749029 EX P-3111 Page 34 of 63 PCB-ARCH0749030 EX P-3111 Page 35 of 63 PCB-ARCH0749031 ouiibi EX P-3111 Page 36 of 63 PCB-ARCH0749032 EX P-3111 Page 37 of 63 EX P-3111 Page 38 of 63 KuiUen S itrr ?CS r ~ . i V / i i t S ttu lc t (A ftily s U by Roa P ailueiar. la b o rjc a ry ) "A 311 13 PCB-ARCH0749034 Si *1 a: - u ii < 4: 0 < * r; * ' n' % * * i i! t II 1 V *- ** 41 ) fv rr;j *. 1 >> *1 *4 % t: . M Hii i r> Hi m . r n H* n ** 11 tl 4 * 4> * *1 rt 1* *: i. ti I O 11 -t it . . *' < w *n -0 ;1 V t.11 r; ti . <: t-; * ( * /. ij M *- At u *1 n t 1 ,v2j" * r,l I* 022726* EX P-3111 Page 39 of 63 PCB-ARCH0749035 0227265 EX P-3111 Page 40 of 63 PCB-ARCH0749036 PCB-ARCH0749037 PCB-ARCH0749038 PCB-ARCH0749039 69ZIZZ0 3U o y * o roos r..*\1*' t( * * iCtl A O70*O' 03o? r*-* 'AH* ?c *UO *S-J SM'f fI* rr t-dj -f>*t ' 1 MrO-** HH>>l ys `c! >t >; M O o P (?, U<:l O l< VIO* O(ii <* *o *o c- 'A O* 'JO'VM* * fll 'C on tT rW M H u*** W fJ - o o o t' o l' M ?au !x!* ii7?(1 . 3 3 ;y :< I 4 )M *T1 -t *&i u y !! EX P-3111 . Page 44 of 63* PCB-ARCH0749040 EX P-3111 Page 45 of 63 PCB-ARCH0749041 EX P-3111 Page 46 of 63 kondout C(Mk K 3 A n ily ill (A n jly li by D epjrtcine o f A g ricu ltu re in i X ivkots) EX P-3111 Page 47 of 63 PCB-ARCH0749042 viiiuii - i'.o;r.c I.aLioril'*cy, /. * I. Extract oil on soxhlct* _ ' II. Alkaline Hydrolysis . t I. Weight cn. I g. sample , - , ' i. A<M *.w- mI ' ' I- II " 3. ' Add I ml KOtl 300g7200 ml H,0 \ ' , 4. Heat Irt waterbath 5 min. 0 77C . 5. Shake7 stopper7 retum to waterbath. Shake 2x more In remainder of 30 min. * * . 6. Allow to cool ' 7. Add 10 ml 20 * i . 8. Add 10.00 ml benzene . ` ( 9. Shake 10 minutes on mechanical shaker ' . 10. Remove AQ. lower layer * II, Add t^SO^ anhyd. to dry benzene fraction III. Dchydrochlorination . ,, . 1. Take 5 ml of benzene fraction , * , * . \ 2. Add 5 ml benzene ^ . . 3. Add boiling chip 4 4.` Add .25 ml DBU soln. (57. w'v in benzene) Aldrich 13,900-9 1,5 diazobicyclo (5,4,0) undec-5-ene . . * ,, - . 5. Place in bo.iling water batlv until benzene is boiled off . 6. Rotate tube while cooling to remove traces of benzene IV. 1. Add 5 ml chromic acid reagent to tube (5 g. CrO^* + 3 ml !l20 + 60 ml CUj COOII.) . , % * , 2. Stopper and place in water bath 75 - 80cC for 10 min. ` * _ 3. Cool in cold water - * ' 4. Add 20 ml l^O/swirl to mix * - ' .. , . 5. Add 15.00 ml hexane ' 6. Shake 1 minute or 5 minutes on mechanical shaker 7. Withdraw lower AQ layer . 8. Add 20 ml 1^0 EX P-3111 .* Page 48 of 63 PCB-ARCH0749043 Jirtliim * ').* Shake 20 see, . lU. V; i tlid raw AQ layer It. Add"20 ml ll20 12.' Shake 20 see. 13. Withdraw layer completely 14. Add Ha2 S0/t to dry hexane fraction *. * . V. Chromatograph- on K.C.C.C. * Fish samples are ground three times in a Hobart Food Chopper and thoroughly mixed in a Hobart Planetary Mixer. An accurately weighed sample ot approximately 50 grams is then lyophilized. Tnis freezedried material is then extracted in a Soxhlit Apparatus with hexane. 0227274 EX P-3111 Page 49 of 63 PCB-ARCH0749044 . - to I vclilm- i natcd I i plu ns'I.:- in [ i^h * i * " . ; . t M r 1 l.qnipm'Ut . . '`iben'ents-'see J AM 1 120-1.23 k'piipmmt - mm: PAM 1 l!U-J.lf Varittn Aevograph I.HDO Gas r.hroKuttugruph - F.C detector with tritivun source. G' x 2 mm i.d. glass column with U.M`.o fill 30 on GD/SO Gnu Ghrom 0. Column temp. lcH^C, Injector temp. 20fjC, Detector temp, 2USC, Carrier gas D2 30 ml/min. I'Jii'U'AViiU.'ili ' Small .1 ish under IV - Remove 'ami discard head and viscera; grind with tails - tiij;uc times`thru gr indcr. Medium fish above 1T>" - Remove and discard bead and viscera; cut J engthwise along backbone and grind one-lialf of the fish - three times thru grinder,. extremely large fish - Cut off caudal section at anal opening, cat lengthwise a lung backbone and grind one-half of the section - three times thru grinder. Extract ion PAII I2L2.Ua ' * ' ' Weigh SO grams of prepared sample into a high speed blendor jar and add 200 ml acetonitrile. 111 end at high speed for 2 min. and filter through a funnel containing a loose plug of glass wool into a 2S0 ml graduated cylinder and record volume (I'J. . - Transfer measured filtrate to a 1 I, separatory funnel. Carefully measure Jill) ml hexane into the same graduate and pour into the separatory funnel. Shake vigorously 1-2 min. Add 10 ml saturated N'aCl soln and about 600 ml 11^0 and mix thoroughly for Mf see. hot .layers separate, discard the aqueous layer Mind gently wash the solvi-ut layer with lwo 100 ml portions of ll^O. Discard w; :hing,;, transler solvent layer to a 100 ml glass stoppered graduate and record volume (P). Calculate the grams (G) of sample to be placed on Florisil column os follows: . . C * S x ( F/T )*x ( P/100 ) (1) S grams of sample extracted - . _ f = volume of acetonitrile extract filtrate T *= total volume pul H^O in sample + ml acetonitrile added - correction in ml Toe volume: concentration) Contraction volume of 5 ml is used . . for HD-9S ml IIJV2UD ml acetonitrile. In this equation the water content of fish my he assumed to be liU%. ` .. P *= ml of hexane extract recovered ` ' Column Chromatography PAM I 21J.lMd . " * Prepare 22 mm i.d. column with the amount of activated l'iorisil dictated by recovery studies. Top rioris.il with about J/2" anhydrous Ha2St)(j. Prcv;ct column with MU ml hexane, Place Kudcr.ina-Danish concentrator with graduated collection vessel under column In receive cluutu. ` ' To the J.DU ml. glass stoppered graduate containing the hexane from the parti tioning step, add l.r> gm anhydrous DapSOq and shake. Do not lot extract remain with Hamblin. Transfer solution to Plorisil column. Rinse graduate 3 times with S ml hexane and add to column. When solution has sunk into column, rinse sides of column twice with S ml hexane, flute column at about S ml/m.in with 2bU ml G"S elhyl ether/hexane eluant. Remove R-l) apparatus and add porcelain boiling chips. Place glass trap on top and concentrate Lite eluant to 10 ml volume on the steam 0227275EX P-3111 . Page 50 of 63 PCB-ARCH0749045 2 - fliiilh. This is the assay solution. ' * Gas tiliiiiaUm* t -iphy ' . Inject a T' iti aliquot oC the assay solution .into the.Gos Chromatograph ( / and compare the retool ion times of Lite subsequent peaks with those of a nuRahle standard whose peak heights are within .10,\> of the injected sample, Quantitate the peaks on the basis of their peak heights. . Pa 1 on 1 ation # Results shnuL4j.bc reported in terms of parts per million PCH's in the product. . . Let /\ ".sum oC heir,fits oT standard's peaks in millimeters ll sunt of heights of assay solutions peaks in mii.limetcrs C " nunogeams ol standard represented by peak heights A / Then ( ll/'A ) x C.- uniiograms of |`CU _ (H) represented by the peak I heights in the assay , ' solution . Prom o(|nation (.1), G = grams oT sample pteed on F3.oris.il column which is also the grams of sample represented by the 1U ml assay solution. Let Y = ui id* assay solution injected . 7, = C./lt), gms of sample per ml assay solution or mg sample per ul of assay solution. . * . * _. ; Then Y x 7. c mill -ig firms of. sample represented (3) . in the amotuit of assay solution injected . Combining equations (2) and (3J with .the definition of ITM: i H/A ) x C _ ppm PCH ' Y x 7* in the product . . . .. John J. flaxstadt Associate Chemist 9/1U/7S HYS FOCJD l./iPOJl.'TOHY Stale Cerjnin - 1 c.Voratery Bldg, 1*120 Washington Avcuuo Albany, HV 2223d * 0227276 EX P-3111 Page 51 of 63 ' PCB-ARCH0749046  ` Ann lysis Proccduc* s and Techniques - Department of Health, Griffin l.abordtocv* . Glean up'procedure for tissue in I'Cll .`nmlysis Soxhlct extraction . 1. Weight 5 g of tissue which have been filleted, ground and composited. 2. Mix well with 15 g of anhydrous Na^SO^ in a 50 ml beaker. ` * . , 3. Transfer to an extraction thimble, (25 X 80 nan, single * thickness). ' 4. Add BO ml of hexane - acetone (2/1) mixture and some glass beads (about 50) to the bottom flask. 5. Set tbc flask on the heating mantle with the soxhlet extractor and condenser In place. * 6. Turn on the water and the power-stat. (setting at 50). Reflux for 12 hours. 7. At the end of refluxing, let the solution evaporate to 5 ml. 8. Add 25 ml of CrO^ mixture (prepared by dissolving 9 g of . CvO-j in 6 ml of water and adding 50 ml of glacial acetic acid). Heat at 90-100 C for 45 minutes with stirring. . ` . ` 9. Pour the oxidation product into a 1/2 liter separatory - `funnel. Add 100 ml of water. . 10. Add 25 mi of petroleum ether. Shake vigorously for two minutes and allow for phase separation. After removing the aqueous phase, transfer the ox. phase into a 125 ml flask. 11. Repeat the extraction (step 10) three more times with 15 ml of petroleum ether. 12. Combine the petroleum ether layer in the same separatory funnel, rinse the 125 ml flask 3 X 5 ml petroleum ether. . Discard the aqueous phase. . * , 13. Filter the petroleum ether solution through anhydrous I.'DjSO^ to remove any moisture. Collect the filtrate in a Kauuma-Danish evaporator. * ` 14. Evaporate to 2.5 ml. ` ' 15. Transfer the extract to a vial for gas chromatography ` analysis. . , 02*lZ7EX P-3111 Page 52 of 63 PCB-ARCH0749047 . 16.. The vial is loaded into1 the ;.n: chromatograph sampter " r-qr consul. The column is 2 i cron l. on Gnr.-Oiro-.no Q, G ft. <->(11:1111, temperatutu 185 C, *liw rate 45 ml per minute. 'Hie integrator ami c-mputer have Goon cal.il>rated with a mixture of 1221 pLus 1016 plus 1256 (1:1:1) using BilliC as an external sl-,,'darJ- . p - we 17. Tito area of the first peak retention time 0.77 minutes is used to estimate 1221. The next 2 peaks (1.80 and 1.55 . minutes) arc used to estimate 1221 plus 1016. Peaks with retention 2.04, 3.17 and 3.98 arc used to quantitate 1016j with-peak retention time 6,63 used to estimate 1016 plus I254f and peaks with rctuntion time 5.97, 7.61, 6.53, 10.95, 11.63, 13.89, 16.01 and 18.60 minutes are used to quantitate ** 1256. Hie mean of the estimate given by each'peek is used ` to determine the total quantity of 1016 or 1254. . 18. ' Calibration is effected by computing unique peaks relative to n mass of 5.0 ug/g of fish and whereas combined peaks ace calibrated with respect to a mass of 10 ug/g of fish. The unique peaks give a better estimate of the quantity present than the combined peaks which are used only as a check on the analysis. * . , 19. Results arc expressed as ug/g wet weight of fish as Aroclor 1016 and as Aroclor 1254. The total PCD present is determined by adding these two estimates. ' ( 0227278 * EX P-3111 Page 53 of 63 DrR_ARnH0749048 t PCM! USER Ceneral Electric AMOUNT ISKD (197A) 520,000 gallons Niagara Transformer Corp. 40,000 gallons York Capacitor Corp. 50,000-70,000 gallons R. F. Interonics - 1,000 gallons Axel Electronics 500 gallons (t EXllUilT "C" 0**7279 EX P-3111 page 54 of 63 PCB-ARCH0749049 Abrahamson, L.'J. nnd J. R, Allen The biological Response of Infant Nonhuman Primates to a Polychlorinated Biphenyl Environmental Health Perspectives, June 1973 Allen, J. R., D. M. Norback and J. C. Hse Tissue Modification in Monkeys as Related to Absorption, Distribution and Excretion pf Polychlorinated Biphenyls "Archives of Env. Cont. and Tox. Volume 2, No. 1 , 1974 Allen, J. R. Carstcns la Barsotti Da - Residual Effects of Short-Term, Low-Level Exposure of Nonhuman Primates to Polychlorinated Biphenyls Tox Aj>pl Ph 30 (3) :440 74 19R - Allen, J. R., L. J. Abrahamson and D. H. Norback Biological Effects of Polychlorinated Biphenyls and Triphenyls on the Subhuman Primate t , Env, Research, 6, 344-354 (1973) . Allen, J. R. . ` + + " Response of the Nonhuman Primate to Polychlorinated Biphenyl D:posure . , . Research Activities at Regional Primate Centers Federation Proceedings, 34:8, July 1975 Allen, J. R. and D. 11. Norback . . Polychlorinated Biphenyl- and Triphcnyl-Induced Gastric Mucosal Hyperplasia in Primates * `. Science, 2 February 1973, 179: 498-499 - * . * ' , ; \ 0**7280 . : "EXHIBIT H" EX P-3111 Page 55 of 63 PCB-ARCH0749050 Alien, J. R., and L. J. Abrahamson . Morphological and Biochemical Changes in the Liver of Rats Fed Polychlorinated Biphenyls ' Archives of Env. Cont. and Tox., ,1:3, 1973 , Aulerich, R, J., et al Reproductive Failure and Mortality in Mink Fed on Great Lakes Fish J, koprod. Fort., Suopl. 19 (1973), 365-376 i Begley, George E, and Eugene Cromartie Elimination Pattern of Aroclor 1254 Components in the Bobwhite Journal of Chromatography 75(1973) 219-226 . Bailey, S., and B J. Bunyan ) ir Interpretation of Persistence and Effect of Polychlorinated Biphenyls in Birds . ( Nature, Volume 235 March 3, 1972, pp 34-36 Barsotti, D. A,, R. J. Marlar and J. R. Allen _ Reproductive Dysfunctions in Rhesus Monkeys Exposed to Low Levels of Polychlorinated Biphenyls (Aroclor 1248) No date of reference given Barsotti, D. A., and J. R. Alien Effects of Polychlorinated Biphenyls on Reproduction in the Primate * Federation Proceedings, 34, 338 (1975) fr - . . onTM*' EX P-3111 Page 56 of 63 PCB-ARCH0749051 -3- BLdlcman, T. F., and C, E. OIney C Chlorinated Hydrocarbons in the Sargasso Sea, Atmosphere and Surface Water Science Volume 183, February 8, 1974, pp516~518 Bourquin, A.W. Cassidy S - Effect of Folychlorinated Biphenyl Formulations "on Growth of Estuarine Bacteria . t Appl Miccob 29(1):125 75 N 10R Bruckner , J. V. ontj K. L. Khanna and 11. H. Cornish . Effect of Prolonged Ingestion of Polychlorinated Biphenyls on the Rat Fd. Cosmt. Toxical, Volume 12, pp323-330, Fegatnon Press 1974 Bush, B., F. D. Bal:er, C. E. Tumasonla, Fa-Chun Lo and C. L. Houch * * ' Modification of the Homolog and Isomer Composition of a Polychlorinated Biphenyl Mixture During Passage Through Two Biological jSysterns International Symposium - Environment and Health CEC - EPA - WHO Paris June 1974 ' Cooley, Kelson J., J. M. Keltner Jr., and Jerrold Forester The Polychlorinated Biphenyls Aroclors 1248 and 1260, Effects on Accumulation by Tctratrymena Pyriformis Journal of Protozoologists, 20(3) 443-445 (1973) 1 * . Dibshith, T. S. S., W. Rockwood, R. Abraham and F. Coulston . * ' % Effect of a Polychlorinated Biphenyl (Aroclor 1254) on Rat Test Experimental and Molecular Pathology 22, 376-385 (1975) ' * Fishbcin, Lawrence. * * ( Toxicity of Chlorinated Biphenyls . - * < Ann. Reviews of Pharmacology, Vol, 14, (1974) 0227282 EX P-3111 Page 57 of 63 PHR-ARCH0749052 -4- Haller, M. T. Johnson HE-Acutc Toxicities of a Polychlorinated Biphenyl (PCD) (. and DDT Alone and In Combination To Early Life Stages of Coho Salmon (Oucorhynchus-Kisutch) J Fish Res 31(9):1543 74 15 R Hansen, D. J., P.R. Parrish.andj. Forester ' Aroclor 1016: Toxicity To and Optahe By Estuarine Animals Environmental Research 7, 363-373 (1974) Hansen, 1). J., P. R. Parrish, J. I. Lowe, A. J. Wilson Jr. and P.D. Wilson ' Chronic Toxigity, Upstate and Retention of Aroclor 1254 in Two Estuarine Fishes Bui. Env. Cent, and Tox., Vol. 6, No. 2 1971 Hansen, J. D., S. C. Schirmiel and E. Matthews $ Avoidance of Aroclor 1254 in Shi'iinp and Fishes O Bull, of Env. Cont. and Tox., Vol`. 12, No. 2 1974 pp.253-256 Hansen, David J. . Aroclor 1254: Effect on Composition of Developing Estuarine Animal Communities in the Laboratory * > Marine Science, Vol. 18, pp 19-33 1974 Hansen, D.J., S. C. Schimmel and J. Forester. 1974 ' Aroclor^L254 in Eggs of Sheepshead Minnows: Effect , ,on Fertilization Success and Survival of. Embryos and Fry. Proceedings of the Southeastern Game and Fish Commission (In Press) llsu, J.C., j. P. VanMillcr, J. L. Seymour & J. R. Allen ' Urinary Metabolites of 2, 5, 2', 5'-Tetraehlorobiphenyl . in the Nonhuman Primate (3.S999) Tree. Soc. Exp. Biology and Medicine, 150: 847-853 (1975) EX P-3111 58 of 63 PCB-ARCH0749053 * -5- Kimbrough, Kenate D. . _ The Toxicity of Polychlorinated Polycyclic Compounds nod ' Related Chemcials . CRC Critical Review in Toxicology, Vol. 2, Issue 4 1974 pp44S-498 Toxicology Review Lincer, Dr. Jefferey L. The Impact of Synthetic Organic Compounds on Estuarine Ecosystems. Nov. 1974, Research Report to EPA Gulf Breeze Lab. Nebecker, A.V. . Puglisi FA - Effect of Polychorinated Biphenyls (PCBS) . . On Survival and Reproduction of Daphnia, Gammarus, and Tanytarsus T AM Fish S 103 (4): 722 74 15R * Nebeker A.V. - . * ' Puglisi Pa Defoe Dl-Effeet of Polychlorinated Biphenyl . Compounds on Survival and Reproduction of Fathead Minnows and Flagfish , T AM Fish S 103 (3): 562 74 12R Nestd, H. & Joan Budal Chronic Oral Exposure of Rainbow Trout (Salmo gorrdneri) to A Polychlorinated Biphenyl (Aroclor 1254) Pathological Effects. Can. J. Comp. Med. Vol. 39 pp. 208-215 April 1975 * * Nimmo, D. R., R. R. Blackman, A. J. Wilson Jr., S. J. Forester Toxicity and Distribution of Aroclor^L254 in the Pink Shrimp Penoeus duorarum ; Marine Biology', International J. on Life in Oceans and Coastal Waters, Vol. II, No. 3 Nov. 1971 ppl91-197 ** 7 EX P-3111 # ; Page 59 of 63 PCB-ARCH0749054 -6- iniiio, D.U., P. D.'Wilson, R. R. Blackman & A. J. Wilson Jr. Polychlorinated Biphenyl Absorbed from Sediment by Fiddler Crabs and Pink Shrimp Nature Vo. 231, No. 5297 ppS0-S2' Hay 7, 1971 iuvno, D.R., & L. II. Bahner * . Some Physiological Consequences of Polychlorinated Biphenyl and Salinity - Stress in Penaeid Shrimp Pollution and Physiology of Marine Organisms 1974 Academic Press Inc. ;lmmo, D.R,, D. J. Hansen, J. A. Couch, N.R. Cooley, P.R. Parrish & J. I. Lowe. 1974. Toxicity of Aroclor ^"1254 and Its Physiological Activity in Several Estuarine Organisms. Archives Environmental Contamination and Toxicology Vol. 3, No. 1, 1975 Niuwo* D.R., J. Forester, P.T. Heitmuller and G. II. Cook. 1974. ( .V- . . Accumulation of Aroclori2S4 in Grass Shrimp (Palaemonetes pugio) in Laboratory and Field Exposures. * Bulletin of Env. Cont. and Tox. (In press) *%.' A Vol. 119, No. 4 1974 * ". * ' * m Norback, D. II. and J. R. Allen A'.. Chlorinated Triphenyl - Induced Extensions of the Hepatic Endoplasmic Reticulum Proc. Soc. Exp. Biology and Medicine, 139:H 1127-1131 (1972). Parrish, Patrick R., David J. Hansen, John N. Couch, James M. Patrick Jr. & Gary II. Cook . ' Effect of the Po.lychlorin.ted Biphenyl^ Ai'oclor lOIC. on . Estuarine Animals ASB Bulletin, Vol 21, No. 2, April 1974 p 74 ` * 022728^ EX P-3111 Page 60 of 63 PCB-ARCH0749055 Parrish, Patrick It., Jack I. Lowe, Alfred J. Wilson Jr., & James M. Patrick, Jr. Effects of Aroclor1254, A PCB on Oysters (. ASB Bulletin, Vol 19, No. 2, April 1972 p.90 * Parrish, Patrick R. 1974. __ Aroclor @L254, DDT and DDD, and Dieldrin: Accumulation and * Loss by AmericaA Oysters f-Crassostrea virginiea) Exposed Continuously for 56 Weeks. . Proceedings of National Shellfisheries (In press) Platonov? , N.S. & L. H. Karstad Dietary Effects of Polychlorinated Biphenyls on Mink Can. J. Comp. Med. 37 391-400 October 1973 Ringer, .K., R. J. Aulerick and M. Zabik /* . V ' * Effect of ^ietary Polyclorinated Biphenyls on Growth and Reproduction of Mink . American Chemical Society, Vo. 12, No. 2 pp.149-154 1972 Presented at 164th Meeting r ` Sehimmel Steven C., David J. Hansen and Jerrold Forester. 1974. t Effects of Aroclor ^L254 on Laboratory-reared Embryos and Fry of Sheepshead Minnows (Cyprinodon varieeatus). Transactions of the American Fisheries Society. Vol. 103, No. 3, July 1974 pp 582-586 Sehimmel , Steven C., David J. Hansen and Jerrold Forester Effects of Aroclor 1254 on Laboratory-reared Embryos and Fry of Cyprinodon variegatus . ... ASB Bulletin,21;2, April 1974,p.81. Stalling , D. L. & Mayer, F. L. (1972) t' Toxicities of PCBS to Fish and Environmental Residues Environ. Hlth Perspect., 1, 159-164 1 n*b \ EX P-3111 Page 61 of 63 PCB-ARCH0749056 c .. VanMiller, J.P., I.C. Hsu, and J.R. Allen Distribution and Metabolism of ^H-2,5,2f,5*-Tetrachlorobiphenyl in Rats (33610) * * Proe. Soc. for Exp.Biology and Medicine 148, 682-687 (1975). Walsh, F. and R. Mitchell * . *" Inhibition of Inter-Microbial Predation by Chlorinated Hydrocarbons Nature Vol 249, pp 673-674, June 14, 1974 Walsh, Gerald E. Insecticides, Herbicides and Polychlorinated Biphenyls in Estuaries J. Wash Acad Sci, Vol. 62, No. 2, 1972 World Health Organization The Hazards to Health and Ecological Effects of Persistent Substances in the Environment - Polychlorinated Biphenyls. Report of a Working Group-Regional Office for Europe . WHO Copenhagen (Printed 1975) 3-7 December 1973 - Good overall review 022728 7 EX P-3111 Page 62 of 63 PCB-ARCH0749057 FAiur.ir EX P-3111 Page 63 of 63 PCB-ARCH0749058